MATERIAL SAFETY DATA SHEET
ICI Paints North America
DEVTHANE 379UVA CLEAR ALIPHATIC URETHANE FINISH
prepared 09/24/07
HAZARDS IDENTIFICATION (ANSI Section 3) explosion-proof equipment. Spills may be collected with absorbent materials. Use non-sparking
tools. Evacuate all unnecessary personnel. Place collected material in proper container. Spilled
Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion.
material is extremely slippery. Complete personal protective equipment must be used during cleanup.
Effects of overexposure :
Large spills - shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage
Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to. Inhalation of spray mist vessels. Use absorbent to pick up excess residue. Keep salvageable material and rinse water out of
may cause irritation of respiratory tract. Mucous membrane irritation, fatigue, drowsiness, sewers and water courses. Small spills - use absorbent to pick up residue and dispose of properly.
dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, coughing,
central nervous system depression, intoxication, anesthetic effect or narcosis, difficulty of
HANDLING AND STORAGE (ANSI Section 7)
15885 Sprague Road Strongsville, Ohio 44136
breathing, allergic response, tremors, pulmonary edema, loss of consciousness, death. Possible
Handling and storage : Store below 80f. Store below 100f (38c). Keep away from heat, sparks and
sensitization to respiratory tract.
open flame. Store in original container. Keep away from direct sunlight, heat and all sources of
Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, severe
ignition. Keep container tightly closed in a well-ventilated area.
skin irritation. Possible sensitization to skin.
Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of
Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision,
children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after
tearing of eyes, redness of eyes, severe eye irritation, corneal injury.
handling, especially before eating or smoking. Keep containers tightly closed and upright when not
Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into
in use. Empty containers may contain hazardous residues. Ground equipment when transferring to
lungs, mouth and throat irritation, drowsiness, dizziness and/or lightheadedness, headache,
prevent accumulation of static charge.
uncoordination, nausea, vomiting, diarrhea, gastro-intestinal disturbances, abdominal pain,
central nervous system depression, anesthetic effect or narcosis, pulmonary edema, loss of
EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)
consciousness.
Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, kidney disorders, liver Respiratory protection : Respiratory protection is required for use in isocyanate containing
disorders. environments. Consider type of application and environmental concentrations when selecting
respiratory protection. Observe governmental regulations for respirator use. (29 CFR
FIRST-AID MEASURES (ANSI Section 4) 1910.134(OSHA))(Canadian z94.4) The use of positive pressure supplied air respirator is
mandatory when the airborne isocyanate concentrations are not known. Note: isocyanate based
Inhalation : Remove to fresh air. Restore and support continued breathing. Get emergency medical
materials have been determined to cause allergic sensitization in humans. Avoid inhalation and
attention. Have trained person give oxygen if necessary. Get medical help for any breathing
dermal (skin) contact with the uncured material.
difficulty.
Ventilation : Provide dilution ventilation or local exhaust to prevent build-up of vapors. Use explosion-
Skin contact : Wash thoroughly with soap and water. If any product remains, gently rub petroleum
EMERGENCY TELEPHONE NO. (800) 545-2643
proof equipment. Use non-sparking equipment.
jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be needed. Remove
Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious
contaminated clothing. Wash contaminated clothing before re-use.
gloves, impervious clothing, face shield, boots.
Eye contact : Flush immediately with large amounts of water, especially under lids for at least 15
minutes. If irritation or other effects persist, obtain medical treatment.
STABILITY AND REACTIVITY (ANSI Section 10)
Ingestion : If swallowed, obtain medical treatment immediately.
Under normal conditions : Stable see section 5 fire fighting measures
FIRE-FIGHTING MEASURES (ANSI Section 5) Materials to avoid : Oxidizers, acids, reducing agents, bases, amines, water, hydrogen chloride,
peroxides, nitric acid, vinyl polymers, alcohols, metal compounds, combustible materials, hydrogen
Fire extinguishing media : Dry chemical or foam water fog. Carbon dioxide. Closed containers may
fluoride, magnesium.
explode when exposed to extreme heat or fire. Vapors may ignite explosively at ambient
Conditions to avoid : Elevated temperatures, moisture, contact with oxidizing agent, sparks, open
temperatures. Vapors are heavier than air and may travel long distances to a source of ignition and
flame, ignition sources.
flash back. Vapors can form explosive mixtures in air at elevated temperatures. Closed containers
Hazardous polymerization : Will not occur
may burst if exposed to extreme heat or fire. May decompose under fire conditions emitting irritant
and/or toxic gases.
TOXICOLOGICAL INFORMATION (ANSI Section 11)
Fire fighting procedures : Water may be used to cool and protect exposed containers. Firefighters
should use full protective clothing, eye protection, and self-contained breathing apparatus. Supplemental health information : Contains a chemical that may be absorbed through skin. Free
Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of diisocyanate may cause allergic reaction in susceptible persons. Notice - reports have associated
nitrogen, toxic gases, acrylic monomers. repeated and prolonged occupational overexposure to solvents with permanent brain and
nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal. Other effects of overexposure may include toxicity to liver,
ACCIDENTAL RELEASE MEASURES (ANSI Section 6)
379CLEAR
kidney, central nervous system, blood.
Steps to be taken in case material is released or spilled : Comply with all applicable health and
environmental regulations. Eliminate all sources of ignition. Ventilate area. Ventilate area with
The information contained herein is based on data available at the time of preparation of this data sheet which ICI Paints believes to be reliable. However, no warranty is expressed or implied regarding the accuracy of this
data. ICI Paints shall not be responsible for the use of this information, or of any product, method or apparatus mentioned and you must make your own determination of its suitability and completeness for your own use,
for the protection of the environment, and the health and safety of your employees and the users of this material.
Complies with OSHA hazard communication standard 29CFR1910.1200.
ECOLOGICAL INFORMATION (ANSI Section 12)
Carcinogenicity : The international agency for research on cancer (IARC) has evaluated ethylbenzene and
classified it as a possible human carcinogen (group 2b) based on sufficient evidence for carcinogenicity No ecological testing has been done by ICI paints on this product as a whole.
in experimental animals, but inadequate evidence for cancer in exposed humans. In a 2 year inhalation
study conducted by the national toxicology program (NTP), ethylbenzene vapor at 750 ppm produced
DISPOSAL CONSIDERATIONS (ANSI Section 13)
kidney and testicular tumors in rats and lung and liver tumors in mice. Genetic toxicity studies showed
no genotoxic effects. The relevance of these results to humans is not known. Waste disposal : Dispose in accordance with all applicable regulations. Avoid discharge to natural waters.
Reproductive effects : High exposures to xylene in some animal studies, often at maternally toxic levels, have
affected embryo/fetal development. The significance of this finding to humans is not known. REGULATORY INFORMATION (ANSI Section 15)
Mutagenicity : No mutagenic effects are anticipated As of the date of this MSDS, all of the components in this product are listed (or are otherwise exempt from
Teratogenicity : No teratogenic effects are anticipated listing) on the TSCA inventory. This product has been classified in accordance with the hazard criteria of the
CPR (controlled products regulations) and the MSDS contains all the information required by the CPR.
Physical Data (ANSI Sections 1, 9, and 14)
Product VOC % Volatile Flash Boiling
Description Wt. / Gal. HMIS DOT, proper shipping name
Code gr. / ltr. by Volume Point Range
379B0020 devthane 379hs aliphatic urethane flat finish - base 8.81 412.94 48.48 80 f 212-595 330 UN1263, paint, 3, PGIII
379B0036 devthane 379 aliphatic urethane gloss finish - base 8.15 450.01 50.91 80 f 147-468 330 UN1263, paint, 3, PGIII
379C0910 devthane 379 hs converter 9.40 112.85 13.00 135 f 293-293 *321 UN1866, resin solution, combustible liquid, PGIII
Ingredients Product Codes with % by Weight (ANSI Section 2)
Chemical Name Common Name CAS. No. 379B0020 379B0036 379C0910
benzene, ethyl- ethylbenzene 100-41-4 .1-1.0
1,3-dioxolan-2-one, 4-methyl- propylene carbonate 108-32-7 1-5
4-heptanone, 2,6-dimethyl- diisobutyl ketone 108-83-8 5-10 1-5
2-heptanone methyl amyl ketone 110-43-0 5-10 10-20
silica gel, precipitated, crystalline-free silica, gel, amorphous 112926-00-8 10-20
acetic acid, butyl ester butyl acetate 123-86-4 10-20 20-30 5-10
benzene, dimethyl- xylene 1330-20-7 .1-1.0 .1-1.0
2-heptanone, 4,6-dimethyl- 4,6-dimethyl-2-heptanone 19549-80-5 1-5 1-5
hexane, 1,6-diisocyanato-, homopolymer aliphatic polyisocyanate 28182-81-2 90-95
ethanol ethyl alcohol 64-17-5 .1-1.0
solvent naphtha (petroleum), light aromatic light aromatic solvent naphtha 64742-95-6 1-5
castor oil castor oil, raw 8001-79-4 1-5
hexane, 1,6-diisocyanato- hexamethylene diisocyanate 822-06-0 .1-1.0
benzene,1,2,4-trimethyl- pseudocumene 95-63-6 .1-1.0 .1-1.0 1-5
acrylic resin acrylic resin Sup. Conf. 30-40 50-60
Chemical Hazard Data (ANSI Sections 2, 8, 11, and 15)
ACGIH-TLV OSHA-PEL S.R.
S2 S3 CC
Std.
Common Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O
ethylbenzene 100-41-4 100 ppm 125 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n y n
propylene carbonate 108-32-7 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
diisobutyl ketone 108-83-8 25 ppm not est. not est. not est. 50 ppm not est. not est. not est. not est. n n n n n n n n
methyl amyl ketone 110-43-0 50 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n n n n n n n n
silica, gel, amorphous 112926-00-8 not est. not est. not est. not est. 6 mg/m3 not est. not est. not est. not est. n n n n n n n n
butyl acetate 123-86-4 150 ppm 200 ppm not est. not est. 150 ppm not est. not est. not est. not est. n n y n n n n n
xylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n n
4,6-dimethyl-2-heptanone 19549-80-5 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
aliphatic polyisocyanate 28182-81-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant
C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant
should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:
even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no
Form: 379CLEAR, Page 2 of 3, prepared 09/24/07
Chemical Hazard Data (Continued) (ANSI Sections 2, 8, 11, and 15)
ACGIH-TLV OSHA-PEL S.R.
S2 S3 CC
Std.
Common Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O
light aromatic solvent naphtha 64742-95-6 not est. not est. not est. not est. 500x ppm not est. not est. not est. not est. n n n n n n n n
castor oil, raw 8001-79-4 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
hexamethylene diisocyanate 822-06-0 0.005 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y y y n n n n
pseudocumene 95-63-6 25 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y n n n n n n
Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant
C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant
should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:
even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no
Form: 379CLEAR, Page 3 of 3, prepared 09/24/07
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