MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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Product Name Champion Gel It Out
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Part Number: 438-8459 Mix Number: 7-7785-2
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Mixture
CAS #
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Vandalism remover
Product Use
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Chase Products Co.
Manufacturer
19th and Gardner Road
Broadview, IL 60155 US
Phone: 708-865-1000
CHEM-TEL: 1-813-248-0585
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LEGEND Health * 2
4
HMIS/NFPA
Flammability 4
Severe 4
2 1
Serious 3
Physical Hazard 1
Moderate 2
Slight 1 Personal Protection
B
Minimal 0
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2. Hazards Identification
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DANGER
Emergency Overview
Extremely flammable. Contents under pressure. Containers may explode when heated.
May cause sensitisation by skin contact.
Contains a potential mutagen.
Contains a potential teratogen.
EYE AND SKIN IRRITANT.
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Potential short term health effects
Eye, Skin contact, Skin absorption, Inhalation, Ingestion.
Routes of exposure
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Causes irritation.
Eyes
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals. This product may be harmful if it is absorbed through the skin.
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Not a normal route of exposure. May cause stomach distress, nausea or vomiting.
Ingestion
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Blood. Eyes. Kidney. Liver. Respiratory system. Skin.
Target organs
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Prolonged or repeated exposure can cause drying, defatting and dermatitis.
Chronic effects
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Symptoms may include redness, oedema, drying, defatting and cracking of the skin.
Signs and symptoms
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
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3. Composition/Information on Ingredients
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Ingredient(s) CAS # Percent
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl) dimethyl, salts with bentonite 68953-58-2 1-5
Pine oil 8002-09-3 1-5
N-Butyl acetate 123-86-4 1-5
Ethanol 64-17-5 1-5
Diacetone alcohol 123-42-2 1-5
Amides, coco, N,N-bis(hydroxyethyl) 68603-42-9 1-5
Alcohols, C10-16, Ethoxylated 68002-97-1 1-5
Hexanedioic acid, dimethyl ester 627-93-0 15 - 40
Trimethyl benzene 25551-13-7 3-7
Propane 74-98-6 3-7
d-Limonene 5989-27-5 3-7
Dimethyl glutarate 1119-40-0 3-7
Toluene 108-88-3 5 - 10
Solvent naphtha (petroleum), light aromatic 64742-95-6 5 - 10
Propylene carbonate 108-32-7 5 - 10
Butane 106-97-8 7 - 13
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4. First Aid Measures
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First aid procedures
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
Eye contact
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a
poison control center or doctor for treatment advice.
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Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
Skin contact
minutes. Call a poison control center or doctor for treatment advice.
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If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention. If breathing has stopped, trained personnel should administer CPR
immediately.
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Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water.
Ingestion
Obtain medical attention. Never give anything by mouth if victim is unconscious, or is
convulsing.
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Symptoms may be delayed.
Notes to physician
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Do not puncture or incinerate container. Keep away from sources of ignition. No
General advice
smoking. If you feel unwell, seek medical advice (show the label where possible).
Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves. Show this safety data sheet to the doctor in
attendance. Avoid contact with eyes and skin. Keep out of reach of children.
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5. Fire-fighting Measures
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Flammable by WHMIS criteria. Containers may explode when heated. Flammable
Flammable properties
aerosol by flame projection test.
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Extinguishing media
Dry chemical. Carbon dioxide. Fog.
Suitable extinguishing media
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Unsuitable extinguishing media Not available
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Protection of firefighters
Contents under pressure. Pressurized container may explode when exposed to heat or
Specific hazards arising from
flame. Cool containers with flooding quantities of water until well after fire is out.
the chemical
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Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighers
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May include and are not limited to: Oxides of carbon.
Hazardous combustion products
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Explosion data
Not available
Sensitivity to mechanical
impact
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Not available
Sensitivity to static discharge
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6. Accidental Release Measures
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Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
basements or confined areas.
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Before attempting clean up, refer to hazard data given above. Remove sources of
Methods for cleaning up
ignition. Although the chance of a significant spill or leak is unlikely in aerosol
containers, in the event of such an occurrence, absorb spilled material with a
non-flammable absorbent such as sand or vermiculite.
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7. Handling and Storage
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Use good industrial hygiene practices in handling this material.
Handling
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Keep out of reach of children. Do not store at temperatures above 49癈 (120.2癋).
Storage
Keep away from heat, open flames or other sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure limits
Ingredient(s) Exposure limits
Alcohols, C10-16, Ethoxylated ACGIH-TLV
Not established
Amides, coco, N,N-bis(hydroxyethyl) ACGIH-TLV
Not established
Butane ACGIH-TLV
TWA: 1000 ppm
Diacetone alcohol ACGIH-TLV
TWA: 50 ppm
Dimethyl glutarate ACGIH-TLV
Not established
d-Limonene ACGIH-TLV
Not established
Ethanol ACGIH-TLV
TWA: 1000 ppm
Hexanedioic acid, dimethyl ester ACGIH-TLV
Not established
N-Butyl acetate ACGIH-TLV
TWA: 150 ppm
STEL: 200 ppm
Pine oil ACGIH-TLV
Mist: 5 mg/m3
Propane ACGIH-TLV
TWA: 1000 ppm
Propylene carbonate ACGIH-TLV
Not established
Quaternary ammonium compounds, bis(hydrogenated ACGIH-TLV
tallow alkyl) dimethyl, salts with bentonite Not established
Solvent naphtha (petroleum), light aromatic ACGIH-TLV
Not established
Toluene ACGIH-TLV
TWA: 20 ppm
Skin: 50 ppm
Trimethyl benzene ACGIH-TLV
TWA: 25 ppm
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Use only under good ventilation conditions or with respiratory protection.
Engineering controls
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Personal protective equipment
Wear safety glasses with side shields.
Eye/Face protection
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Rubber gloves. Confirm with a reputable supplier first.
Hand protection
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As required by employer code.
Skin and body protection
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Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respiratory protection
Avoid breathing mists or vapours.
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General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical & Chemical Properties
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Hazy liquid.
Appearance
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Tan
Colour
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Spray
Form
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Petroleum
Odour
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Not available
Odour threshold
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Liquid
Physical state
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Not available
pH
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Not applicable
Melting point
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Not available
Freezing point
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210 - 225 癈 (410.00 - 437.00 癋)
Boiling point
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Not available
Flash point
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> 1 (1=butyl acetate)
Evaporation Rate
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Not available
Flammability limits in air, lower, %
by volume
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Flammability Limits in Air, Upper, % Not available
by Volume
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Not available
Vapour pressure
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Not available
Vapour density
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0.978 ?0.005
Specific gravity
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Not available
Octanol/water coefficient
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Insoluble
Solubility (H2O)
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Not available
Auto-ignition temperature
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49.68
VOC (Weight %)
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Not available
Viscosity
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Not available
Percent volatile
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10. Chemical Stability & Reactivity Information
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Stable under recommended storage conditions.
Chemical stability
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Aerosol containers are unstable at temperatures above 49癈 (120.2癋). Do not mix with
Conditions to avoid
other chemicals.
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Oxidizers. Caustics.
Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon.
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Hazardous polymerisation does not occur.
Possibility of hazardous reactions
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11. Toxicological Information
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Component analysis - LC50
Ingredient(s) LC50
Alcohols, C10-16, Ethoxylated > 50 mg/l/4h rat
Amides, coco, N,N-bis(hydroxyethyl) Not available
Butane Not available
Diacetone alcohol Not available
Dimethyl glutarate 6.1 mg/l/4h rat
d-Limonene Not available
Ethanol 31623 ppm rat
Hexanedioic acid, dimethyl ester > 11 mg/l/4h rat
N-Butyl acetate 2000 ppm rat; 2000 mg/l/4h rat
Pine oil Not available
Propane Not available
Propylene carbonate Not available
Quaternary ammonium compounds, bis(hydrogenated 12.6 mg/l/4h rat
tallow alkyl) dimethyl, salts with bentonite
Solvent naphtha (petroleum), light aromatic 5.2 mg/l/4h rat
Toluene 12.5 mg/l/4h rat
Trimethyl benzene 10983 mg/l/4h rat
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Component analysis - Oral LD50
Ingredient(s) LD50
Alcohols, C10-16, Ethoxylated 2000 mg/kg rat
Amides, coco, N,N-bis(hydroxyethyl) 2700 mg/kg rat
Butane Not available
Diacetone alcohol 4000 mg/kg rat
Dimethyl glutarate 8191 mg/kg rat
d-Limonene 4400 mg/kg rat; 5600 mg/kg mouse
Ethanol 3450 mg/kg mouse; 1501 mg/kg rat
Hexanedioic acid, dimethyl ester 1920 mg/kg rat
N-Butyl acetate 10770 mg/kg rat; 7100 mg/kg mouse; 7400 mg/kg rabbit
Pine oil 3200 mg/kg rat
Propane Not available
Propylene carbonate 29000 mg/kg rat
Quaternary ammonium compounds, bis(hydrogenated 5000 mg/kg rat
tallow alkyl) dimethyl, salts with bentonite
Solvent naphtha (petroleum), light aromatic 4700 mg/kg rat
Toluene 636 mg/kg rat
Trimethyl benzene 5000 mg/kg rat
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Effects of acute exposure
Causes irritation.
Eye
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals. This product may be harmful if it is absorbed through the skin.
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Not a normal route of exposure. May cause stomach distress, nausea or vomiting.
Ingestion
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Contains potential skin sensitizers.
Sensitisation
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Non-hazardous by WHMIS criteria.
Chronic effects
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Non-hazardous by WHMIS criteria.
Carcinogenicity
ACGIH - Threshold Limits Values - Carcinogens
Ethanol 64-17-5 A4 - Not Classifiable as a Human Carcinogen
Toluene 108-88-3 A4 - Not Classifiable as a Human Carcinogen
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Mutagenic effects were observed in somatic and reproductive cells of live animals (rats
Mutagenicity
and mice) exposed to high oral doses of ethanol.
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Non-hazardous by WHMIS criteria.
Reproductive effects
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Contains a potential teratogen.
Teratogenicity
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12. Ecological Information
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Components of this product have been identified as having potential environmental
Ecotoxicity effects
concerns.
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Not available
Environmental effects
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Not available
Aquatic toxicity
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Not available
Persistence and degradability
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Not available
Bioaccumulation/accumulation
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Not available
Partition coefficient
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Not available
Mobility in environmental media
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Not available
Chemical fate information
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13. Disposal Considerations
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Not available
Waste codes
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Dispose in accordance with all applicable regulations.
Disposal instructions
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Not available
Waste from residues / unused
products
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Not available
Contaminated packaging
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14. Transport Information
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Transportation of Dangerous Goods (TDG)
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
80
Special provisions
<1L - Consumer Commodity
Packaging exceptions
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15. Regulatory Information
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This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHMIS - Ingredient Disclosure List
Butane 106-97-8 1%
Diacetone alcohol 123-42-2 1%
d-Limonene 5989-27-5 1%
Ethanol 64-17-5 0.1 %
N-Butyl acetate 123-86-4 1%
Propylene carbonate 108-32-7 1%
Toluene 108-88-3 1%
Trimethyl benzene 25551-13-7 1%
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Class A - Compressed Gas, Class B - Division 5; Flammable Aerosol, Class D - Division
WHMIS classification
2A, 2B
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Controlled
WHMIS status
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WHMIS labeling
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Inventory Status
Country(s) or region Inventory Name On Inventory (Yes/No)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing
country(s)
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16. Other Information
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Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
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07-Feb-2008
Issue date
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01-Feb-2008
Effective Date
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01-Feb-2011
Expiry Date
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Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
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