Page 1/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
* 1 Identification of substance:
?Product details:
?Trade name: Acrysol 83925
?Article number: 83925
?Application of the substance / the preparation Cleaner solvent
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@@@
???
GCD
Xn Harmful
F Highly flammable
N Dangerous for the environment
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in
the latest valid version.
R 11 Highly flammable.
R 20/21 Harmful by inhalation and in contact with skin.
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Danger
H225 - Highly flammable liquid and vapour.
~ Danger
H340 - May cause genetic defects.
H350 - May cause cancer.
H304 - May be fatal if swallowed and enters airways.
~
Warning
H315 - Causes skin irritation.
~
H411 - Toxic to aquatic life with long lasting effects.
?Prevention:
P201 Obtain special instructions before use.
(Contd. on page 2)
GB
Page 2/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 1)
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 1330-20-7 xylene, mixed isomers, pure 25-50%
EINECS: 215-535-7 ? Xn, ? Xi; R 10-20/21-38
@
G G
@
Warning: ~ 2.6/3; ~ 3.1.D/4, 3.1.I/4, 3.2/2
CAS: 64742-49-0 Naphtha (petroleum) hydrotreated light 10-25%
EINECS: 265-151-9 ? Xn; R 65
G
@
Danger: ~ 3.5/1B, 3.6/1B, 3.10/1
CAS: 111-65-9 octane 10-25%
EINECS: 203-892-1 ? Xn, ? Xi, ? F, ? N; R 11-38-50/53-65-67
@
G G
@ @
C @
D
Danger: ~ 2.6/2; ~ 3.10/1
Warning: ~ 4.1.C/1; ~ 3.2/2, 3.8/3
CAS: 142-82-5 heptane 2.5-10%
EINECS: 205-563-8 ? Xn, ? Xi, ? F, ? N; R 11-38-50/53-65-67
G
@ G
@ @
C D
@
Danger: ~ 2.6/2; ~ 3.10/1
Warning: ~ 4.1.C/1; ~ 3.2/2, 3.8/3
CAS: 100-41-4 ethylbenzene 2.5-10%
EINECS: 202-849-4 ? Xn, ? F; R 11-20
@
G C
@
Danger: ~ 2.6/2
Warning: ~ 3.1.I/4
CAS: 108-87-2 methylcyclohexane 2.5-10%
EINECS: 203-624-3 ? Xn, ? Xi, ? F, ? N; R 11-38-51/53-65-67
G
@ @
G C
@ @
D
Danger: ~ 2.6/2; ~ 3.10/1
Warning: ~ 3.2/2, 3.8/3
~ 4.1.C/2
CAS: 110-82-7 cyclohexane 1-2.5%
EINECS: 203-806-2 ? Xn, ? Xi, ? F, ? N; R 11-38-50/53-65-67
G
@ G
@ @
C D
@
Danger: ~ 2.6/2; ~ 3.10/1
Warning: ~ 4.1.C/1; ~ 3.2/2, 3.8/3
CAS: 73513-42-5 Hexane, mixture of isomers (containing less than 5% 0.1-1.0%
@
? Xn, ? Xi, ? F, ? N; R 11-38-51/53-65-67
G @
G @
C @
D
Danger: ~ 2.6/1; ~ 3.10/1
Warning: ~ 3.2/2, 3.8/3
~ 4.1.C/2
CAS: 110-54-3 n-hexane 0.1-1.0%
EINECS: 203-777-6 ? Xn, ? Xi, ? F, ? N; R 11-38-48/20-62-51/53-65-67
G
@ G
@ @
C @
D
Danger: ~ 2.6/2; ~ 3.10/1, 3.7/2, 3.9/2
Warning: ~ 3.2/2, 3.8/3
~ 4.1.C/2
?Additional information For the wording of the listed risk phrases refer to section 16.
4 First aid measures
?General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
?After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness bring patient into stable side position for transport.
?After skin contact Instantly wash with water and soap and rinse thoroughly.
?After eye contact Rinse opened eye for several minutes under running water.
(Contd. on page 3)
GB
Page 3/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 2)
?After swallowing Do not induce vomiting; instantly call for medical help.
* 5 Fire fighting measures
?Suitable extinguishing agents
Carbon dioxide
Fire-extinguishing powder
Water haze
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
?Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained breathing apparatus.
* 6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
?Handling
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
xylene, mixed isomers, pure
WEL Short-term value: 441 mg/m? 100 ppm
Long-term value: 220 mg/m? 50 ppm
Sk; BMGV
heptane
WEL Long-term value: 500 ppm
ethylbenzene
WEL Short-term value: 552 mg/m? 125 ppm
Long-term value: 441 mg/m? 100 ppm
(Contd. on page 4)
GB
Page 4/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 3)
cyclohexane
WEL Short-term value: 1050 mg/m? 300 ppm
Long-term value: 350 mg/m? 100 ppm
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing
apparatus that is independent of circulating air.
Use breathing protection in case of insufficient ventilation.
Filter AX/P2.
?Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
Nitrile rubber, NBR
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Tightly sealed safety glasses.
?Body protection: Use protective suit.
* 9 Physical and chemical properties:
?General Information
Form: Fluid
Colour: Transparent
Odour: Characteristic
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 98癈
?Flash point: 2癈
?Ignition temperature: 200.0癈
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible.
?Critical values for explosion:
Lower: 0.8 Vol %
Upper: 7.7 Vol %
?Vapour pressure at 20癈: 15 hPa
?Density at 20癈 0.796 g/cm?br>
?Solubility in / Miscibility with
Water: Not miscible or difficult to mix
?Solvent content:
Organic solvents: 796.0G/L VOC
GB
(Contd. on page 5)
Page 5/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 4)
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous products of decomposition: Carbon monoxide and carbon dioxide
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
xylene, mixed isomers, pure
Oral LD50 8700 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
Inhalative LC50/4 h 6350 mg/l (rat)
ethylbenzene
Oral LD50 3500 mg/kg (rat)
Dermal LD50 17800 mg/kg (rabbit)
cyclohexane
Oral LD50 12705 mg/kg (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: No irritant effect.
?Sensitization: No sensitizing effect known.
?Additional toxicological information:
Harmful
Irritant
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
* 12 Ecological information:
?Ecotoxical effects:
?Remark: Toxic for fish
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
g
cd
d?br>
x
?ADR/RID-GGVS/E Class: 3 (F1)
(Contd. on page 6)
GB
Page 6/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 5)
?Kemler Number: 33
?UN-Number: 1993
?Packaging group: II
?Label 3
?Special marking: ?
?Designation of goods: 1993 FLAMMABLE LIQUID, N.O.S. (vapor pressure at 50癈 at most 110 kPa) (Naphtha (petroleum)
hydrotreated light, OCTANES)
?Maritime transport IMDG:
x
g
c
d
?IMDG Class: 3
?UN Number: 1993
?Label 3
?Packaging group: II
?EMS Number: F-E,S-D
?Marine pollutant: No
?Correct technical name: FLAMMABLE LIQUID, N.O.S. (Naphtha (petroleum) hydrotreated light, OCTANES)
?Air transport ICAO-TI and IATA-DGR:
g
c
x
d
?ICAO/IATA Class: 3
?UN/ID Number: 1993
?Label 3
?Packaging group: II
?Correct technical name: FLAMMABLE LIQUID, N.O.S. (Naphtha (petroleum) hydrotreated light, OCTANES)
?UN "Model Regulation": UN1993; FLAMMABLE LIQUID, N.O.S.; 3; II
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
?Code letter and hazard designation of product:
GCD
@@@
???
Xn Harmful
F Highly flammable
N Dangerous for the environment
?Hazard-determining components of labelling:
Naphtha (petroleum) hydrotreated light
octane
xylene, mixed isomers, pure
?Risk phrases:
11 Highly flammable.
20/21 Harmful by inhalation and in contact with skin.
38 Irritating to skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
?Safety phrases:
9 Keep container in a well-ventilated place.
13 Keep away from food, drink and animal feedingstuffs.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
36/37 Wear suitable protective clothing and gloves.
(Contd. on page 7)
GB
Page 7/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: Acrysol 83925
(Contd. of page 6)
46 If swallowed, seek medical advice immediately and show this container or label.
?National regulations
?Technical instructions (air):
Class Share in %
II 30.0
NK 70.0
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
20 Harmful by inhalation.
20/21 Harmful by inhalation and in contact with skin.
38 Irritating to skin.
48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
62 Possible risk of impaired fertility.
65 Harmful: may cause lung damage if swallowed.
67 Vapours may cause drowsiness and dizziness.
?Department issuing data specification sheet: Environment protection department
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
|