MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND SUPPLIER
Product name: SilvaShield?Injectable Tree Insecticide
Other names: None
Product code: Not available
Chemical group: Guanidine
Recommended use: For direct injection into trees for the systemic control of insect pests
Formulation: Soluble Concentrate (SL)
Supplier: Bayer Environmental Science ?A Business Operation of Bayer CropScience Pty Ltd
ABN 87 000 226 022
Address: 391 - 393 Tooronga Road, East Hawthorn
Victoria 3123, Australia
Telephone: (03) 9248 6888
Facsimile: (03) 9248 6800
Website: www.bayeres.com.au
Contact: Technical Manager (03) 9248 6888
Emergency
Telephone Number: 1800 033 111 ?Orica SH&E Shared Services
2. HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE - NON-DANGEROUS GOOD
Irritating to eyes.
Hazard designation: Hazardous (National Occupational Health and Safety Commission - NOHSC)
Risk phrases: R36 ?Irritating to eyes
Safety phrases: See Sections 4, 5, 6, 7, 8, 9, 13
ADG classification: Not "dangerous goods" for transport by road or rail according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail.
SUSDP Schedule 5 (Standard for the Uniform Scheduling of Drugs and Poisons)
classification:
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients: CAS Number: Concentration (g/L):
Imidacloprid [138261-41-3] 200
Propylene carbonate [108-32-7] 235
Other ingredients (non hazardous) ~730
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MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
4. FIRST AID MEASURES
If poisoning occurs, immediately contact a doctor or Poisons Information Centre (telephone 13 11 26), and
follow the advice given. Show this Material Safety Data Sheet to a doctor.
Inhalation: Remove patient to fresh air. Keep rested and warm.
Skin contact: Remove patient's clothing and wash skin thoroughly with soap and water. If available,
wash with polyethylenglykol 400 followed by water.
Eye contact: Irrigate eyes immediately with water for 15 minutes. Seek medical advice if irritation
occurs.
Ingestion: Give plenty of water to drink. Never give anything by mouth to an unconscious person.
First Aid Facilities: Provide washing facilities in the workplace.
Symptoms: Symptoms of intoxication that may arise if the product is mishandled include nausea,
abdominal pain and diarrhoea. Muscular cramps, apathetic state, depressed muscular
tone, respiratory disturbance and trembling are also possible in severe cases of poisoning.
Medical attention: Treatment
Basic aid, decontamination, symptomatic treatment.
Note for physicians
Check blood pressure and pulse rate frequently since bradycardia and hypotension are
possible. Provide supportive measures for respiratory and cardiac function. Give artificial
respiration if signs of paralysis appear. Additional therapeutic measures involve
elimination of the substance from the body or acceleration of its excretion (gastro-lavage,
saline laxatives). No specific antidote known.
Contraindications: Absorption promoting agents such as alcoholic beverages and milk.
Oils and fats are of no special significance due to the low liposolubility of the active
ingredient.
5. FIRE FIGHTING MEASURES
Extinguishing media: Sprayed water jet, foam, extinguishing powder, carbon dioxide, and sand.
Hazards from In the event of fire, the formation of hydrogen chloride, hydrogen cyanide, carbon
combustion monoxide and nitrogen oxides must be anticipated. Do not breathe fumes.
products:
Precautions for fire Fight fire in the early stages if safe to do so. Wear respiratory protection.
fighters: Well ventilated areas: wear full face mask with combination filter eg., ABEK-P2 (offers no
protection from carbon monoxide).
Enclosed premises: wear respirator with independent air supply.
Contain firefighting water. If at all possible do not allow firefighting water to enter drains
and waterways.
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MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
6. ACCIDENTAL RELEASE MEASURES
Prevent spill from spreading or entering waterways or drains. Take up with absorbent material such as sawdust,
peat or binding agent for chemicals. Fill material along with any contaminated soil etc. into sealable containers.
Clean affected area with an aqueous detergent and a small amount of water. On completion of clean-up remove and
wash all protective clothing and equipment with detergent and water. Any heavily contaminated clothing should be
placed in a plastic garbage bag and placed in a sealable drum. Do not smoke, eat or drink during clean-up
operation.
7. HANDLING AND STORAGE
Handling: Keep out of reach of children. Avoid contact with the eyes and skin.
Storage: Store in original container in a cool, well ventilated area. Do not store for prolonged
periods in direct sunlight. Do not store near any material intended for use or consumption
by humans or animals.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure standards: NOHSC exposure standards have not been established for any ingredient in this product.
Engineering controls: No engineering controls are required for the normal use of this product according to label.
Personal Protective When preparing product for use, wear cotton overalls buttoned to the neck and wrist,
Equipment: elbow-length PVC gloves and goggles. Wash hands after use. After each day's use, wash
gloves, goggles and contaminated clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear pale yellow-amber liquid (soluble concentrate)
Odour: Slight garlic odour
Vapour pressure: Not available
Vapour density: Not available
Boiling point: Not available
Solubility: Soluble
Density: 1.163 ?1.173 g/mL at 20 癈
pH: 6.0 ?8.0 (1% in distilled water)
97 癈
Flash Point:
Flammability Not available
(explosive) limits:
Auto-ignition Not available
temperature:
Octanol/water Imidacloprid: Log Pow = 0.57 (21?C)
partition coefficient:
Formulation: Soluble concentrate
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MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
10. STABILITY AND REACTIVITY
Chemical stability: Product is stable. Not flammable under normal conditions of use.
Avoid strong oxidising agents and sources of ignition.
Conditions to avoid: None particularly recommended
Incompatible Avoid strong oxidising agents.
materials:
Hazardous In the event of fire, the formation of hydrogen chloride, hydrogen cyanide, carbon
decomposition monoxide and nitrogen oxides must be anticipated. Do not breathe fumes.
products:
11. TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
Inhalation: Not expected to be harmful if inhaled.
Skin contact: Unlikely to cause skin irritation.
Eye contact: Irritating to the eyes.
Ingestion: Harmful if swallowed.
ANIMAL TOXICITY DATA ?PRODUCT:
Acute:
Oral toxicity: LD50 rat: = 2500 mg/kg i.e. practically non-toxic
Dermal toxicity: LD50 rat: >4000 mg/kg i.e. practically non-toxic
Inhalation toxicity: LC50 rat: approx 6000 mg/cubic metre i.e. practically non-toxic
Skin irritation: Not irritating ?rabbit
Eye irritation: Slightly irritating ?rabbit
Sensitisation: Non-sensitising
Chronic:
Animal studies show no evidence of carcinogenic, mutagenic or teratogenic effects.
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MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
12. ECOLOGICAL INFORMATION ?ACTIVE INGREDIENT
Imidacloprid is toxic to certain aquatic species. Dangerous to bees.
Do not contaminate ponds, waterways or drains with the product or used containers.
Ecotoxicity: Imidacloprid:
Fish toxicity:
LC50: 237 mg/L (96 h); golden orfe (Leuciscus idus melanotis)
LC50: 211 mg/L (96 h); rainbow trout (Oncorhynchus mykiss)
Aquatic invertebrate toxicity:
EC50: 85 mg/L (48 h) Daphnia magna
Algae toxicity:
EC50: > 100 mg/L (72 h); green alga (Pseudokirchneriella subcapitata)
Bacteria toxicity:
EC50: > 10000 mg/L; activated sludge (OECD 209)
Bird toxicity:
Acute oral LD50: 31 mg/kg; Japanese quail
Acute oral LD50: 152 mg/kg; bobwhite quail
Environmental fate, Imidacloprid shows a medium adsorption to soil. Classified as immobile in soil. Not
persistence and expected to leach.
degradation:
13. DISPOSAL CONSIDERATIONS
1) After intended use:
Rinse container before disposal and pour rinsate around the base of trees which have been treated. DO NOT
dispose of undiluted chemicals on site. Dispose of at a local authority landfill. If no landfill is available, bury the
containers below 500 mm in a disposal pit specifically marked and set up for this purpose clear of waterways,
desirable vegetation and tree roots. Empty containers and product should not be burnt.
2) After spill or accident:
Dispose of containers at an approved local waste disposal site.
14. TRANSPORT INFORMATION
UN number: Not applicable
Proper shipping Not applicable
name:
Class and Not "dangerous goods" for transport by road or rail according to the Australian Code for the
Subsidiary Risk: Transport of Dangerous Goods by Road and Rail.
Packing Group: Not applicable
EPG: Not applicable
Hazchem code: Not applicable
15. REGULATORY INFORMATION
Not yet registered according to the Agricultural and Veterinary Chemicals Act 1988
Australian Pesticides and Veterinary Medicines Authority Approval Number: 62475
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MATERIAL SAFETY DATA SHEET
Date of Issue: September 11th, 2008
16. OTHER INFORMATION
Trademark SilvaShield?is a Registered Trademark of Bayer
information:
Preparation First edition
information:
Data sources: Bayer CropScience Pty Ltd product safety data and published data
This MSDS summarises our best knowledge of the health and safety hazard information of the product and how to
safely handle and use the product in the workplace. Each user should read this MSDS and consider the information
in the context of how the product will be handled and used in the workplace including in conjunction with other
products.
If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user
should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our
customers and is also available on request.
END OF MSDS
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