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LM-0217
MATERIAL SAFETY DATA SHEET
I. IDENTIFICATION .
MANUFACTURED BY: Diamond Vogel Paint REVISED: 09/15/2009
1020 Albany Place SE PRINTED: 09/22/2009
Orange City, IA 51041
General Information:
24 Hour Emergency Telephone Mon-Fri 8 AM - 5 PM
CHEMTREC 1-800-424-9300 712-737-4993
TRADE NAME: Mult-E-Poxy 180 FD/Low Temp (Pt B)
MFG. PRODUCT NUMBER: LM-0217
II. HAZARDOUS INGREDIENTS .
CAS #14807-96-6 Talc (powder) WT %: 5-20
ACGIH TLV: 2 mg/m3 TWA (resp) ACGIH STEL:
OSHA PEL: 20 mppcf TWA OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: LEL%:
Trade Secret WT %: 5-20
ACGIH TLV: NE ACGIH STEL: NE
OSHA PEL: NE OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: NA LEL%: NA
Trade Secret WT %: 5-20 Footnote: (1)
ACGIH TLV: N.E. ACGIH STEL: N.E.
OSHA PEL: N.E. OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: <.1mmHg@25C LEL%: N.E.
CAS #1330-20-7 Xylene WT %: 5-20 Footnote: (1)
ACGIH TLV: 100 ppm ACGIH STEL: 150 ppm
OSHA PEL: 100 ppm OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: 7 mmHg@20C LEL%: 1
CAS #68515-49-1 Diisodecyl Phthalate WT %: 1-5
ACGIH TLV: NE ACGIH STEL: NE
OSHA PEL: NE OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: .0 mmHg@68F LEL%: 0.3
CAS #108-32-7 Propylene carbonate WT %: 1-5
ACGIH TLV: ACGIH STEL:
OSHA PEL: OSHA CEILING: OSHA PEAK:
VAPOR PRESSURE: .02 mmHg20C LEL%: 1.8
Trade Secret WT %: 1-5
ACGIH TLV: N.E. ACGIH STEL: N.E.
OSHA PEL: N.E. OSHA CEILING: N.E. OSHA PEAK: N.E.
VAPOR PRESSURE: <.01 @ 20 C LEL%: N.E.
Trade Secret WT %: 1-5
ACGIH TLV: n.e. ACGIH STEL: n.e.
OSHA PEL: n.e. OSHA CEILING: n.e. OSHA PEAK: n.e.
VAPOR PRESSURE: 0.01 mmHg21c LEL%:
CAS #9046-10-0 Polyoxypropylenediamine WT %: 1-5
ACGIH TLV: NE ACGIH STEL: NE
OSHA PEL: NE OSHA CEILING: NE OSHA PEAK: NE
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VAPOR PRESSURE: 1 mmHg@212F LEL%: 0.7
CAS #98-00-0 Furfuryl Alcohol WT %: 1-5
ACGIH TLV: 10 ppm ACGIH STEL: 15 ppm
OSHA PEL: 50 ppm OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: .6 mmHg@20C LEL%: 1.8
CAS #100-41-4 Ethyl Benzene WT %: 1-5 Footnote: (2)
ACGIH TLV: 100 ppm ACGIH STEL: 125 ppm
OSHA PEL: 100 ppm OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: 10 mmHg@20C LEL%: 1
CAS #14808-60-7 Crystalline Silica WT %: 0.248 Footnote: (3)
ACGIH TLV: 0.025 mg/m3 ACGIH STEL: NE
OSHA PEL: 10/(%SiO2+2) mg/m3 OSHA CEILING: NE OSHA PEAK: NE
VAPOR PRESSURE: NA LEL%: NA
WARNING MESSAGES:
(1) Reports have associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Chronic exposure may
cause damage to the central nervous system, respiratory system, lung, eye, skin, liver,
gastrointestinal tract, spleen, kidneys, and blood.
(2) International Agency for Research on Cancer (IARC) Monograph Volume 77 (2000) concluded
that Ethylbenzene is "possibly carcinogenic to humans (Group 2B)" based on inadequate
evidence in humans and sufficient evidence in experimental animals.
(3) International Agency for Research on Cancer (IARC) Monograph Volume 68 (1997) concludes
that Crystalline Silica is "carcinogenic to humans (Group 1)" based on sufficient
evidence in humans and experimental animals.
(4) See Section IX for reportable Hazardous Air Pollutants.
III. PHYSICAL DATA .
BOILING RANGE: 266-500?F
EVAPORATION RATE: * slower than ether *
PERCENT VOLATILE BY VOLUME: 29.97% WEIGHT PER GALLON: 11.55 LBS
VAPOR DENSITY: * heavier than air *
ACTUAL VOC (lb/gal): 2.27
EPA VOC (lb/gal): 2.28 EPA VOC (g/L): 273.24
IV. FIRE AND EXPLOSION HAZARD DATA .
FLASH POINT: 27?C 81?F LEL: Refer to Section II
FLAMMABILITY CLASSIFICATION: CLASS 1C
HAZARD CLASSIFICATION: *Flammable Liquid - CORROSIVE
EXTINGUISHING MEDIA: Use water spray, dry chemical, foam, or Carbon
Dioxide. Use water spray to cool fire-exposed
containers.
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UNUSUAL FIRE AND EXPLOSION HAZARDS:
May generate toxic or irritating combustion products.
Sudden reaction and fire may result if product is mixed
with an oxidizing agent.
SPECIAL FIRE FIGHTING PROCEDURES:
In case of fire and/or explosion do not breathe fumes.
Burning will produce toxic fumes. Wear NIOSH approved
self-contained breathing apparatus with independent air
supply and full turn-out gear to fight fires. Use water
spray to reduce vapors. If water pollution occurs, notify
appropriate authorities. Keep containers cool with water
spray. Avoid skin contact.
V. HEALTH HAZARD DATA .
THRESHOLD LIMIT VALUE: See Section II.
EFFECTS OF OVEREXPOSURE:
CORROSIVE
ACUTE-
Eye Contact: Severe irritant, chemical burn possible, possible
skin damage. Vapors may cause headaches,
dizziness, anesthesia, drowsiness,
unconsciousness, and other central nervous system
effects, including death.
Skin Contact: Severe irritant, corrosion to tissue, possible
skin burns.
Inhalation: Moderate to severe irritant. Minute amounts
aspirated into the lungs during ingestion or
vomiting may cause mild to severe pulmonary injury
and possible death. High vapor concentrations are
irritating to the eyes and the respiratory tract,
and may cause headaches, dizziness, anesthesia,
drowsiness, unconsciousness, and other central
nervous system effects, including death.
Ingestion: Severe irritation, possible gastrointestinal tract.
May cause nausea unless treated promptly.
CHRONIC- Repeated and/or prolonged exposure to low concentrations
of vapor may cause: sore throat, eye irritation, nausea,
headache, adverse skin effects (such as defatting, rash,
irritation or corrosion), adverse eye effects (such as
conjunctivitis or corneal damage). Repeated and/or
prolonged contact with the skin may cause allergic
reaction/sensitization or burns. Xylene contains
ethylbenzene which has been classified as a possible
carcinogen to humans, Group 2B, by the International
Agency for Research on Cancer (IARC), based on
sufficient evidence in laboratory animals but inadequate
evidence for cancer in humans. Prolonged or repeated
overexposure to ethylbenzene may cause the following:
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kidney effects, liver effects, lung effects, thyroid
effects, testicular effects, pituitary effects.
This product contains crystalline silica which may cause
delayed respiratory disease (silicosis) if inhaled over a
prolonged period of time. Avoid breathing dust. Use a
NIOSH/MSHA approved respirator where TLV for crystalline
silica may be exceeded.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Asthma, Chronic respiratory disease (e.g. Bronchitis, Emphysema)
Eye disease, Skin disorders and Allergies.
PRIMARY ROUTE(S) OF ENTRY: Ingestion, Skin Absorption, Inhalation
EMERGENCY AND FIRST AID PROCEDURES:
EYE CONTACT- Hold eyelids apart and immediately flush eyes
with plenty of water for at least 15 minutes. Call a
Physician.
SKIN CONTACT- Remove product and immediately flush affected area
with water for at least 15 minutes. Call a physician.
Except in the most minor, superficial and localized burns,
cover the affected area with a sterile dressing or clean
sheeting and transport for medical care. DO NOT APPLY
GREASES OR OINTMENTS. Control shock if present.
INHALATION- Move patient to fresh air. If breathing has stopped
or is labored give mouth-to-mouth respiration. Supplemental
oxygen may be indicated. Prevent aspiration of vomit. Turn
victim's head to the side. Assure mucus does not obstruct
airway. Call a physician.
INGESTION- In the event of ingestion, administer 3-4 glasses of
milk or water. DO NOT INDUCE VOMITING. Obtain medical care
and hospital treatment immediately. Note to physician: This
product is highly injurious to all tissues, similar to that
of ammonia or ammonia gas. Chemical pneumonitis, pulmonary
edema, laryngeal edema and delayed scarring of the airway or
other affected tissues may occur following exposure. There
is no specific treatment. Clinical management is based on
supportive treatment, which is similar to that for thermal
burns.
VI. REACTIVITY DATA .
STABILITY: *stable* HAZARDOUS POLYMERIZATION: *will not occur*
INCOMPATIBILITY:
Oxidizing agents, cleaning solutions, such as chromerge (sulfonic
acid/dichromate) and aqua regia. A reaction accompanied by large
heat release occurs when the product is mixed with acids. Heat
generated may be sufficient to cause vigorous boiling creating a
hazard due to splashing or splattering of hot material. CAUTION!
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LM-0217
N-Nitrosamines, many of which are known to be potent carcinogens,
may be formed when the product comes in contact with nitrous acid,
nitrites or atmospheres with high nitrous oxide concentrations.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide and Nitrogen Oxides in a
fire. Nitrogen Oxide can react with water vapors to form
corrosive nitric acid (TLV= 2 ppm). Combustion of product
under oxygen-starved conditions can be expected to produce
numerous toxic products including: nitiles, amides.
Irritating and toxic fumes at elevated temperatures.
CONDITIONS TO AVOID: Avoid acid contamination and skin contact.
Keep containers tightly closed. No smoking
or eating in handling area.
VII. SPILL OR LEAK PROCEDURES .
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Remove all sources of ignition (flames, hot surfaces and
electrical, static or frictional sparks). Avoid breathing
vapors. Ventilate area. Use non-sparking tools. Remove with
inert absorbant.
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and
federal regulations.
VIII. SPECIAL PROTECTION INFORMATION .
RESPIRATORY PROTECTION:
If air concentrations above the TLV are possible, wear a
NIOSH/MSHA approved respirator.
VENTILATION: Provide general dilution or local exhaust ventilation in
volume and pattern to keep TLV and LEL of most hazardous
ingredient in Section II, below acceptable limit.
PROTECTIVE GLOVES:
Wear suitable gloves (S37). Nitrile rubber gloves. In
emergency situations, wear impermeable gloves with cuffs to
prevent spread of material to area above the wrists.
EYE PROTECTION:
Splash proof eye goggles. In emergency situations, use eye
goggles with a full face shield.
OTHER PROTECTIVE EQUIPMENT:
Wear suitable clothing. Long sleeved clothing.
HYGIENIC PRACTICES: See Section V
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IX. SPECIAL PRECAUTIONS .
PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:
Keep away from heat. Keep away from sparks, flames and other
sources of ignition. Store in a cool, dry place. Keep
container closed when not in use. Avoid contact with eyes,
skin and clothing. Avoid breathing vapor or mist. Use with
adequate ventilation. Ground and bond containers when
transferring material. Use explosion proof equipment. Follow
all MSDS/label precautions even after the container is emptied
because it may retain product residues. Wash thoroughly after
handling.
OTHER PRECAUTIONS: Do not use sodium nitrite or other nitrosating
agents in formulations containing this product.
Cancer-causing nitrosamines could be formed. Adhere to
work practice rules established by government
regulations.
LIST OF HAZARDOUS AIR POLLUTANTS SUBJECT TO THE PROVISIONS OF THE CLEAN AIR
ACT, TITLE I SECTION 112 'National Emission Standards for Hazardous Air
Pollutants':
Wt% of HAPS Pounds HAPS/
Ingredient CAS # in product Gal product
------------------------------ ------------ ----------- ----------
Xylene 1330-20-7 12.5 % 1.4
Ethyl Benzene 100-41-4 2.7 % 0.3
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