Material Safety Data Sheet
Section 1: Product and Company Identification
Product Name: Bridge Deck Membrane Concrete Primer - Part A
Sold By: Bridge Preservation
87 Shawnee Avenue
Kansas City, KS 66105
913.321.9000
Spill, leak, fire, exposure, or accident, call CHEMTREC day or night
FOR CHEMICAL
Domestic North America 800.424.9300 International 703.527.3887
EMERGENCY
Fax Phone: 913.321.1490
TSCA Inventory: All components of this product are included, or are exempt from inclusion, in the EPA Toxic Substance
Control Act (TSCA) Chemical Substance Inventory.
Canadian DSL: All components of this product are included, or are exempt from inclusion, in the Canadian Domestic
Substance List (DSL).
Section 2: Composition/Information on Ingredients
Hazardous Components CAS# ACGIH TLV OSHA PEL % by Wgt
4,4'-Diphenylmethane-Diisocyanate 101-68-8 10 ppm 005 ppm
Petroleum Hydrocarbon 64742-95 Not Determined Not Determined
Section 3: Hazards Identification
Emergency Overview:
Routes of Entry: Route Entry Risk
Possible
Inhalation
Possible
Ingestion
Skin Contact Possible
Eye Contact Possible
Potential Health Effects: Inhalation May cause nausea and respiratory tract irritation. May cause respiratory sensitization
in susceptible individuals.
Ingestion No significant signs or symptoms of any adverse health hazards.
Skin Contact Product is a slight skin irritant. May cause swelling and redness.
Eye Contact Mild eye irritant. Vapors slightly uncomfortable. Splashes irritating and painful.
Acute Health Hazards: No information is available on the acute health hazards of this product. Based upon data from
testing of similar products, no significant effects are expected.
Chronic Health Hazards: If misted or at high concentrations, may cause pallor, nausea, anesthetic or narcotic effects.
Medical Conditions Skin and eye sensitization. Depending on individual skin sensitivity, chronic or prolonged exposure
Generally Aggravated by
may result in irritation, blistering, burning and peeling of skin layers.
Exposure:
Carcinogenicity: No data No data No data No data
OSHA: ACGIH: NTP: IARC:
Other:
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 1 of 6
Section 4: First Aid Measures
Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning
sensation develops, seek medical attention.
Skin Contact: Remove from skin immediately. Rinse with clean water for 20-30 minutes. Use soapy water if
needed. If redness, itching, or a burning sensation develops, seek medical attention.
Ingestion: Do NOT induce vomiting! Dilute with water and seek medical attention immediately.
Inhalation: Move victim to fresh air immediately. Give oxygen and seek medical attention.
Section 5: Fire-Fighting Measures
Flammable Limits: Not determined
Flash Point, (Method 145?Fahrenheit (Pensky Marten Closed)
Used):
Autoignition Temperature:
NFPA Hazard Rating:
2 Hazard Scale Protective Equipment
Health:
0=LEAST A=SAFETY GLASSES
2
Flammability:
1=SLIGHT B=SAFETY GLASSES, GLOVES
0
Reactivity: 2=MODERATE C=SAFETY GLASSES, GLOVES AND APRON
3=HIGH D= SAFETY GLASSES, GLOVES , APRON and
B
Other: 4=EXTREME RESPIRATOR
HMIS Hazard Rating:
2
Health:
2
Flammability:
0
Reactivity:
B
Protection:
Extinguishing Media: Foam/Carbon dioxide/Dry chemical/Water fog
Special Fire Fighting Remove all ignition sources. Wear self-contained breathing apparatus and complete personal
Procedures:
protective equipment when entering confined areas where potential for exposure to vapors or
products exist.
Unusual Fire and Closed containers may rupture due to build-up of pressure when exposed to extreme heat.
Explosion Hazards:
Hazardous Decomposition
Products:
Section 6: Accidental Release Measures
Accidental Release Avoid contact with material. Persons not wearing appropriate protective equipment should be
Measures:
excluded until the spill is cleaned up. Stop spill at source, pump liquid to salvage container.
Remaining liquid may be taken up on clay, diatomaceous earth, or other absorbent. Treat with 3-8%
concentration of ammonium hydroxide or 5-10% sodium carbonate. Add 10 parts neutralizing
solution/part isocyanate. Let stand 48 hours.
Section 7: Handling and Storage
Handling & Storage Prevent all skin and eye contact. Avoid breathing vapors. Re-seal partially used containers. Wash
Precautions:
with soap and water before eating or drinking. Protect from moisture contamination. Exothermic
generation of carbon dioxide may cause dangerous pressure. Keep away from all ignitable sources
as well as extreme heat. Do not expose to excessive moisture.
Section 8: Exposure Control/Personal Protection
Ventilation: Adequate ventilation required. Local exhaust may be required in some areas. Special exhausting generally not
required. Mechanical exhaust usually adequate.
Respiratory Protection: Respiratory masks should be worn at all times when adequate ventilation does not exist. A NIOSH/MSHA
respirator is acceptable.
Eye Protection: Chemical tight goggles; full face shield if splashing is possible.
Skin Protection: Coveralls and impervious foot covering is recommended.
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 2 of 6
Other Protective Clothing Use impervious gloves, neoprene or rubber.
or Equipment:
Work/ Hygienic Practices: Good air flow in working area. Eyewash station and safety shower should be available. Gloves and respiratory
equipment should be worn at all times.
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 3 of 6
Section 9: Physical and Chemical Properties
Clear Liquid
Appearance:
Mild aromatic odor
Odor:
Thin liquid
Physical State:
No Data
ph As Supplied:
No Data
ph (Other):
Boiling Point: >300?Fahrenheit
Not determined
Melting Point:
No Data
Freezing Point:
Not determined
Vapor Pressure (mmHg):
Not determined
Vapor Density (Air=1):
Specific Gravity
1.055
(Water=1):
Evaporation Rate (Butyl
<1
Acetate=1):
Reacts
Solubility in Water:
>60%
Percent Solids by Weight:
Percent
0% 0%
By Weight: By Volume:
Volatile(grams/liter):
Volatile Organic
0% 0%
Compounds With Water: Without Water:
(VOC)(grams/liter):
30 cps
Viscosity:
Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid excessive heat, open flam, sparks and strong oxidizing agents. Protect from atmospheric
Avoid (Stability):
moisture. Replace outage with inert dry nitrogen.
Incompatibility (Materials Avoid water, acid, base (alkalis, ammonia), alcohols, metal compounds.
to Avoid):
Hazardous Decomposition Isocyanate vapors or mist, carbon dioxide, carbon monoxide, nitrogen oxides.
or Byproducts:
Hazardous Will not occur under normal circumstances.
Polymerization:
Conditions to Avoid Avoid incompatible reactants, especially strong bases, water or temperatures over 160?Centigrade.
(Polymerization):
Section 11: Toxicological Information
Toxicological Information: No Data
Section 12: Ecological Information
Ecological Information: No Data
Section 13: Disposal Considerations
Waste Disposal Method: Use excess product in an alternate beneficial application. Dispose of according to local, state and
federal regulations.
Non-regulated
RCRA Hazard Class:
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 4 of 6
Section 14: Transport Information
U.S. Department of Transportation
Proper Shipping Name: Methylene diphenyl diisocyanate blend
Hazard Class: Non-Regulated in 55 gallon drums, NOI
ID Number: None
Packing Group: III
Label Statement:
Water Transportation
Proper Shipping Name: Methylene diphenyl diisocyanate blend
Hazard Class: Non-Regulated, NOI
ID Number:
Packing Group: III
Label Statement:
Air Transportation
Proper Shipping Name: Methylene diphenyl diisocyanate blend
Hazard Class: Non-Regulated, NOI
ID Number:
Packing Group: III
Label Statement:
Other Agencies:
Section 15: Regulatory Information
U.S. Federal Regulations
TSCA (Toxic Substance Control Act): Section 12(b) Export Notification. This product contains the following chemical
substances subject to the reporting requirements of TSCA 12(b) if exported from the
United States: There are no TSCA 12(b) Chemicals in this product.
CERCLA (Comprehensive Response CERCLA section 103(a) specifically requires the person in charge of a vessel or facility
Compensation and Liability Act):
to report immediately to the National Response Center (NRC) a release of a hazardous
substance whose amount equals or exceeds the assigned RQ. The following hazardous
substances are contained in this product: Chemical Name- See Section 2
SARA Title III (Superfund Amendments This product has been reviewed according to the EPA `Hazard Categories' promulgated
and Reauthorization Act):
under Sections 311 and 312 of the Superfund Amendments and Reauthorization Act of
1986 (SARA Title III) and is considered, under applicable definitions, to meet the
following categories:
311/312 Hazard Categories: Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard: See Section 3
313 Reportable Ingredients: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372: Chemical Name- See Section 2
State Regulations: California Proposition 65. The chemicals(s) noted below and contained in this product
are known to the state of California to cause cancer, birth defects or other reproductive
harm. Unless otherwise specified in Section 2 of this MSDS, these chemicals are
present at <0.1%: There are no proposition 65 chemicals known to exist in this product.
International Regulations:
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 5 of 6
Section 16: Other Information
Other Information:
Preparation Information:
Disclaimer: To the best of our knowledge, the information contained in this MSDS is accurate. It is intended to
assist the user in his evaluation of the product's hazards, and safety precautions to be taken in its
use. The data in this MSDS relate only to the specific material designated herein. We do not assume
liability for the use of, or reliance on this information, nor do we guarantee its accuracy or
completeness.
Bridge Preservation ?009 Bridge Deck Membrane Concrete Primer - Part A MSDS
Rev: 01-01-09 Page 6 of 6
|