Material Safety Data Sheet
Page 1 of 6
MR 1165 SLOW
Isocyanate
1. PRODUCT AND COMPANY IDENTIFACTION
Product Name: MR 1165 Slow Isocyanate
NB2006139540-3 ISO
Material Type: Isocyanate
Manufacturer/Supplier: American Recycling Center, Inc.
655 Wabassee Drive
Owosso, MI 48867
24-Hour Emergency Phone Number: 989-636-4400
Customer Information Center: 989-725-5100
2. COMPOSITION/DATA ON COMPONENTS
Chemical characterization:
CAS No. Description
5873-54-1 0-(p-isocyanatobenzyl)phenyl isocyanate 7-13%
101-68-8 4,4'-methylenediphenyl diisocyanate 7-13%
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 53862-89-8 polymethylenepolyphenyl polyisocyanate, polypropyleneglycol, copolymer 60-100%
CAS: 5873-54-1 o-(p-isocyanatobenzyl)phenyl isocyanate 7 ?13%
EINECS: 227-534-9
CAS: 101-68-8 4,4'-methylenediphenyl diisocyanate 7 ?13%
EINECS: 202-966-0
CAS: 117-81-7 bis(2-ethylhexyl) phthalate 1 - 5%
EINECS: 204-211-0
Additional information: For the wording of the listed risk phrases refer to section 16.
3. HAZARDS IDENTIFICATION
Hazard description: T Toxic
Information pertaining to particular dangers for man and environment: The product has to be
labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU"
in the latest valid version. May impair fertility. May cause harm to the unborn child. Irritation to eyes,
respiratory system and skin. May cause sensitization by inhalation and skin contact. Contains isocyanates.
See information supplied by the manufacturer.
American Recycling Center, Inc
655 Wabassee Drive, Owosso, MI 48867
(989) 725-5100 www.americanrecycling.com
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MATERIAL SAFETY DATA SHEET Page 2 of 6
MR 1165 Slow Isocyanate
Classification system: The classification was made according to the latest editions of international
substances lists, and expanded upon from company and literature data.
NFPA ratings (scale 0-4)
Health = 2
Fire = 1
Reactivity = 1
HMIS-ratings (scale 0 ?4)
Health = 2
Fire = 1
Reactivity = 1
4. FIRST-AID MEASURES
After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place
patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediately rinse with
water.
After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
After swallowing: If symptoms persist consult doctor.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing agents: Use fire fighting measures that suit the environment.
Protective equipment: No special measures required.
6. ACCIDENTAL RELEASE MEASURES
Person-related safety precautions: Not required.
Measures for environmental protection: Do not allow product to reach sewage system or any water
course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow
to enter sewers/surface or ground water.
Measures for Cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders,
universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure
adequate ventilation.
7. HANDLING AND STORAGE
Handling:
Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Open and handle
receptacle with care. Prevent formation of aerosols.
Information about protection against explosions and fires: Keep respiratory protective device
available.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
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MATERIAL SAFETY DATA SHEET Page 3 of 6
MR 1165 Slow Isocyanate
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
101-68-8 4, 4' 璵ethylenediphenyl diisocyanate
PEL Short-term value: C 0.2 mg/m? C 0.2 ppm
REL Short-term value: C 0.2*mg/m?, C 0.02* ppm
Long-term value: 0.05 mg/m?, 0.005 ppm
*10-min
TLV 0.051 mg/m?, 0.005 ppm
117-81-7 bis(2-ethylhexyl) phthalate
PEL 5 mg/m?br>
REL Short-term value: 10mg/m?br>
Long-term value: 5 mg/m?br>
TLV 5 mg/m?br>
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures: Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of
work. Store protective clothing separately. Avoid contact with the eyes and skin.
Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of
intensive or longer exposure use respiratory protective device that is independent of circulating air.
Protection of hands: Protective gloves. The glove material has to be impermeable and resistant to the
product/the substance/ the preparation. Due to missing tests no recommendation to the glove material can
be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on
consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of
several substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
Penetration time of glove material The exact break through time has to be found out by the
manufacturer of the protective gloves and has to be observed.
Eye protection: Tightly sealed goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information
Form: Fluid
Color: According to product specification
Odor: Characteristic
Change in condition :
Melting point/ Melting range: Undetermined.
Boiling point/Boiling range: 208癈 (406癋)
Flash point: 212癈 (414?F)
Ignition temperature 520癈 (968癋)
Auto Igniting: Product is not self igniting.
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MATERIAL SAFETY DATA SHEET Page 4 of 6
MR 1165 Slow Isocyanate
Danger of explosion: Product does not present an explosion hazard.
Explosion Limits: Lower: 0.4 Vol%
Vapor pressure at 20癈 (68癋): 0 hPa
Density: Not determined.
Solubility in/Miscibility with
Water: Not miscible or difficult to mix. Organic Solvents: 0.0%
Solids content: 11.1%
10. STABILITY AND REACTIVITY
Thermal decomposition/conditions to be avoided: No decomposition if used according to
specifications.
Dangerous reactions: No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
LD/LC50 vaules that are relevant for classification: 101-68-8 4, 4'-methylenediphenyl
diisocyanate Oral LD50>10000 mg/kg (mouse) Dermal LD50>2000 mg/kg (Rabbit)
117-81-7 bis(2-ethylhexyl) phthalate Oral LD50 30600 mg/kg (Rat) Dermal LD50 25000
mg/kg/(Rabbit)
Primary irritant effect: on the skin: Irritant to skin and mucous membranes. On the eye: Irritating
effect. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin
contact. Additional toxicological information: The product shows the following dangers according to
internally approved calculation methods for preparations: Harmful, Irritant.
12. ECOLOGICAL INFORMATION
General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow
undiluted product or large quantities of it to reach ground water, water course or sewage system.
13. DISPOSAL CONSIDERATIONS
Product: Recommendation: Must not be disposed of together with household garbage. Do not allow
product to reach sewage system.
Uncleaned packagings: Recommendation: Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
DOT regulations: Hazard class: -
Land transport ADR/RID (cross-border):
ADR/RID class: -
Maritime transport IMDG:
IMDG Class:-
Marine pollutant: No
Air transport ICAO-TI and IATA-DGR:
ICA/IATA Class: No
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MATERIAL SAFETY DATA SHEET Page 5 of 6
MR 1165 Slow Isocyanate
15. Regulations
Sara
Section 355 (extremely hazardous substances): None of the ingredient is listed.
Section 313 (Specific toxic chemical listings): 101-68-8 4,4'-methylenediphenyl diisocyanate
11.132% 117-81-7 bis(2-ethylhexyl) phthalate 3.0%
SARA Section 311/312 (Hazardous Categorization): 101-68-8 4,4'-methylenediphenyl diisocyanate
Immediate Health, Delayed Health 11.132%
TSCA (Toxic Substances Control Act): All components are TSCA listed or are not required to be listed
unless specifically stated otherwise.
Proposition 65 None of the ingredients is listed.
EPA (Environmental Protection Agency) 101-68-8 4,4'-methylenediphenyl diisocyanate BD;D
117-81-7 bis(2-ethylhexyl) phthalate B2
OSHA-National 101-68-8 4,4'-methylenediphenyl diisocyanate 3
117-81-7 bis(2-etylhexyl) phthalate 3
98-88-4 benzoyl chloride 2A
NTP (National Toxicology Program) 117-81-7 bis(2-ethylhexyl) phthalate R
TLV (Threshold Limit Value established by ACGIH) 117-81-7 bis(2-ethylhexyl) phthalate A3
98-88-4 benzoyl chloride A4
Product related hazard informations: The product has been classified and marked in accordance with
directives on hazardous materials.
Hazard symbols: T. Toxic
Hazard-determining components of labeling: polymethylenepolyphenyl polyisocyanate,
polypropyleneglycol, copolymer. 4,4'-methylenediphenyl diisocyanate, 0-(p-isocyanatobenzyl)phenyl
isocyanate, bis(2-ethylhexyl) phthalate.
Risk phrases: May impair fertility. May cause harm to the unborn child. Irritating to eyes, respiratory
system and skin. May cause sensitization by inhalation and skin contact.
Safety phrases: Avoid exposure-obtain special instructions before use. Keep locked up and out of the
reach of children. Keep container in a well-ventilated place. Keep away from food, drink and animal feeding
stuffs. When using do not eat or drink. Do not breathe gas/fumes/vapor/spray. Use in well ventilated
area or wear respiratory protection. Avoid contact with skin and eyes. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with
plenty of water. Do not empty into drains, dispose of this material and its container at hazardous or special
waste collection point. Wear suitable gloves and eye/face protection. In case of accident or if your feel
unwell, seek medical advice immediately. Not recommended for interior use on large surface areas. This
material and its container must be disposed of as hazardous waste. In case of accident by inhalation:
remove casualty to fresh air and keep at rest.
Special labeling of certain preparations: Contains isocyanates. See information supplied by the
manufacturer.
National regulations: None of the ingredients is listed.
Technical instructions (air): Class I, Share 10-30%, Class NK, Share 1-5%
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16. OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
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MATERIAL SAFETY DATA SHEET Page 6 of 6
MR 1165 Slow Isocyanate
American Recycling Center, Inc. urges each customer or recipient of this SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data
contained in this SDS and any hazards associated with the product. The information herein is provided in
good faith and believed to be accurate as of the effective date of the SDS. However, no warranty, express
or implied, is given. Regulatory requirements are subject to change and may differ between various
locations. It is the buyer's/user's duty to ensure that its activities comply with all applicable
Federal, state, provincial and local laws. The information presented here pertains only to the product
shipped. Since conditions for use of the product are not under the control of American Recycling Center,
Inc. it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product.
Department issuing MSDS: EH&S Delivery
Contact: Ms. Linda Brown (800-735-3129)
ARC MSDS MR1165 SUMMER
The information herein is to assist customers in determining whether our products are suitable for their applications. Our products are intended for sale to industrial and
commercial customers. We request that customers inspect and test our products before use and satisfy themselves as to contents and suitability. We warrant that our
products will meet our written specifications. Nothing herein shall constitute and other warranty express or implied, including any warranty of merchantability or fitness,
nor is protection form any law or patent to be inferred. All patent rights are reserved. The exclusive remedy for all proven claims is replacement of our materials and in no
event shall we be liable for special, incidental or consequential damages.
American Recycling Center, Inc
655 Wabassee Drive, Owosso, MI 48867
(989) 725-5100 www.americanrecycling.com
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