Material Safety Data Sheet
Acc. to ISO/DIS 11014
Printing date 06/20/2006 Reviewed on 06/20/2008
?Product details
?Trade name: Magic-Glos
?Article number: UV Formulation
Supplier:
JHB International.
?Information department: Product safety department.
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) resin (number average
molecular Weight 700) 50-100% 2386-87-0 7-Oxabicyclo[4.1.0]heptane-3-carboxylic
acid,7oxibicyclo[4.1.0]hept-3-ylmethyl ester 25-50% 37625-56-2 2-Oxepanone,polymer
with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol 10-25%
?Additional information:
HEALTH HAZARDS / ROUTES OF EXPOSURE
INHALATION: No significant signs or symptoms indicative of any adverse health hazard
are expected to occur at standard conditions due to the low volatility of this material.
However, aerosols, or vapors which may be generated at elevated processing
temperatures, may cause respiratory tract irritation. Symptoms of irritation may include
coughing, mucous production and shortness of breath.
EYE CONTACT -- PRIMARY ROUTE: Although no appropriate human or animal health
effects data are known to exist, this material is expected to cause eye irritation. May
cause moderate irritation with symptoms including burning sensation, tearing, redness or
swelling.
SKIN ABSORPTION -- PRIMARY ROUTE: Although no appropriate human or animal
health effects data are known to exist, this material is expected to be a slight skin
absorption hazard.
SKIN IRRITATION -- PRIMARY ROUTE: Although no appropriate human or animal
health effects data are known to exist, this material is expected to be a skin irritant.
Symptoms may include localized redness or rash and swelling of the affected area.
Symptoms may be delayed. A more severe skin response may occur after prolonged
contact with this material. Although no appropriate human or animal health effects data
is known to exist, this material may cause an allergic skin reaction (sensitization) in
susceptible individuals upon repeated exposure.
INGESTION: Although no appropriate human or animal health effects data are known to
exist, this material is expected to be a slight ingestion hazard.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: This material or its
emissions may induce an allergicor sensitization reaction and thereby aggravate systemic
disease.
?Hazard description:
Irritant
Dangerous for the environment
?Information pertaining to particular dangers for man and environment:
Irritating to eyes and skin.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Only for trade users / technical specialists
Keep out of the reach of children.
?Classification system:
The classification was made according to the latest editions of international substances
lists, and expanded upon from company and literature data.
?NFPA ratings (scale 0 - 4)
11Health = 1
Fire = 1
Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTHIRE
REACTIVITY
1
1
0
Health = 1
Fire = 1
Reactivity = 0
?Additional information:
WARNING! This is a light sensitive product polymerized by exposure to UV Light. Do not
expose to Ultraviolet
Light/Radiation, Direct Sunlight, High temperatures (>100 F), and oxidizing agents.
High temperatures, exposure to light, radiation exposure, inhibitor depletion, accidental
impurities, inert gas blanketing, and oxidizing agents may cause spontaneous
polymerization reaction. Polymerization in large masses may cause excess exothermic
reaction generating heat and also pressure. Closed containers may rupture or explode
during runaway polymerization.
4 First aid measures?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult
doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a
doctor.
?After swallowing:
If symptoms persist consult doctor.
A person vomiting while lying on their back should be turned onto their side.
DO NOT attempt to give anything by mouth to an unconscious person.
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
Use fire fighting measures that suit the environment.
?Special hazards caused by the material, its products of combustion or resulting gases:
High temperatures, exposure to light, radiation exposure, inhibitor depletion, accidental
impurities, inert gas blanketing, and oxidizing agents may cause spontaneous
polymerization reaction. Polymerization in large masses may cause excess exothermic
reaction generating heat and also pressure. Closed containers may rupture or explode
during runaway polymerization.
?Protective equipment:
Wear fully protective suit.
Do not inhale explosion gases or combustion gases.
Do not enter fire area with out proper protection. Acrid smoke-fumes/carbon
monoxide/carbon dioxide/nitrogen oxides and perhaps other toxic vapors may be
released during a fire involving this product. fight fire from safe distance/protected
location. Heat/impurities may increase temperature/build pressure/rupture closed
containers, spreading fire, increasing risk of burns/injuries. Water may be ineffective in
firefighting due to low solubility.
Use water spray/fog for cooling. Pressure relief system may plug with solids, increasing
risk of overpressure.
Notify authorities if liquid enters sewer/public waters.
6 Accidental release measures?Person-related safety precautions:
Wear protective clothing.
Keep people at a distance and stay upwind.
?Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Ensure adequate ventilation.
Spilled or released material may polymerize and release heat/gases. Extinguish all
ignition sources and ventilate area. Wear protective equipment during clean up. Dike and
recover large spill. Soak up small spill with inert solids (such as vermiculite, clay) and
sweep/shovel into vented disposal container. wash spill area with a strong detergent and
water solution; rinse with water but minimize water use during clean up. For spills on
water, contain, minimize dispersion and collect. Dispose/report per regulatory
requirements.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Wear appropriate protective equipment when handling this material (See Section 8 of
MSDS). Do not use localized heat sources such as ovens or band heaters to heat product.
Exposing this product to elevated temperatures (>100 F) may compromise the product
quality and/or result in an uncontrolled hazardous polymerization. Product is packaged
with inhibitor(s). The product's inhibitor(s) require the presence of dissolved oxygen.
Maintain, at a minimum, the original headspace in the product container and do not
blanket or mix with oxygen-free gas. as it renders inhibitor ineffective.
?Information about protection against explosions and fires: No special measures
required.
?Storage:
?Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
Store in dark area away from light.
Store at temperatures between 25 C - 35 C.
Store indoors. DO NOT EXPOSE TO OXYGEN-FREE GAS.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems:
If handling results in aerosol or vapor generation, local exhaust ventilation is
recommended.
?Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that
have to be monitored at the workplace.
?Additional information: The lists that were valid during the creation were used as
basis.
?Personal protective equipment:
?General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Avoid contact with the eyes and skin.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or
using toilet facilities.
Promptly remove soiled clothing/wash thoroughly before reuse. Shower after work using
plenty of soap and
water.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use respiratory protective device that is independent of
circulating air.
If this material is handled at elevated temperatures or under mist/vapor forming
conditions, NIOSH/MSHA approved respiratory protection equipment should be used.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the
product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of
diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is
a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective
gloves and has to be observed.
?Eye protection:
Tightly sealed goggles
?Body protection: Impervious protective clothing
?General Information
Form: Liquid
Color: According to product specification
Odor: Mild
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 211癈 (412癋)
?Flash point: 118癈 (244癋)
?Auto igniting: Product is not self-igniting.
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation
methods for preparations:
Irritant
12 Ecological information
?Ecotoxical effects:
?Remark: Toxic for fish
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Must not be disposed of together with household garbage. Do not allow product to reach
sewage system.
?Uncleaned packaging:
?Recommendation:
Disposal must be made according to official regulations.
Dispose of in accordance to all local, state, and/or national relegislation.
14 Transport information
?DOT regulations:
?Hazard class: -
?Remarks: Not regulated.
?Maritime transport IMDG:
?IMDG Class: -
?Marine pollutant: No
?Remarks: Not regulated.
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
?Remarks: Not regulated
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
71-43-2 benzene
?TSCA (Toxic Substances Control Act):
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) resin (number average
molecular weight
700)
108-32-7 propylene carbonate
71-43-2 benzene
?Proposition 65
?Chemicals known to cause cancer:
71-43-2 benzene
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
71-43-2 benzene
?Chemicals known to cause developmental toxicity:
71-43-2 benzene
?Cancerogenity categories
?EPA (Environmental Protection Agency)
71-43-2 benzene A
?IARC (International Agency for Research on Cancer)
71-43-2 benzene 1
?NTP (National Toxicology Program)
71-43-2 benzene K
?TLV (Threshold Limit Value established by ACGIH)
71-43-2 benzene A1
?NIOSH-Ca (National Institute for Occupational Safety and Health)
71-43-2 benzene
?OSHA-Ca (Occupational Safety & Health Administration)
71-43-2 benzene
?Product related hazard information:
The product has been classified and marked in accordance with directives on hazardous
materials.
?Hazard symbols:
Irritant
Dangerous for the environment
?Hazard-determining components of labeling:
reaction product: bisphenol-A-(epichlorhydrin) resin (number average molecular weight
700)
?Risk phrases:
Irritating to eyes and skin.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
?Safety phrases:
Keep out of the reach of children.
Avoid contact with skin and eyes.
Do not empty into drains, dispose of this material and its container at hazardous or
special waste collection point.
Do not breathe fumes/aerosol.
Wear suitable protective clothing, gloves and eye/face protection.
Use only in well-ventilated areas.
After contact with skin, wash immediately with plenty of soap and water.
?Special labeling of certain preparations:
Only for trade users / technical specialists
Keep out of the reach of children.
this information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid
contractual relationship. The information given and the recommendations made herein
apply to our product alone and are not combined with other product(s).
Such are based on our research and on data from other reliable sources and are believed
to be accurate. No guarantee of accuracy is made. It is the user's responsibility before
using any product to verify this data under their own operating conditions and to
determine whether the product is suitable for their purposes.
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