BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
1. MATERIAL AND COMPANY IDENTIFICATION
Material Name : BR Conventional Gasoline- Not Oxygenated
Uses : Fuel for spark ignition engines designed to run on unleaded
fuel.
Company : Shell Oil Products US
P. O. Box 4453
Houston, TX 77210-4453
United States
MSDS Request : 877-276-7285
Emergency Telephone Number
Spill Information : 877-242-7400
Health Information : 877-504-9351
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Concentration
Gasoline 100.00 %
Contains Alkanes, Cycloalkanes, Alkenes and Aromatic Hydrocarbons, Mixture.
Contains 1,2,4 Tri-methyl-benzene, CAS# 95-63-6
Contains Benzene, CAS # 71-43-2.
Contains Toluene, CAS # 108-88-3.
Contains Ethylbenzene, CAS # 100-41-4.
Contains n-Hexane, CAS # 110-54-3.
Contains Xylene (Mixed Isomers), CAS # 1330-20-7.
Contains Naphthalene, CAS # 91-20-3.
Contains Cyclo-hexane, CAS# 110-82-7
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance and Odour : Bronze. Clear, bright liquid. Hydrocarbon.
Health Hazards : Harmful: may cause lung damage if swallowed. Vapours may
cause drowsiness and dizziness. Irritating to skin. A
component or components of this material may cause cancer.
This product contains benzene which may cause leukaemia
(AML ?acute myelogenous leukaemia).
Safety Hazards : Extremely flammable. The vapour is heavier than air, spreads
along the ground and distant ignition is possible. Electrostatic
charges may be generated during handling. Electrostatic
discharge may cause fire.
Environmental Hazards : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Health Hazards
Inhalation : Vapours may cause drowsiness and dizziness.Slightly irritating
1/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
to respiratory system.
Skin Contact : Irritating to skin.
Eye Contact : Moderately irritating to eyes.
Ingestion : Harmful: may cause lung damage if swallowed.
Other Information : Possibility of organ or organ system damage from prolonged
exposure; see Chapter 11 for details. Target organ(s):
Blood-forming organs.
Peripheral nervous system.
May cause heritable genetic damage. Possible risk of harm to
the unborn child. A component or components of this material
may cause cancer. This product contains benzene which may
cause leukaemia (AML ?acute myelogenous leukaemia).
Signs and Symptoms : Skin irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blisters. Eye irritation signs
and symptoms may include a burning sensation and a
temporary redness of the eye. If material enters lungs, signs
and symptoms may include coughing, choking, wheezing,
difficulty in breathing, chest congestion, shortness of breath,
and/or fever. The onset of respiratory symptoms may be
delayed for several hours after exposure. Breathing of high
vapour concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness,
headache, nausea and loss of coordination. Continued
inhalation may result in unconsciousness and death. Damage
to blood-forming organs may be evidenced by: a) fatigue and
anaemia (RBC), b) decreased resistance to infection, and/or
excessive bruising and bleeding (platelet effect). Peripheral
nerve damage may be evidenced by impairment of motor
function (incoordination, unsteady walk, or muscle weakness in
the extremities, and/or loss of sensation in the arms and legs).
Auditory system effects may include temporary hearing loss
and/or ringing in the ears.
Environmental Hazards : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Additional Information : This product is intended for use in closed systems only.
4. FIRST AID MEASURES
Inhalation : Remove to fresh air. If rapid recovery does not occur, transport
to nearest medical facility for additional treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Eye Contact : Flush eyes with water while holding eyelids open. Rest eyes for
30 minutes. If redness, burning, blurred vision, or swelling
persist, transport to the nearest medical facility for additional
treatment.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration. If
2/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
any of the following delayed signs and symptoms appear within
the next 6 hours, transport to the nearest medical facility: fever
greater than 101?F (37?C), shortness of breath, chest
congestion or continued coughing or wheezing.
Advice to Physician : Treat symptomatically. In cases of ingestion, consider gastric
lavage. Gastric lavage must only be undertaken after cuffed
endotracheal intubation in view of the risk of aspiration.
Administration of carbon for medicinal use (carbo medicinalis)
may reduce absorption from the digestive tract.
5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
Flash point : -40 癈 / -40 癋
Explosion / Flammability : 1.3 - 7.6 %(V)
limits in air
Specific Hazards : Hazardous combustion products may include: A complex
mixture of airborne solid and liquid particulates and gases
(smoke). Carbon monoxide. Unidentified organic and inorganic
compounds. The vapour is heavier than air, spreads along the
ground and distant ignition is possible. Will float and can be
reignited on surface water.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Proper protective equipment including breathing apparatus
Firefighters must be worn when approaching a fire in a confined space.
Additional Advice : If the fire cannot be extinguished the only course of action is to
evacuate immediately. Keep adjacent containers cool by
spraying with water. If possible remove containers from the
danger zone. Contain residual material at affected sites to
prevent material from entering drains (sewers), ditches, and
waterways.
6. ACCIDENTAL RELEASE MEASURES
Observe all relevant local and international regulations. Avoid contact with skin, eyes and
clothing. Evacuate the area of all non-essential personnel. Ventilate contaminated area
thoroughly. Avoid contact with spilled or released material. Immediately remove all contaminated
clothing. For guidance on selection of personal protective equipment see Chapter 8 of this
Material Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this
Material Safety Data Sheet. If contamination of sites occurs remediation may require specialist
advice. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Take
precautionary measures against static discharges.
Protective measures : Vapour can travel for considerable distances both above and
below the ground surface. Underground services (drains,
pipelines, cable ducts) can provide preferential flow paths. Do
not breathe fumes, vapour. Take measures to minimise the
effects on groundwater. Contain residual material at affected
3/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
sites to prevent material from entering drains (sewers), ditches,
and waterways. Shut off leaks, if possible without personal
risks. Remove all possible sources of ignition in the
surrounding area. Use appropriate containment (of product
and fire fighting water) to avoid environmental contamination.
Prevent from spreading or entering drains, ditches or rivers by
using sand, earth, or other appropriate barriers. Attempt to
disperse the vapour or to direct its flow to a safe location for
example by using fog sprays. Take precautionary measures
against static discharge. Ensure electrical continuity by
bonding and grounding (earthing) all equipment.
Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
Maritime spillages should be dealt with using a Shipboard Oil
Pollution Emergency Plan (SOPEP), as required by MARPOL
Annex 1 Regulation 26. U.S. regulations may require reporting
releases of this material to the environment which exceed the
reportable quantity (refer to Chapter 15) to the National
Response Centre at (800) 424-8802. Under Section 311 of the
Clean Water Act (CWA) this material is considered an oil. As
such, spills into surface waters must be reported to the
National Response Centre at (800) 424-8802. This material is
covered by EPA's Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA) Petroleum
Exclusion. Therefore, releases to the environment may not be
reportable under CERCLA.
7. HANDLING AND STORAGE
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material. Air-dry
contaminated clothing in a well-ventilated area before
laundering. Contaminated leather articles including shoes
cannot be decontaminated and should be destroyed to prevent
reuse. Turn off all battery operated portable electronic devices
4/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
(examples include: cellular phones, pagers and CD players)
before operating gasoline pump. Properly dispose of any
contaminated rags or cleaning materials in order to prevent
fires. Prevent spillages. For comprehensive advice on
handling, product transfer, storage and tank cleaning refer to
the product supplier. Do not use as a cleaning solvent or other
non-motor fuel uses.
Handling : When using do not eat or drink. Extinguish any naked flames.
Do not smoke. Remove ignition sources. Avoid sparks. Never
siphon by mouth. The vapour is heavier than air, spreads along
the ground and distant ignition is possible. Avoid exposure.
Obtain special instructions before use. Not expected to be a
health hazard when used under normal conditions.
Storage : Drum and small container storage: Keep containers closed
when not in use. Drums should be stacked to a maximum of 3
high. Use properly labelled and closeable containers.
Packaged product must be kept tightly closed and stored in a
diked (bunded) well-ventilated area, away from, ignition
sources and other sources of heat. Take suitable precautions
when opening sealed containers, as pressure can build up
during storage. Tank storage: Tanks must be specifically
designed for use with this product. Bulk storage tanks should
be diked (bunded). Locate tanks away from heat and other
sources of ignition. Cleaning, inspection and maintenance of
storage tanks is a specialist operation which requires the
implementation of strict procedures and precautions.
Product Transfer : Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (<= 1 m/sec until fill pipe
submerged to twice its diameter, then <= 7 m/sec). Avoid
splash filling. Do NOT use compressed air for filling,
discharging, or handling operations. Wait 2 minutes after tank
filling (for tanks such as those on road tanker vehicles) before
opening hatches or manholes. Wait 30 minutes after tank filling
(for large storage tanks) before opening hatches or manholes.
Recommended Materials : For container and container linings, use mild steel or
aluminium. Aluminium may also be used for applications where
it does not present an unnecessary fire hazard. Examples of
suitable materials are: high density polyethylene (HDPE),
polypropylene (PP), and Viton (FKM), which have been
specifically tested for compatibility with this product. For
container linings, use amine-adduct cured epoxy paint. For
seals and gaskets use: graphite, PTFE, Viton A, Viton B.
Unsuitable Materials : Some synthetic materials may be unsuitable for containers or
container linings depending on the material specification and
intended use. Examples of materials to avoid are: natural
rubber (NR), nitrile rubber (NBR), ethylene propylene rubber
(EPDM), polymethyl methacrylate (PMMA), polystyrene,
polyvinyl chloride (PVC), polyisobutylene. However, some may
be suitable for glove materials.
Container Advice : Do not cut, drill, grind, weld or perform similar operations on or
5/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
near containers. Gasoline containers must not be used for
storage of other products. Containers, even those that have
been emptied, can contain explosive vapours.
Additional Information : Ensure that all local regulations regarding handling and storage
facilities are followed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Material Source Type ppm mg/m3 Notation
Gasoline, ACGIH TWA 300 ppm
low boiling
point
naphtha
Gasoline, ACGIH STEL 500 ppm
low boiling
point
naphtha
Xylene ACGIH TWA 100 ppm
Xylene ACGIH STEL 150 ppm
Xylene OSHA Z1 PEL 100 ppm 435 mg/m3
Xylene OSHA Z1A TWA 100 ppm 435 mg/m3
Xylene OSHA Z1A STEL 150 ppm 655 mg/m3
Toluene ACGIH TWA 20 ppm
Toluene ACGIH SKIN_DES Can be absorbed through
the skin.
Toluene OSHA Z1A TWA 100 ppm 375 mg/m3
Toluene OSHA Z1A STEL 150 ppm 560 mg/m3
Toluene SHELL IS TWA 50 ppm
1,2,4- ACGIH TWA 25 ppm
trimethylbe
nzene
1,2,4- OSHA Z1A TWA 25 ppm 125 mg/m3
trimethylbe
nzene
Ethylbenze ACGIH TWA 100 ppm
ne
Ethylbenze ACGIH STEL 125 ppm
ne
Ethylbenze OSHA Z1 PEL 100 ppm 435 mg/m3
ne
Ethylbenze OSHA Z1A TWA 100 ppm 435 mg/m3
ne
Ethylbenze OSHA Z1A STEL 125 ppm 545 mg/m3
ne
Benzene ACGIH TWA 0.5 ppm
Benzene ACGIH STEL 2.5 ppm
Benzene ACGIH SKIN_DES Can be absorbed through
the skin.
Benzene OSHA REF
6/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Benzene OSHA TWA 1 ppm
Benzene OSHA STEL 5 ppm
Benzene OSHA OSHA_ACT 0.5 ppm
Benzene OSHA Z1A TWA 1 ppm
Benzene OSHA Z1A STEL 5 ppm
n-hexane ACGIH TWA 50 ppm
n-hexane ACGIH SKIN_DES Can be absorbed through
the skin.
n-hexane OSHA Z1 PEL 500 ppm 1,800 mg/m3
n-hexane OSHA Z1A TWA 50 ppm 180 mg/m3
Cyclohexan ACGIH TWA 100 ppm
e
Cyclohexan OSHA Z1 PEL 300 ppm 1,050 mg/m3
e
Cyclohexan OSHA Z1A TWA 300 ppm 1,050 mg/m3
e
Styrene ACGIH TWA 20 ppm
Styrene ACGIH STEL 40 ppm
Styrene OSHA Z1A TWA 50 ppm 215 mg/m3
Styrene OSHA Z1A STEL 100 ppm 425 mg/m3
Naphthalen ACGIH TWA 10 ppm
e
Naphthalen ACGIH STEL 15 ppm
e
Naphthalen ACGIH SKIN_DES Can be absorbed through
e the skin.
Naphthalen OSHA Z1 PEL 10 ppm 50 mg/m3
e
Naphthalen OSHA Z1A TWA 10 ppm 50 mg/m3
e
Naphthalen OSHA Z1A STEL 15 ppm 75 mg/m3
e
Additional Information : Skin notation means that significant exposure can also occur
by absorption of liquid through the skin and of vapour through
the eyes or mucous membranes. Shell has adopted as Interim
Standards the OSHA Z1A values that were established in 1989
and later rescinded.
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Use sealed systems as far as
possible. Adequate explosion-proof ventilation to control
airborne concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended. Eye washes and
showers for emergency use.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
7/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are suitable, select an appropriate combination of
mask and filter. Where air-filtering respirators are unsuitable
(e.g., airborne concentrations are high, risk of oxygen
deficiency, confined space) use appropriate positive pressure
breathing apparatus. All respiratory protection equipment and
use must be in accordance with local regulations.
Respirator selection, use and maintenance should be in
accordance with the requirements of the OSHA Respiratory
Protection Standard, 29 CFR 1910.134.
Hand Protection : Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended. Suitability and
durability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material,
glove thickness, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced.
Eye Protection : Chemical splash goggles (chemical monogoggles).
Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron (where
risk of splashing).
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Bronze. Clear, bright liquid.
Odour : Hydrocarbon.
Freezing Point : -58 癈 / -72 癋
Flash point : -40 癈 / -40 癋
Explosion / Flammability : 1.3 - 7.6 %(V)
limits in air
Specific gravity : 0.72 - 0.76
Water solubility : Negligible.
Vapour density (air=1) : 3.5
10. STABILITY AND REACTIVITY
Stability : Stable under normal conditions of use.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Materials to Avoid : Strong oxidising agents.
Hazardous Decomposition : Hazardous decomposition products are not expected to form
Products during normal storage. Thermal decomposition is highly
dependent on conditions. A complex mixture of airborne solids,
liquids and gases, including carbon monoxide, carbon dioxide
and other organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.
11. TOXICOLOGICAL INFORMATION
Basis for Assessment : Information given is based on product data, a knowledge of the
8/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
components and the toxicology of similar products.
Acute Oral Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat
Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat
Acute Inhalation Toxicity : Low toxicity: LC50 >5 mg/l / 4.00 h, Rat
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Skin Irritation : Irritating to skin.
Eye Irritation : Moderately irritating to eyes (but insufficient to classify).
Respiratory Irritation : Based on human experience, breathing of vapours or mists
may cause a temporary burning sensation to nose, throat and
lungs.
Sensitisation : Not a skin sensitiser.
Repeated Dose Toxicity : Kidney: caused kidney effects in male rats which are not
considered relevant to humans
Blood-forming organs: repeated exposure affects the bone
marrow. (Benzene)
Peripheral nervous system: repeated exposure causes
peripheral neuropathy in animals. (n-hexane)
Mutagenicity : May cause heritable genetic damage. (Benzene)
Mutagenicity studies on gasoline and gasoline blending
streams have shown predominantly negative results.
Carcinogenicity : Known human carcinogen. (Benzene)
May cause leukaemia (AML - acute myelogenous leukaemia).
(Benzene)
Inhalation exposure to mice causes liver tumours, which are
not considered relevant to humans.
Material : Carcinogenicity Classification
Gasoline, low boiling point : ACGIH Group A3: Confirmed animal carcinogen with unknown
naphtha relevance to humans.
Gasoline, low boiling point : IARC 2B: Possible carcinogen.
naphtha
Xylene : ACGIH Group A4: Not classifiable as a human carcinogen.
Xylene : IARC 3: Classification not possible from current data.
Toluene : ACGIH Group A4: Not classifiable as a human carcinogen.
Toluene : IARC 3: Classification not possible from current data.
Benzene : ACGIH Group A1: Confirmed human carcinogen.
Benzene : NTP: Known carcinogen.
Benzene : IARC 1: Human carcinogen.
Benzene : OSHASP: Cancer hazard.
Ethylbenzene : ACGIH Group A3: Confirmed animal carcinogen with unknown
relevance to humans.
Ethylbenzene : IARC 2B: Possible carcinogen.
Naphthalene : NTP: Anticipated carcinogen.
Naphthalene : IARC 2B: Possible carcinogen.
Styrene : ACGIH Group A4: Not classifiable as a human carcinogen.
Styrene : IARC 2B: Possible carcinogen.
9/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Reproductive and : Causes foetotoxicity at doses which are maternally toxic.
Developmental Toxicity (Toluene)
Causes adverse effects on the foetus based on animal studies.
(Toluene)
Many case studies involving abuse during pregnancy indicate
that toluene can cause birth defects, growth retardation and
learning difficulties. (Toluene)
Additional Information : Exposure to very high concentrations of similar materials has
been associated with irregular heart rhythms and cardiac
arrest.
Prolonged and repeated exposures to high concentrations
have resulted in hearing loss in rats. Solvent abuse and noise
interaction in the work environment may cause hearing loss.
(Toluene)
Abuse of vapours has been associated with organ damage and
death. (Toluene)
Myelodysplastic syndrome (MDS) was observed in individuals
exposed to very high levels (50 ppm to 300 ppm range) of
benzene over a long period of time in the workplace. The
relevance of these results to lower levels of exposure is not
known. (Benzene)
12. ECOLOGICAL INFORMATION
Fuels are typically made from blending several refinery streams. Ecotoxicological studies have
been carried out on a variety of hydrocarbon blends and streams but not those containing
additives. Information given is based on a knowledge of the components and the ecotoxicology
of similar products.
Acute Toxicity : Toxic: LL/EL/IL50 1-10 mg/l (to aquatic organisms) (LL/EL50
expressed as the nominal amount of product required to
prepare aqueous test extract).
Mobility : Floats on water. Evaporates within a day from water or soil
surfaces. Large volumes may penetrate soil and could
contaminate groundwater. Contains volatile constituents.
Persistence/degradability : Persists under anaerobic conditions. Major constituents are
expected to be inherently biodegradable. The volatile
constituents will oxidize rapidly by photochemical reactions in
air.
Bioaccumulation : Contains constituents with the potential to bioaccumulate.
Other Adverse Effects : Films formed on water may affect oxygen transfer and damage
organisms.
13. DISPOSAL CONSIDERATIONS
Material Disposal : Recover or recycle if possible. It is the responsibility of the
waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations. Waste arising from a spillage or tank
cleaning should be disposed of in accordance with prevailing
10/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
regulations, preferably to a recognised collector or contractor.
The competence of the collector or contractor should be
established beforehand. Do not dispose into the environment,
in drains or in water courses. Do not dispose of tank water
bottoms by allowing them to drain into the ground. This will
result in soil and groundwater contamination.
Container Disposal : Drain container thoroughly. After draining, vent in a safe place
away from sparks and fire. Residues may cause an explosion
hazard. Do not, puncture, cut, or weld uncleaned drums. Send
to drum recoverer or metal reclaimer. Do not pollute the soil,
water or environment with the waste container.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations. Local regulations may
be more stringent than regional or national requirements and
must be complied with.
14. TRANSPORT INFORMATION
US Department of Transportation Classification (49CFR)
Identification number UN 1203
Proper shipping name Gasoline
Class / Division 3
Packing group II
Emergency Response Guide 128
No. .
Additional Information Oil: This product is an oil under 49CFR (DOT) Part 130. If
shipped by rail or highway in a tank with a capacity of 3500
gallons or more, it is subject to these requirements. Mixtures
or solutions containing 10% or more of this product may also
be subject to this rule.
IMDG
Identification number UN 1203
Proper shipping name GASOLINE
Class / Division 3
Packing group II
Marine pollutant: No
IATA (Country variations may apply)
Identification number UN 1203
Proper shipping name Gasoline
Class / Division 3
Packing group II
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
Federal Regulatory Status
11/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Comprehensive Environmental Release, Compensation & Liability Act (CERCLA)
BR Conventional Gasoline- Not
Oxygenated ()
Gasoline, low boiling point naphtha () Reportable quantity: 100 lbs
Xylene (1330-20-7) Reportable quantity: 100 lbs
Toluene (108-88-3) Reportable quantity: 1000 lbs
Benzene (71-43-2) Reportable quantity: 10 lbs
Ethylbenzene (100-41-4) Reportable quantity: 1000 lbs
n-hexane (110-54-3) Reportable quantity: 5000 lbs
Naphthalene (91-20-3) Reportable quantity: 100 lbs
Cyclohexane (110-82-7) Reportable quantity: 1000 lbs
Styrene (100-42-5) Reportable quantity: 1000 lbs
Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore
releases to the environment are not reportable under CERCLA.
Clean Water Act (CWA) Section 311
Xylene (1330-20-7) Reportable quantity: 100 lbs
Toluene (108-88-3) Reportable quantity: 1000 lbs
Benzene (71-43-2) Reportable quantity: 10 lbs
Ethylbenzene (100-41-4) Reportable quantity: 1000 lbs
Naphthalene (91-20-3) Reportable quantity: 100 lbs
Cyclohexane (110-82-7) Reportable quantity: 1000 lbs
Styrene (100-42-5) Reportable quantity: 1000 lbs
12/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Under Section 311 of the Clean Water Act (CWA) this material is considered an oil. As such,
spills into surface waters must be reported to the National Response Centre at (800) 424-8802.
SARA Hazard Categories (311/312)
Immediate (Acute) Health Hazard. Delayed (Chronic) Health Hazard. Fire Hazard.
SARA Toxic Release Inventory (TRI) (313)
Xylene (1330-20-7) 25.00%
Toluene (108-88-3) 25.00%
1,2,4-trimethylbenzene (95-63-6) 5.00%
Benzene (71-43-2) 4.90%
Ethylbenzene (100-41-4) 4.50%
n-hexane (110-54-3) 3.00%
Naphthalene (91-20-3) 1.00%
Cyclohexane (110-82-7) 1.00%
Styrene (100-42-5) 1.00%
State Regulatory Status
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65)
This product contains a chemical known to the State of California to cause cancer.
Known to the State of California to cause birth defects or other reproductive harm.
New Jersey Right-To-Know Chemical List
Xylene (1330-20-7) 25.00% Listed.
Toluene (108-88-3) 25.00% Listed.
1,2,4-trimethylbenzene (95-63-6) 5.00% Listed.
Benzene (71-43-2) 4.90% Listed.
Ethylbenzene (100-41-4) 4.50% Listed.
n-hexane (110-54-3) 3.00% Listed.
Naphthalene (91-20-3) 1.00% Listed.
Cyclohexane (110-82-7) 1.00% Listed.
Styrene (100-42-5) 1.00% Listed.
Pennsylvannia Right-To-Know Chemical List
Gasoline, low boiling point naphtha () 100.00% Listed.
Xylene (1330-20-7) 25.00% Environmental hazard.
Listed.
13/14
Print Date 07/26/2007 MSDS_US
BR Conventional Gasoline- Not Oxygenated
MSDS# 401728E
Version 4.
Effective Date 07/25/2007
Material Safety Data Sheet
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Toluene (108-88-3) 25.00% Environmental hazard.
Listed.
1,2,4-trimethylbenzene (95-63-6) 5.00% Environmental hazard.
Listed.
Benzene (71-43-2) 4.90% Special hazard.
Environmental hazard.
Listed.
Ethylbenzene (100-41-4) 4.50% Environmental hazard.
Listed.
n-hexane (110-54-3) 3.00% Listed.
Naphthalene (91-20-3) 1.00% Environmental hazard.
Listed.
Cyclohexane (110-82-7) 1.00% Environmental hazard.
Listed.
Styrene (100-42-5) 1.00% Environmental hazard.
Listed.
16. OTHER INFORMATION
Additional Information : This document contains important information to ensure the
safe storage, handling and use of this product. The information
in this document should be brought to the attention of the
person in your organisation responsible for advising on safety
matters.
NFPA Rating (Health, : 1, 3, 0
Fire, Reactivity)
MSDS Version Number : 4.
MSDS Effective Date : 07/25/2007
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : The content and format of this MSDS is in accordance with the
OSHA Hazard Communication Standard, 29 CFR 1910.1200.
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : The information contained herein is based on our current
knowledge of the underlying data and is intended to describe
the product for the purpose of health, safety and environmental
requirements only. No warranty or guarantee is expressed or
implied regarding the accuracy of these data or the results to
be obtained from the use of the product.
14/14
Print Date 07/26/2007 MSDS_US
|