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MSDS Material Safety Data Sheet
CAS

02-04-2 1330-20-7 78-93-3 98-56-6 108-32-7 67-64-1 540-88-5

File Name: 02-04-2_1330-20-7_78-93-3_98-56-6_108-32-7_67-64-1_540-88.asp

Material Safety Data Sheet - PermaShine



Material Safety Data Sheet
According to ANSI Z400.1-2003
Date Printed: 02-04-2010


Section 1 - Product and Company Information


Product Name: PermaShine
Product Part Number(s): 3620-1, 3620-4

COMPANY IDENTIFICATION: EMERGENCY TELEPHONE NUMBER
Urethane Supply Company 24 Hour Emergency Contact Chemtrec - 1-800-424-9300
1128 Kirk Rd. Customer Information Number 256-638-4103
Rainsville, AL 35986


Section 2 - Hazards Identification

Appearance: Clear, Low Viscosity, Pourable liquid
Odor: Strong, sweet solvent odor
Hazards of Product:

WARNING! Flammable liquid and vapor. May cause allergic skin reaction. May
cause eye irritation. Vapor explosion hazard. Vapors may travel long
distances; ignition and/or flash back may occur. Isolate area. Stay out of low
areas.

Signal Word: WARNING!
Signal Word
Flammable Liquid
Hazard:

HMIS Rating (Scale 0 - 4) NFPA Ratings

HEALTH 2 Health = 2 Health = 2
3
FIRE 3 Fire = 3 Fire = 3
2 0
PHYSICAL 1 Physical = 1 Reactivity = 0

PERSONAL PROTECTION G Personal Protection = G




Potential Health Effects


Eye Contact: Moderate irritation, redness, blurred vision.
Skin Contact: Moderate irritation, redness, dermatitis.
Skin
None known.
Sensitization:
Inhalation: May result in irritation to the respiratory tract.
Ingestion: Gastrointestinal irritation.
Repeated Xylene is reported to have caused hearing loss in laboratory animals upon exposure to high
Exposure: concentrations; such effects have not been reported in humans.




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Material Safety Data Sheet - PermaShine


Section 3 - Composition/Information on Ingredients

Component CAS # Amount

Xylene 1330-20-7 1 - 3%
Methyl Ethyl Ketone 78-93-3 1 - 3%
Parachlorobenzotriflouride (PCBTF) 98-56-6 20 - 30%
Propylene Carbonate 108-32-7 15 - 20%
Acetone 67-64-1 10 - 15%
tert-Butyl Acetate 540-88-5 30 - 35%
Acrylic polymer Blend 15 - 30%


Section 4 - First-Aid Measures

Eye Contact: Flush with large amounts of water until all material is removed. If irritation persists, get medical attention
immediately.
Skin Contact: Wash with soap and water. Remove contaminated clothing and wash before re-use. Shower. If irritation
persists, see physician.
Inhalation: Move to fresh air; artificial respiration if necessary. Consult physician immediately.
Ingestion: Do not induce vomiting. Consult physician immediately.
Medical Conditions Aggravated by Exposure: Bronchitis, CNS disorders, allergies, nausea.


Section 5 - Fire Fighting Measures

Extinguishing Media: Dry chemical, carbon dioxide, chemical foam.
Fire Fighting Procedures: Fight source of fire. Water spray to cool containers.
Special Protective Equipment for Firefighters: If this material is involved in a fire, NIOSH approved self contained
breathing apparatus should be worn.
Unusual Fire and Explosion Hazards: Vapors are heavy, may concentrate at lower levels creating hazard. At high
temperatures, containers may burst.
Hazardous Combustion Products: Chlorine, hydrogen chloride, hydrogen chloride (hydrochloric acid), phosgene.


Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled:
Personal Precautions: Remove from ingnition sources, ventilate and vacate area. Allow solvents to evaporate.
Environmental Precautions:


Section 7 - Handling and Storage

General Handling: Do not breathe vapor. Avoid contact with skin, eyes, or clothing. Wash thoroughly after handling.
Other Precautions: Wear gloves, goggles and protective clothing to prevent contact with the product.
Storage: Store material at temperatures between 49癈 (120癋) and 2癈 (36癋). Do not store containers in direct sunlight.


Section 8 - Exposure Controls / Personal Protection

Component Source Type Value Remarks
Acetone OSHA STEL PEL 1000 ppm
Acetone OSHA TWA PEL 750 ppm
Acetone ACGIH STEL 750 ppm TLV
Acetone ACGIH TWA 500 ppm TLV
Methyl Ethyl Ketone OSHA STEL PEL 300 ppm
Methyl Ethyl Ketone ACGIH TWA 200 ppm
Methyl Ethyl Ketone ACGIH STEL 300 ppm



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Material Safety Data Sheet - PermaShine

Methyl Ethyl Ketone NIOSH TWA 590 mg/m3
Methyl Ethyl Ketone NIOSH STEL 885 mg/m3
Methyl Ethyl Ketone NIOSH TWA 200 ppm
Methyl Ethyl Ketone OSHA TWA PEL 200 ppm
Methyl Ethyl Ketone OSHA TWA PEL 590 mg/m3
Methyl Ethyl Ketone OSHA STEL PEL 885 mg/m3
Methyl Ethyl Ketone NIOSH STEL 300 ppm
tert-Butyl Acetate CEIL 250 ppm
tert-Butyl Acetate TWA 200 ppm
Xylene ACGIH TWA 100 ppm
Xylene ACGIH STEL 150 ppm


Personal Protection


Eye/Face Protection: Goggles or side-shielded safety glasses.
Skin Protection: Polyvinyl gloves and apron.
Respiratory Protection: Use of a NIOSH approved chemical/mechanical filter, designed to remove a combination of
particles and vapor.
Hygenic Measures: Wash hands before eating, smoking or using wash room
Other Protection Measures: Wear protective clothing to prevent contact with product.
Engineering Controls: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
TLV(s).




Section 9 - Physical and Chemical Properties

Appearance: Low viscosity pourable liquid.
Color: Clear.
Odor: Strong, sweet solvent odor.
Boiling Point: >140癈
Specific Gravity: 1.00
Evaporation Rate: Faster than n-Butyl Acetate
Percent Volitiles: 80 - 85%
Volitile Organic Compounds: 252g/l (2.1 lb/gal)


Section 10 - Stability and Reactivity

Stability/Instability: Stable
Conditions To Avoid: Excessive heat and freezing temperatures.
Incompatible Materials: Oxidizing agents, alkalies and high temperatures.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: Chlorine, hydrogen chloride (hydrochloric acids), phosgene.


Section 11 - Toxicological Information

Acute Toxicity
Ingestion
LD50: Not available
Skin Absorption
LD50: Not available
Inhalation
LC50: Not Available
Sensitization
Not Available
Skin Irritation
Irritant



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Material Safety Data Sheet - PermaShine


Section 12 - Ecological Information

CHEMICAL FATE
ECOTOXICITY
Not Available


Section 13 - Disposal Considerations

Disposal Method:
Disposal should be in accordance with applicable regional, national and local laws. Local regulations may be more stringent
that regional or national requirements.


Section 14 - Transport Information


DOT

Proper Shipping Name: Paint
Hazard Class: 3
ID Number: UN1263
Packing Group: II




Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know
Act of 1986) Sections 311 and 312


The following table list hazardous components and the regulatory lists for which they are required to be reported.




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http://www.urethanesupply.com/MSDS3620.php
NTP Cancerogenity
IARC Cancerogenity
EPA Cancerogenity
CERCLA
Rhode Island Listed
Massachusetts Hazardous Listed
Material Safety Data Sheet - PermaShine




Pennsylvania Hazardous Substance List
Known to California to cause cancer
SARA 313 Listed
Amount
# CAS




Page 5 of 6
Component
Material Safety Data Sheet - PermaShine


Section 16 - Other Information

Legend
ACGIH American Conference of Governmental Hygenists
CAS Chemical Abstract Service
CFR Code of Federal Regulations
EPA Environmental Protection Agency
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
LC Lethal Concentration
LD Lethal Dose
LTEL Long Term Exposure Limit
MSDS Material Safety Data Sheet
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OEL Occupational Exposure Limit
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Level
SARA Superfund Amendment and Reauthorization Act
STEL Short Term Exposure Limit
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
TWA Time Weighted Average
VOC Volitile Organic Compounds

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.




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