MATERIAL SAFETY DATA SHEET
FIRE
PRODUCT NAME: 711 Side-A
1
SECTION I - MANUFACTURER IDENTIFICATION
3 1 REACTIVITY
HEALTH
H
MANUFACTURER'S NAME: Custom Linings
ADDRESS: Buena Vista, CO
PERSONAL PROTECTION (SECTION VIII)
INFORMATION PHONE: 719-395-4414
HMIS HAZARD RATING
LEAST ----------- 0 SLIGHT ---- 1
EMERGENCY CONTACT: 888-878-5233 MODERATE --- 2 HIGH ------- 3
EXTREME ---- 4
DATE REVISED: January 2003
SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION
OCCUPATIONAL EXPOSURE LIMITS VAPOR PRESSURE
HAZARDOUS COMPONENTS CAS NUMBER OSHA PEL ACGIH TLV MFG TLV mm Hg @ TEMP
*4,4'-DIPHENYLMETHANE DIISOCYANATE 101-68-8 .02 ppm .005 ppm <5.0 25癈 (77癋)
(CEILING)
URETHANE PREPOLYMER N/E N/E
* Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT: >150癈 (>302癋) SPECIFIC GRAVITY: (H2O=1): 1.01
VAPOR DENSITY: Heavier than air EVAPORATION RATE: Slower than ether
SOLUBILITY IN WATER: Reacts with water APPEARANCE AND ODOR: Clear, mild aromatic
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: 302癋 METHOD USED: PMCC
FLAMMABLE LIMITS IN AIR BY VOLUME: Lower: N/E Upper: N/E
EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide, avoid use of water.
SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved self contained breathing apparatus in positive pressure mode with
full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Excessive pressure or temperature
may cause rupture of sealed containers.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Water contamination will produce carbon dioxide. Do not reseal contaminated
containers as pressure buildup may rupture them.
SECTION V - REACTIVITY DATA
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Do not expose container to high temperature (400 Degrees F.) or to moisture. Contact with heat or moisture
can cause CO2 gas to form and could rupture container.
INCOMPATIBILITY (MATERIALS TO AVOID): This product will react with any material containing active hydrogens, such as water,
alcohol, ammonia, amines, alkalis and acids. The reaction with water is very slow under 50癈, but is accelerated at higher temperature
and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Keep away from strong oxidizers
such as hydrogen peroxide, bromine and chronic acid.
Page 1 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: When mixed with incompatible materials, may produce: carbon dioxide,
carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, trace amounts of hydrogen cyanide and unidentified organic compounds.
HAZARDOUS POLYMERIZATION: May occur. High temperatures, above 400 Degrees F. in the presence of moisture alkalis, tertiary
amines, and metal compounds will accelerate polymerization.
SECTION VI - HEALTH HAZARD DATA
SKIN CONTACT: Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening,
swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can
develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. Animal
tests have indicated that respiratory sensitization can result from skin contact with MDI prolonged skin contact may, under extreme
conditions, cause skin cancer. This reinforces the need to prevent direct skin contact with the product.
EYE CONTACT: Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged
vapor contact may cause conjunctivitis. Any level of contact should not be left untreated.
SKIN ABSORPTION: Systemically toxic concentrations of this product will probably not be absorbed through human skin.
INGESTION: Can result in irritating and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore
throat, abdominal pain, nausea, vomiting and diarrhea.
INHALATION: MDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the
respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung
function (breathing obstruction). High vapor concentrations may cause central nervous system (CNS) depression as evidenced by
giddiness, headache, dizziness, and nausea. Persons with a preexisting, non-specific bronchial hyperactivity can respond to
concentrations below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis,
bronchial spasm and pulmonary edema (fluid in lungs). As a result of previous repeated overexposures or a single large dose, certain
individuals may develop isocyanate sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at
levels well below the TLV. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can
experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for weeks and
in severe cases for several years. Chronic overexposure to isocyanate has also been reported to cause lung damage (including
decrease in lung function) which may be permanent. Sensitization can either be temporary or permanent.
HEALTH HAZARDS: ACUTE: Exposure may cause mucous membrane and respiratory tract irritation, tightness of chest, headache,
shortness of breath, and a dry cough. At concentrations exceeding current occupational limits and for sensitized individuals at levels
less than or greater than current occupational limits, asthma-like symptoms may occur. These symptoms may include coughing,
wheezing, and shortness of breath. A hypersensitive pneumonitis may also occur if the person is sensitized. This syndrome is
characterized by fever, nonproductive cough, wheezing, chills, and shortness of breath. Central nervous system (CNS) depression may
also result. The effects of acute exposure may be delayed in onset up to 12-24 hours. CHRONIC: Repeated exposure above current
occupational limits may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response upon
re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest tightness, and may be
fatal. Central nervous system (CNS) depression may also result; unconsciousness and death may occur in extreme cases.
CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Cardiovascular disease, asthma or asthmatic bronchitis,
emphysema, allergic disease, dermatitis, chronic respiratory disease, sinusitis, headache and dizziness.
EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush eyes with plenty of water, preferably lukewarm.
After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and treated by
medical personnel. INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If
breathing is labored, give oxygen. Consult medical personnel. SKIN CONTACT: Wash material off the skin thoroughly with plenty of
soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing and
decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1-2 glasses of milk or water to drink and refer person
to medical personnel. Do not give anything by mouth to an unconscious person.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear skin, eye, and respiratory protection during cleanup.
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work
area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% ammonia in 90% water. Follow the precautions on the
supplier's material safety data sheets. All operations should be performed by trained personnel familiar with the hazards of the
chemicals used. Treat the spill area with the decontamination solution, using about 10 parts of solution for each part of the spill, and
allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues not reacted from spill
Page 2 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as
hazardous waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
WASTE DISPOSAL METHOD: Slowly stir the isocyanate waste into the decontamination solution described above using 10 parts of
the solution for each part of the isocyanate. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still
be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and
regulations regarding treatment.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep in cool, dry, ventilated storage area, in closed containers and
out of direct sunlight. Keep containers closed when not in use. Do not store in containers made of copper, copper alloys or
galvanized containers. Ideal storage temperature is 50 ?00 degrees F.
OTHER PRECAUTIONS: Prevent skin and eye contact, observe TLV limitations. Avoid breathing vapors. Workers should shower and
change to fresh clothing after each shift. A sensitized individual should not be exposed to the product that caused the sensitization. Air
circulation and exhaustion of isocyanate vapors must be maintained until the coatings have fully cured to insure that no potential fire,
explosion or health hazard remains. Warning properties (irritation of the eyes, nose and throat or odor) are not adequate to prevent
chronic overexposure from inhalation. This product can produce asthmatic sensitization upon either single inhalation exposure to a
relatively high concentration or upon repeated inhalation exposure to lower concentrations. Exposure to vapors of heated isocyanates
can be extremely dangerous. Employee education and training in safe handling of this material is required under OSHA hazard
communication standard. Individuals with existing respiratory disease such as chronic bronchitis, emphysema, or asthma should not be
exposed to isocyanates. These individuals should be identified through baseline and annual evaluation and removed from further
exposure. Medical examination should include medical history, vital capacity, and forced expiratory volume at one second.
SECTION VIII - CONTROL MEASURES
VENTILATION: If needed, use local exhaust ventilation to keep airborne concentrations below the TLV.
RESPIRATORY PROTECTION: If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved
positive pressure supplied air respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-
contained breathing apparatus.
PROTECTIVE CLOTHING: Gloves determined to be impervious under the conditions of use should be worn always when working with
this product. Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash
contaminated clothing before wearing.
NOTE: Clothing constructed of butyl rubber, viton, silver shield, Saranex coated Tyvek, as well as some nitrile rubber and
polyvinyl alcohol (PVA) coated garments have demonstrated excellent resistance to permeation by isocyanate. Clothing constructed of
Teflon, as well as some garments constructed of nitrile rubber, natural rubber and PVA exhibited limited resistance to permeation by
isocyanate.
EYE PROTECTION: Goggles and/or full-face shield.
OTHER PROTECTIVE EQUIPMENT AND MEASURES: Unhindered access to eye wash station. As a general hygienic practice, wash
hands and face after use. Showers and cleaning of clothes are recommended. Follow all label instructions. Educate and train
employees in safe use of product.
SECTION IX - REGULATORY INFORMATION
DOT PROPER SHIPPING NAME: Not Regulated.
TOXIC SUBSTANCE CONTROL ACT: All chemicals comprising this product are listed on the TSCA inventory.
USER'S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the
responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where,
precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on
to your customers or employees, as the case may be.
DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole
responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular
purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the
information refers. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.
Page 3 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
MATERIAL SAFETY DATA SHEET
FIRE
PRODUCT NAME: 711 Side-B
1
SECTION I - MANUFACTURER IDENTIFICATION
2 0 REACTIVITY
HEALTH
H
MANUFACTURER'S NAME: Custom Linings
ADDRESS: Buena Vista, CO
PERSONAL PROTECTION (SECTION VIII)
INFORMATION PHONE: 719-395-4414 HMIS HAZARD RATING
LEAST ----------- 0 SLIGHT ---- 1
EMERGENCY CONTACT: 888-878-5233 MODERATE --- 2 HIGH ------- 3
EXTREME ---- 4
DATE REVISED: January 2003
SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION
OCCUPATIONAL EXPOSURE LIMITS VAPOR PRESSURE
HAZARDOUS COMPONENTS CAS NUMBER OSHA PEL ACGIH TLV MFG TLV mm Hg @ TEMP
AROMATIC AMINE 68479-98-1 N/E N/E 0.001 20癈 (68癋)
* No toxic chemical(s) subject to the reporting requirements of Section 313 of Title III and of 40 CFR 372.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT: 586癋 SPECIFIC GRAVITY: (H2O=1): 0.98
COATING V.O.C.: N/A VAPOR DENSITY: Heavier than air
EVAPORATION RATE: Slower than ether SOLUBILITY IN WATER: Insoluble
APPEARANCE AND ODOR: Amber liquid, slight odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: >275癋 METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME: Lower: N/E Upper: N/E
EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide, water spray (fog).
SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with
full face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Excessive pressure or temperature
may cause rupture of containers.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Sudden reaction and foaming may result when the product is exposed to oxidizing
agents.
SECTION V - REACTIVITY DATA
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: High temperatures, open flame and moisture.
INCOMPATIBILITY (MATERIALS TO AVOID): This product will react with any material containing isocyanate.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Combustion products: organic vapors and thermal decomposition fragments.
HAZARDOUS POLYMERIZATION: Will not occur.
Page 4 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
SECTION VI - HEALTH HAZARD DATA
SKIN CONTACT: Skin sensitization and irritation may develop after repeated and/or prolonged contact with human skin.
EYE CONTACT: Can induce irritation or chemical burns on contact with eyes.
SKIN ABSORPTION: Product may be absorbed through skin and cause nausea, headache, and general discomfort.
INGESTION: In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion,
and injury may be severe and cause death.
INHALATION: Vapors can irritate eyes, nose and respiratory passages. Severe overexposure may induce respiratory sensitization with
asthma like symptoms. Symptoms include chronic cough, tightness of chest with difficulty in breathing. These symptoms may be
immediate or delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.
HEALTH HAZARDS: ACUTE: Exposure may cause skin and eye irritation, respiratory tract irritation. Chemical burns may result due to
overexposure. Affects of exposure may be delayed. CHRONIC: Repeated and prolonged exposure at low levels may result in adverse
skin and eye effects, liver and kidney disorders.
CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Cardiovascular disease, asthma or asthmatic bronchitis, skin
allergies, chronic respiratory disease, sinusitis, headache, dizziness, eye diseases.
EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush eyes with plenty of water. After initial flushing,
remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and treated by medical personnel.
INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is labored,
give oxygen. Consult medical personnel. SKIN CONTACT: Wash material off the skin with plenty of soap and water. If redness, itching,
or a burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse.
INGESTION: Do not induce vomiting. Give 1 or 2 glasses of water to drink and refer person to medical personnel. Never give anything
by mouth to an unconscious person.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear skin, eye, and respiratory protection during cleanup.
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work
area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as
hazardous waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
WASTE DISPOSAL METHOD: Residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance
with all relevant local, state, and federal laws and regulations regarding treatment.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in tightly sealed containers to protect from atmospheric
moisture. Store in a dry area. Ideal storage temperature 50 ?100 Degrees F.
OTHER PRECAUTIONS: Prevent skin and eye contact, observe TLV limitations. Avoid breathing vapors. Workers should shower and
change to fresh clothing after each shift. A sensitized individual should not be exposed to the product that caused the sensitization.
SECTION VIII - CONTROL MEASURES
VENTILATION: If needed, use local exhaust ventilation to keep airborne concentrations below the TLV. Exhaust air may need to be
cleaned by scrubbers of filters to reduce environmental contamination.
RESPIRATORY PROTECTION: If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved
positive pressure supplied air respirator with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-
contained breathing apparatus.
PROTECTIVE CLOTHING: Gloves determined to be impervious under the conditions of use should be worn always when working with
this product. Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash
contaminated clothing before wearing.
EYE PROTECTION: Goggles and/or full-face shield.
Page 5 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
OTHER PROTECTIVE EQUIPMENT AND MEASURES: Unhindered access to eye wash station. As a general hygienic practice, wash
hands and face after use. Showers and cleaning of clothes are recommended.
SECTION IX - REGULATORY INFORMATION
DOT PROPER SHIPPING NAME: Not regulated.
TOXIC SUBSTANCE CONTROL ACT: All chemicals comprising this product are listed on the TSCA inventory.
USER'S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the
responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where,
precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on
to your customers or employees, as the case may be.
DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole
responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular
purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the
information refers. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.
Page 6 of 6 Copyright ?2000 by CUSTOM LININGS, All Rights Reserved MSDS 2000/711 A & B msds.doc/12
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