Material Safety Data Sheet
Preparation Date: 30-Dec-2009 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F400-0400A
Trade Name ELASTO-SHIELD
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
HARMFUL IF INHALED.
MAY CAUSE LUNG INJURY.
MAY CAUSE ALLERGIC RESPIRATORY REACTION; EFFECTS MAY BE PERMANENT.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Moderately irritating to the eyes. Risk of serious damage to eyes.
Skin Irritating to skin. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system. May cause allergic respiratory reaction.
Ingestion May be harmful if swallowed.
Chronic Effects
Avoid repeated exposure
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Eyes, Respiratory system
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
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3. COMPOSITION/INFORMATION ON INGREDIENTS
101-68-8 54.05
DIPHENYLMETHANE DIISOCYANATE (MDI)
REACTIVE MONOMER
108-32-7 4.7
PROPYLENE CARBONATE
101-68-8 0.55
DIPHENYLMETHANE DIISOCYANATE
(VOLATILE MONOMER)
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties No information available
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Hydrogen cyanide.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Use only with adequate ventilation.Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene
and safety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Close container after each use.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
Ceiling: 0.2 mg/m3 TWA: 0.051 mg/m3 TWA: 0.2 祄ol/m3 TWA: 0.2 mg/m3 TWA:
DIPHENYLMETHANE TWA: 0.005 ppm
DIISOCYANATE (MDI) Ceiling: 0.02 ppm TWA: 0.005 ppm TWA: 0.005 ppm CEV: 0.005 ppm TWA: 0.051
mg/m3 TWA: 0.02 ppm
REACTIVE MONOMER 0.02 ppm CEV: 0.8
祄ol/m3
Ceiling: 0.2 mg/m3 TWA: 0.051 mg/m3 TWA: 0.2 祄ol/m3 TWA: 0.2 mg/m3 TWA:
DIPHENYLMETHANE TWA: 0.005 ppm
DIISOCYANATE (VOLATILE Ceiling: 0.02 ppm TWA: 0.005 ppm TWA: 0.005 ppm CEV: 0.005 ppm TWA: 0.051
mg/m3 TWA: 0.02 ppm
MONOMER) 0.02 ppm CEV: 0.8
祄ol/m3
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection Safety glasses with side-shields
Respiratory Protection INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. Do not breathe
vapor or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved)
during and after application unless air monitoring demonstrates vapor/mist levels are below
applicable limits. An airline respirator (TC 19C NIOSH/MSHA) is recommended. A vapor-
particulate respirator (TC 23C NIOSH/MSHA) may be appropriate where air monitoring
demonstrates vapors are less than ten times the applicable exposure limits and the
isocyanate concentration is less than its applicable exposure limit. The use of an air-supplied
respirator is mandatory whenever the airborne concentration of isocyanate monomer is
unknown.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point Not applicable
Method Pensky Martens - Closed Cup
Boiling Point/Range No information available
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.11133
Density 9.24796
VOC Content (lbs/gal) .051
% Volatile by Weight .5500
% Volatile by Volume .5142
10. STABILITY AND REACTIVITY
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10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks.
Amines.
Incompatible Products Water, alcohols, amines, strong Possibility of Hazardous None under normal processing
bases, metal components, Reactions
surface active materials.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
DIPHENYLMETHANE 9200 mg/kg ( Rat )
DIISOCYANATE (MDI) REACTIVE
MONOMER
PROPYLENE CARBONATE 29000 mg/kg ( Rat ) 20000 mg/kg ( Rabbit )
DIPHENYLMETHANE 9200 mg/kg ( Rat )
DIISOCYANATE (VOLATILE
MONOMER)
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Eyes, Respiratory system.
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
PROPYLENE CARBONATE EC50 > 500 mg/L 72 h LC50= 2200 mg/L Leuciscus EC50 > 10000 mg/L 17 h EC50 > 500 mg/L 48 h
idus 96 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
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14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT,WATER BASE FREEZABLE
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
Component
DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER)
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
DIPHENYLMETHANE DIISOCYANATE (MDI) REACTIVE 101-68-8 54.05 1.0
MONOMER
DIPHENYLMETHANE DIISOCYANATE (VOLATILE 101-68-8 0.55 1.0
MONOMER)
SARA 311/312 Hazardous Categorization
Chronic Health Hazard Yes
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
DIPHENYLMETHANE DIISOCYANATE (MDI) REACTIVE 5000 lb
MONOMER
DIPHENYLMETHANE DIISOCYANATE (VOLATILE 5000 lb
MONOMER)
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
State Right-to-Know
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Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
DIPHENYLMETHANE X X X X X
DIISOCYANATE (MDI)
REACTIVE MONOMER
DIPHENYLMETHANE X X X X X
DIISOCYANATE (VOLATILE
MONOMER)
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
D2A Very toxic materials
Component NPRI
DIPHENYLMETHANE DIISOCYANATE (MDI) REACTIVE MONOMER Part 1, Group 1 Substance
DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) Part 1, Group 1 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 3 Flammability 1 Reactivity 0
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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Material Safety Data Sheet
Preparation Date: 30-Dec-2009 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F400-WH04B
Trade Name ELASTO-SHIELD OFF-WHITE
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
WARNING!
CAUSES SKIN AND EYE BURNS.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Causes burns.
Skin Causes burns. May cause sensitization by skin contact. May cause cyanosis.
Inhalation Irritating to respiratory system. May cause cyanosis.
Ingestion May be harmful if swallowed. May cause cyanosis.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Eyes, Lungs, Respiratory system
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
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3. COMPOSITION/INFORMATION ON INGREDIENTS
9046-10-0 30 - 60
POLYOXYPROPYLENEDIAMINE
68479-98-1 10 - 30
DIETHYLTOLUENEDIAMINE
13463-67-7 5 - 10
TITANIUM DIOXIDE (TOTAL DUST)
1318-02-1 5 - 10
POTASSIUM ALUMINOSILICATE
5285-60-9 5 - 10
N,N'-DIALKYLAMINO-DIPHENYLMETHANE
25322-69-4 1-5
POLYPROPYLENE GLYCOL
7631-86-9 1-5
AMORPHOUS SILICA
1344-28-1 0.1 - 1
ALUMINUM OXIDES
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties No information available
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Hydrogen cyanide. Ammonia.
Aldehydes.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
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7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 STEL:
TITANIUM DIOXIDE (TOTAL
15 mg/m3 20 mg/m3
DUST)
TWA: 1 mg/m3 TWA: 10 mg/m3 TWA: 5 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3
ALUMINUM OXIDES
mg/m3 TWA: 15 mg/m3
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection Safety glasses with side-shields
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point Not applicable
Boiling Point/Range No information available.0.0
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.12514
Density 9.36282
VOC Content (lbs/gal) .099
% Volatile by Weight 1.0630
% Volatile by Volume 1.3254
10. STABILITY AND REACTIVITY
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10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks. Epoxy
constituents. Isocyanates.
Incompatible Products Strong oxidizing agents. Acids. Possibility of Hazardous None under normal processing
Bases. Metals . Hypochlorites. Reactions
Peroxides. Hydroxyl
Compounds.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
POLYOXYPROPYLENEDIAMINE 242 mg/kg ( Rat ) 360 mg/kg ( Rabbit )
DIETHYLTOLUENEDIAMINE 472 mg/kg ( Rat )
TITANIUM DIOXIDE (TOTAL DUST) 10000 mg/kg ( Rat )
POTASSIUM ALUMINOSILICATE 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.4 mg/L ( Rat ) 1 h
POLYPROPYLENE GLYCOL 2 g/kg ( Rat )
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
ALUMINUM OXIDES 5000 mg/kg ( Rat )
Irritation The absorption of this product into the body may lead to the formation of methaemoglobine
that, in sufficient concentration, causes cyanosis
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
TITANIUM DIOXIDE (TOTAL Group 2B X
DUST)
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Eyes, Lungs, Respiratory system.
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
POTASSIUM EC50 = 18 mg/L 96 h LC50= 1800 mg/L Brachydanio EC50 3200 - 5600 mg/L 8 h EC50 1000 - 1800 mg/L 48 h
ALUMINOSILICATE rerio 96 h LC50 3200 - 5600 EC50 = 1550 mg/L 16 h
mg/L Oryzias latipes 96 h
LC50 1800 - 3200 mg/L
Poecilia reticulata 96 h
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Component Freshwater Algae Freshwater Fish Microtox Water Flea
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name UN3066,PAINT,8,PGIII,ERG 153
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
U.S. Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
CERCLA
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TITANIUM DIOXIDE (TOTAL X X X X
DUST)
AMORPHOUS SILICA X X
ALUMINUM OXIDES X X X X
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Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
D2B Toxic materials
E Corrosive material
Component NPRI
ALUMINUM OXIDES Part 1, Group 1 Substance (fibrous form)
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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