Material Safety Data Sheet
Foam-It Series MSDS No. 482
Date Of Preparation: January 4, 2010 Revision: 0004
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Foam-It Series Part A
General Use: Polyurethane Foam
Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA 18042
Phone (610)252-5800, FAX (610)252-6200
Emergency Contact: Chem-Tel
Domestic 800-255-3924 International 813-248-0585
Section 2- Hazards Identification
Hazard Designation:
Europe Canada
HMIS
2
H
1
F
Xn = Harmful 1
R
Information pertaining to particular dangers
R20: Harmful by inhalation
R36/37/38: Irritating to eyes, respiratory system and skin
R40: Limited evidence of a carcinogenic effect
R48/20: Harmful; danger of serious damage to health by prolonged exposure through inhalation
Classified according to Articles 6 & 7of Directive 1999/45/EC
Section 3 - Composition / Information on Ingredients
Component ACGIH TWA OSHA PEL Hazard Designation
Weight Percent
(%)
50-60
Polymethylene polyphenyl None Established None Established None Established
isocyanates
CAS Number: 9016-87-9
EINECS Number: Not Classified
4,4' Methylene
0.005 ppm 0.02 ppm 40-50
bis(phenylisocyanate) Xn
(MDI)
CAS Number: 101-68-8
EINECS Number: 202-966-0
Section 4 - First Aid Measures
Inhalation: Remove source(s) of contamination and move victim to fresh air. If breathing has
stopped, give artificial respiration, then oxygen if needed. Contact physician immediately.
Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention.
Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove
contaminated clothing and launder before reuse; seek medical attention if rash develops.
Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician
immediately
After first aid, get appropriate in-plant, paramedic, or community medical support.
MSDS No. 482 Revision: 0004
Section 5 - Fire-Fighting Measures
Flash Point: 262?(128?br>
F C) NFPA
Flash Point Method: COC LEL: Not Established UEL: Not Established
Flammability Classification: Non-Flammable 1
Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam 2 1
Unusual Fire or Explosion Hazards: Hazardous decomposition products may
0
be formed. Avoid water contamination in closed containers or confined areas as
exothermic heat and carbon dioxide can evolve.
Fire-Fighting Instructions: Fire fighters should wear self-contained breathing apparatus. Do not
release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products,
wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure-
demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Only properly protected personnel should remain in the spill area; dike
and contain spill; absorb or scrape up excess into suitable container for disposal; wash area with
dilute ammonia solution. Stop or reduce discharge if it can be done safely.
Section 7 - Handling and Storage
Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact
with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper
respiratory equipment. Avoid moisture contamination. Reseal partial containers. Use good
general housekeeping procedures.
Storage Requirements: Store in cool dry, well-ventilated area.
Section 8 - Exposure Controls / Personal Protection
Respiratory Protection: Follow OSHA respirator regulations 29 CFR 1910.134 and European
Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator.
Warning! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If
respirators are used, OSHA requires a written respiratory protection program that includes at
least: medical certification, training, fit-testing, periodic environmental monitoring, maintenance,
inspection, cleaning, and convenient, sanitary storage areas
Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or
repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye-
and face-protection regulations 29 CFR 1910.133 and European Standard EN166. Contact
lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in
conjunction with contact lenses.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after
using this material, especially before eating, drinking, smoking, using the toilet, or applying
cosmetics
Page 2
MSDS No. 482 Revision: 0004
Section 9 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Reacts with water
Appearance : Dark Brown Boiling Point: 392癋(200癈)
Odor : Musty odor % Volatile: Nil
Vapor Pressure: <0.00001 @ 25? C Freezing/Melting Point: None Determined
Vapor Density (Air=1): None Determined Viscosity: 1 poise
Specific Gravity (H2O=1, at 4 ?1.2
C): Evaporation Rate: Not Applicable
Section 10 - Stability and Reactivity
Stability: These products are stable at room temperature in closed containers under normal
storage and handling conditions.
Polymerization: Hazardous polymerization can occur.
Chemical Incompatibilities: Strong bases, water, amines, alcohols.
Conditions to Avoid: Avoid contamination with water and other materials that react with
Isocyanates.
Hazardous Decomposition Products: MDI vapors, hydrogen cyanide gas, oxides of nitrogen,
carbon monoxide and carbon dioxide
Section 11- Toxicological Information
Hazardous Component LD50 Oral LC50 Inhalation
Rat: 178 mg/m3
4,4' Methylene Mouse: 2200 mg/kg
bis(phenylisocyanate) Rat: 9200 mg/kg
(MDI)
Section 12 - Ecological Information
For MDI:
Aquatic: Rapidly hydrolyzes to form an insoluble crust. Terrestrial: Will bind with moist
soil no leaching will occur. Atmospheric: Remains in the vapor phase and half life is 32
hours. Will not biodegrade.
Section 13 - Disposal Considerations
Disposal: Must be disposed of in accordance with local regulations.
Section 14 - Transport Information
IMDG
DOT IATA
Not Regulated Not Regulated Not Regulated
Section 15 - Regulatory Information
United States EPA Regulations:
Clean Air Act
SOCMI Chemical: 4, 4' Methylene bis(phenylisocyanate) Hap Code: XOV
This product contains the following chemicals that are subject to release reporting requirements
under section 313 of SARA Title III.
Chemical Name CAS # % by Weight
4, 4' Methylene bis(phenylisocyanate) 101-68-8 60.0 Max.
Polymethylene polyphenyl isocyanate 9016-87-9 50.0 Max.
Page 3
MSDS No. 482 Revision: 0004
Section 15 - Regulatory Information (Continued)
TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA
Inventory.
California Proposition 65: These products do not intentionally contain any chemicals which have
been identified by the state of California to cause cancer, birth defects or other reproductive
harm.
Canadian Regulations;
WHMIS Identification: D2A, D2B
CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): Listed on CDSL
Labeling according to EEC Directive
Risk Phrases Symbol(s) Required for EU Label Safety Phrases
R20: Harmful by inhalation S1/2: Keep locked up and
R36/37/38: Irritating to eyes, out of reach of children
respiratory system and skin S23: Do not breath vapors
R40: Limited evidence of a S36/37: Wear suitable
carcinogenic effect protective equipment.
R48/20: Harmful; danger of S45: In case of an accident
= Harmful)
(Xn
serious damage to health by or if you feel sick , seek
prolonged exposure through medical attention
inhalation
16 - Other Information
Disclaimer: The information contained in this MSDS is considered accurate as of the version
date. However, no warranty is expressed or implied regarding the accuracy of the data. Since
the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to
determine the suitability of the product for its intended application and assumes all risk and
liability for its safe use.
This Material Safety Data Sheet is prepared to comply with the United States Occupational
Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR
1910.1200), the Canadian Workplace Hazardous Materials Information System (WHMIS), and
European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are
based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are
not "hazardous" per the OSHA Hazard Communication Standard (29 CFR 1910.1200), the
Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union
(EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law
(29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union
Directives.
Page 4
Material Safety Data Sheet
Foam-It Series MSDS No. 482
Date Of Preparation: January 4, 2010 Revision: 0004
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Foam-It Series Part B
General Use: Polyurethane Foam
Manufacturer: Smooth-On Inc., 2000 St. John St., Easton PA 18042
Phone (610)252-5800, FAX (610)252-6200
Emergency Contact: Chem-Tel
Domestic 800-255-3924 International 813-248-0585
Section 2- Hazards Identification
Not hazardous according to United States Occupational Safety and Health HMIS
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200) and 1
H
Council directive 1999/45/EC and its subsequent amendments 1
F
0
R
Section 3 - Composition / Information on Ingredients
No hazardous ingredients
Section 4 - First Aid Measures
Inhalation: Remove source(s) of contamination and move victim to fresh air.
Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention.
Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove
contaminated clothing and launder before reuse.
Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician
immediately
After first aid, get appropriate in-plant, paramedic, or community medical support.
Section 5 - Fire-Fighting Measures
Flash Point: 262?(128?br>
F C) NFPA
Flash Point Method: PMCC
Flammability Classification: Non-Flammable 1
Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam
1 0
Unusual Fire or Explosion Hazards: None
Fire-Fighting Instructions: Fire fighters should wear self-contained breathing 0
apparatus. Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition
products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in
pressure-demand or positive-pressure mode.
MSDS No. 482 Revision: 0004
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Dike and contain spill; absorb or scrape up excess into suitable
container for disposal. Stop or reduce discharge if it can be done safely.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact
with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper
respiratory equipment. Use good general housekeeping procedures.
Storage Requirements: Store in cool dry, well-ventilated area.
Section 8 - Exposure Controls / Personal Protection
Respiratory Protection: Follow OSHA respirator regulations 29 CFR 1910.134 and European
Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator.
Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or
repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye-
and face-protection regulations 29 CFR 1910.133 and European Standard EN166. Contact
lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in
conjunction with contact lenses.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after
using this material, especially before eating, drinking, smoking, using the toilet, or applying
cosmetics
Section 9 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Negligible:
Appearance: Clear Straw liquid Boiling Point: None (Polymeric Resin)
Odor: Mild odor % Volatile: Nil
Vapor Pressure: None (Polymeric Resin) Freezing/Melting Point: None Determined
Vapor Density (Air=1): >1 Viscosity: 7.5 poise
Specific Gravity (H2O=1, at 4 ?1.04
C): Evaporation Rate: None (Polymeric Resin)
Section 10 - Stability and Reactivity
Stability: These products are stable at room temperature in closed containers under normal
storage and handling conditions.
Polymerization: Hazardous polymerization can not occur.
Chemical Incompatibilities: Strong acids and oxidizers.
Conditions to Avoid: Avoid contamination with water and other materials that react with amines.
Thermal Decomposition Products: Oxides of nitrogen, carbon monoxide and carbon dioxide
Page 6
MSDS No. 482 Revision: 0004
Section 11- Toxicological Information
Toxicity Data:
Reproductive Toxicity: None Established
Acute Inhalation Effects: None
Mutagenicity: None Established
established
Teratogenicity: None Established
Acute Oral Effects: None
Sensitization: None Established
Established
Section 12 - Ecological Information
None Established
Section 13 - Disposal Considerations
Disposal: These materials must be disposed of in accordance with applicable local regulations.
Section 14 - Transport Information
IMDG
DOT IATA
Not Regulated Not Regulated Not Regulated
Section 15 - Regulatory Information
US TSCA Inventory Status (40 CFR 710): All components of this product are listed on the
TSCA inventory.
California Proposition 65: These products do not intentionally contain any chemicals which have
been identified by the state of California to cause cancer, birth defects or other reproductive
harm
WHMIS Identification: Not controlled
CDSL/NDL (Canadian Domestic Substance List/Non Domestic Substance List): All are Listed
Labeling according to EEC Directive
No special packaging or labeling requirements..
Page 7
MSDS No. 482 Revision: 0004
16 - Other Information
Disclaimer: The information contained in this MSDS is considered accurate as of the version
date. However, no warranty is expressed or implied regarding the accuracy of the data. Since
the use of this product is not within the control of Smooth-On Inc., it is the user's obligation to
determine the suitability of the product for its intended application and assumes all risk and
liability for its safe use.
This Material Safety Data Sheet is prepared to comply with the United States Occupational
Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR
1910.1200), the Canadian Workplace Hazardous Materials Information System (WHMIS), and
European Union Directive 1907/2006/EEC (REACH). Hazard symbols and risk phrases are
based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are
not "hazardous" per the OSHA Hazard Communication Standard (29 CFR 1910.1200), the
Canadian Workplace Hazardous Materials Information System (WHMIS) or the European Union
(EU/EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal Law
(29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union
Directives.
Page 8
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