ULTRAZOL?8219CM
Material Safety Data Sheet
ULTRAZOL?8219CM
Prepared according to 29CFR 1910.1200.
1 Chemical Product and Company Identification
The Lubrizol Corporation
29400 Lakeland Boulevard
Wickliffe, Ohio 44092
Tel: (440) 943-4200
ULTRAZOL?8219CM
Product Trade Name
Not applicable for mixtures.
CAS Number
None.
Synonyms
Mixture.
Generic Chemical Name
Gasoline additive.
Product Type
24 June 2009
Preparation/Revision Date
FOR TRANSPORT EMERGENCY call CHEMTREC: (+1) 703-527-3887 (outside the
Transportation Emergency
U.S.), 1-800-424-9300 (in the U.S.)
Phone No.
27485028-2422266-5024920-102103
MSDS No.
2 Hazards Identification
Clear light brown liquid.
Appearance
Hydrocarbon
Odor
Danger.
Principal Hazards
Flammable liquid. may create a flash fire hazard.
Harmful if inhaled.
Causes skin irritation.
Causes respiratory tract irritation.
May be harmful if absorbed through skin.
May cause eye irritation.
May cause allergic skin reaction.
Contains components which may cause cancer.
May cause chronic health effects.
Blood Central nervous system Heart Kidney Liver
Target Organs:
See Section 11 for complete health hazard information.
3 Composition/Information on Ingredients
Hazardous Ingredients
Comp CAS No. Percentage (by wt.) Carcinogen
Xylene 1330-20-7 28.7% N/E
Petroleum naphtha 64742-94-5 From 10 to 19.9 percent N/E
Ethylbenzene 100-41-4 7.2% IARC Suspect Carcinogen
Polyether amine Confidential. From 1 to 4.9 percent N/E
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ULTRAZOL?8219CM
Naphthalene 91-20-3 1.4% IARC Suspect Carcinogen NTP Carcinogen
Alkarylamine Confidential. From 0.5 to 1.5 percent N/E
(N/E) - None established
4 First Aid Measures
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
Eyes
to do. Continue rinsing. If eye irritation persists, get medical attention.
Wash with plenty of soap and water. Immediately remove contaminated clothing. If skin
Skin
irritation occurs, get medical attention. Launder contaminated clothing before reuse and
discard leather articles saturated with the material.
Remove exposed person to fresh air. If breathing is labored, administer oxygen. If breathing
Inhalation
has stopped, apply artificial respiration. Call a poison center or doctor if you feel unwell.
DO NOT INDUCE VOMITING. Aspiration of material due to vomiting can cause chemical
Oral
pneumonitis which can be fatal. Get immediate medical attention. If vomiting occurs
naturally, the casualty should lean forward to reduce the risk of aspiration. Do NOT induce
vomiting. Immediately call a poison center or doctor.
If exposed or concerned: Get medical attention.
Additional Information
5 Fire Fighting Measures
37 癈, 98.6 癋 PMCC (Typical)
Flash Point
CO2, dry chemical, or foam. Water can be used to cool and protect exposed material.
Extinguishing Media
Recommend wearing self-contained breathing apparatus. Water may cause splattering.
Firefighting Procedures
Toxic fumes, gases or vapors may evolve on burning. Vapors may be heavier than air and
Unusual Fire & Explosion
may travel along the ground to a distant ignition source and flash back. Container may
Hazards
rupture on heating.
6 Accidental Release Measures
May form explosive mixtures with air. Immediately evacuate all personnel from danger area.
Spill Procedures
Personal Protective Equipment must be worn, see Personal Protection Section for PPE
recommendations. Eliminate all sources of heat, sparks pilot lights, static electricity and open
flames. Ventilate spill area. Prevent entry into sewers and waterways, dispose of in
accordance with all federal, state and local environmental regulation. Pick up free liquid for
recycle and/or disposal if can be accomplished safely with explosion proof equipment.
Residual liquid can be absorbed on inert material. Check under Transportation and Labeling
(DOT/CERCLA) and Other Regulatory Information Section (SARA) for hazardous
substances to determine regulatory reporting requirements for spills.
7 Handling and Storage
Ambient
Pumping Temperature
Maximum Handling
Ambient
Temperature
Handling Procedures Keep away from ignition sources such as heat, sparks and open flame. No smoking. Keep
containers closed when not in use. Do not discharge into drains or the environment, dispose
to an authorized waste collection point. Use appropriate containment to avoid environmental
contamination. Avoid breathing dust, fume, gas, mist, vapors or spray. Ground / bond
container and receiving equipment. Use explosion-proof equipment. Use only non-sparking
tools. Wash thoroughly after handling. Contaminated work clothing should not be allowed
out of the workplace. Launder contaminated clothing before reuse. Empty containers retain
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ULTRAZOL?8219CM
material residue. Do not cut, weld, braze, solder, drill, grind or expose containers to heat,
flame, spark or other sources of ignition.
Maximum Storage
Ambient
Temperature
Do not store near potential sources of ignition. Isolated outside storage is preferred. Inside
Storage Procedures
storage area should be in a flammable liquids cabinet or storage area. Take precautions to
avoid release to the environment. Store in a cool, dry, well-ventilated area. Keep container
tightly closed.
Not determined.
Loading Temperature
8 Exposure Controls/Personal Protection
Exposure Limits
Exposure Guidelines
OSHA ACGIH Other
Comp TWA STEL TWA STEL TWA STEL
Xylene 100 ppm N/E 100 ppm 150 ppm N/E N/E
Petroleum
N/E N/E N/E N/E 100 ppm (l) N/E
naphtha
Ethylbenzene 100 ppm N/E 100 ppm 125 ppm N/E N/E
Naphthalene 10 ppm N/E 10 ppm (s) 15 ppm N/E N/E
(s) - Skin exposure
(p) - Proposed limit
(c) - Ceiling exposure
(l) - Recommended exposure limit
(u) - Supplier recommended exposure limit
(N/E) - None established
None known.
Other Exposure Limits
Use material in well ventilated area only. Additional ventilation or exhaust may be required
Engineering Controls
to maintain air concentrations below recommended exposure limits. Use explosion proof
equipment.
Viton. Teflon. Polyvinyl alcohol. Note: polyvinyl alcohol gloves are water soluble and
Gloves Procedures
should not be used when there is potential for water contact.
Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield.
Eye Protection
Use NIOSH/MSHA approved full face respirator with a combination organic vapor and high
Respiratory Protection
efficiency filter cartridge if the recommended exposure limit is exceeded. Use self-contained
breathing apparatus for entry into confined space, for other poorly ventilated areas and for
large spill clean-up sites. Consult with an industrial hygienist to determine the appropriate
respiratory protection for your specific use of this material. A respiratory protection program
compliant with all applicable regulations must be followed whenever workplace conditions
require the use of a respirator.
Clothing Recommendation Gloves, coveralls, apron, boots as necessary to minimize contact. Wear either a chemical
protective suit or apron when potential for contact with material exists. Use chemically
protective boots when necessary to avoid contaminating shoes. Do not wear rings, watches or
similar apparel that could entrap the material and cause a skin reaction. Launder
contaminated clothing before reuse.
9 Physical and Chemical Properties
37 癈, 98.6 癋 PMCC (Typical)
Flash Point
Not determined.
Upper Flammable Limit
Not determined.
Lower Flammable Limit
Not determined.
Autoignition Point
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ULTRAZOL?8219CM
Material does not have explosive properties in the liquid state, but vapors may form
Explosion Data
explosive mixtures with air.
Not determined.
Vapor Pressure
Not determined.
pH
0.9 (15.6 癈)
Specific Gravity
Not determined.
Bulk Density
Insoluble.
Water Solubility
Not determined.
Percent Solid
Not determined.
Percent Volatile
Volatile Organic Compound Not determined.
Not determined.
Vapor Density
Not determined.
Evaporation Rate
Hydrocarbon
Odor
Clear light brown liquid.
Appearance
28 Centistokes (0 癈)
Viscosity
11 Centistokes (25 癈)
7.4 Centistokes (40 癈)
Not determined.
Odor Threshold
137 癈, 278.6 癋(Initial)
Boiling Point
< -57 癈, < -71 癋
Pour Point Temperature
Not determined.
Melting / Freezing Point
The above data are typical values and do not constitute a specification. Vapor pressure
data are calculated unless otherwise noted.
10 Stability and Reactivity
Material is normally stable at moderately elevated temperatures and pressures.
Stability
Not determined.
Decomposition Temperature
Strong oxidizing agents.
Incompatibility
Will not occur.
Polymerization
Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete
Thermal Decomposition
combustion.
Not determined.
Conditions to Avoid
11 Toxicological Information
-- ACUTE EXPOSURE --
Weak to moderate eye irritant. Does not meet EU R36 criteria. Based on data from similar
Eye Irritation
materials.
Skin irritant. Based on data from similar materials. Prolonged or repeated skin contact as
Skin Irritation
from clothing wet with material may cause dermatitis. Symptoms may include redness,
edema, drying, and cracking of the skin.
Nose, throat and lung irritant. Based on data from components or similar materials. Exposure
Respiratory Irritation
to a high concentration of vapor or mist is irritating to the respiratory tract.
The LD50 in rabbits is > 2000 mg/Kg. Based on data from components or similar materials.
Dermal Toxicity
Components of this material may be absorbed through the skin.
Inhalation Toxicity
High concentrations may cause headaches, dizziness, fatigue, nausea, vomiting, drowsiness,
stupor, other central nervous system effects leading to visual impairment, respiratory failure,
unconsciousness and death. The inhalation toxicity potential of certain components of this
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ULTRAZOL?8219CM
product are not completely understood. As a precaution avoid handling practices that could
result in prolonged or repeated inhalation exposure.
The LD50 in rats is > 5000 mg/Kg. Based on data from components or similar materials.
Oral Toxicity
Swallowing this material causes irritation of mouth, esophagus and stomach, with nausea,
vomiting, diarrhea and abdominal pain. Ingestion of this material may cause headache,
dizziness, uncoordination, and general weakness. Material can be aspirated into the lungs
during the act of swallowing or vomiting. This could result in severe injury to the lungs and
death.
May cause skin sensitization. Based on data from similar materials.
Dermal Sensitization
No data available to indicate product or components may be respiratory sensitizers.
Inhalation Sensitization
-- CHRONIC EXPOSURE --
Repeated overexposure to petroleum naphtha can cause nervous system damage. Xylene has
Chronic Toxicity
been found to cause cardiac, liver and kidney effects, anemia and eye damage in laboratory
animals. Prolonged and repeated inhalation of hydrocarbon solvents such as xylene can cause
chronic neurological disturbances. Chronic exposure to xylene has been shown to cause
hearing loss in experimental animals.
A two-year National Toxicology Program (NTP) study found an increased incidence of
Carcinogenicity
tumors of the nose in rats exposed to naphthalene by inhalation. In mice similarly exposed,
increased incidences of alveolar/bronchiolar adenomas were observed. Naphthalene has been
classified by the International Agency for Research on Cancer (IARC) as a possible human
carcinogen (Group 2B) on the basis of sufficient evidence of carcinogenicity in experimental
animals but inadequate evidence in exposed humans. A National Toxicology Program (NTP)
study found an increased incidence of renal tubule neoplasms in male and female rats
exposed to ethylbenzene by inhalation for two years. In male and female mice similarly
exposed, increased incidences of alveolar/bronchiolar neoplasms, and hepatocellular
neoplasms, respectively, were observed. Ethylbenzene has been classified by IARC as a
possible human carcinogen (Group 2B) on the basis of sufficient evidence of carcinogenicity
in experimental animals but inadequate evidence in exposed humans.
No data available to indicate product or any components present at greater than 0.1% are
Mutagenicity
mutagenic or genotoxic.
No data available to indicate either product or components present at greater than 0.1% that
Reproductive Toxicity
may cause reproductive toxicity.
Xylene is fetotoxic in rats and rabbits in the absence of maternal toxicity. Prolonged and
Teratogenicity
repeated exposure of pregnant animals to toluene by inhalation has been reported to cause
adverse fetal developmental effects.
-- ADDITIONAL INFORMATION --
No other health hazards known.
Other
12 Ecological Information
-- ENVIRONMENTAL TOXICITY --
The acute LC50 is 1 - 10 mg/L based on component data.
Freshwater Fish Toxicity
Freshwater Invertebrates
The acute EC50 is 1 - 10 mg/L based on component data.
Toxicity
The acute EC50 is 1 - 10 mg/L based on component data.
Algal Inhibition
Not determined.
Saltwater Fish Toxicity
Saltwater Invertebrates
Not determined.
Toxicity
Not determined.
Bacteria Toxicity
Not determined.
Miscellaneous Toxicity
-- ENVIRONMENTAL FATE --
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ULTRAZOL?8219CM
At least 25% of the components in this product show moderate biodegradation based on
Biodegradation
OECD 302-type test data.
10 ?25% of the components potentially bioconcentrate, based on octanol/water coefficients.
Bioaccumulation
Not determined.
Soil Mobility
13 Disposal Considerations
This material, if discarded, is a hazardous waste under RCRA Regulation 40 CFR 261.
Waste Disposal
Material, if discarded, is expected to be hazardous waste under RCRA due to ignitability
(D001). 0.005% Benzene, CAS no. 71-43-2, D018. Treatment, storage, transportation, and
disposal must be in accordance with applicable Federal, State/Provincial, and Local
regulations.
14 Transport Information
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
ICAO/IATA I
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
ICAO/IATA II
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
IMDG
F-E
IMDG EMS Fire
S-E
IMDG EMS Spill
*Subsection 4.2
IMDG MFAG
Not determined.
MARPOL Annex II
Not determined.
USCG Compatibility
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene) Class 3, PG III, RQ
U.S. DOT Bulk
(Naphthalene, Xylene)
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene) Class 3, PG III
U.S. DOT Non-Bulk
128
DOT NAERG
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
TDG Bulk
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
TDG Non-Bulk
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
Mexico
UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
Mexico Non-Bulk
85000 liters, 22457 gal.
Bulk Quantity
207.8 liters, 55 gal.
Non-Bulk Quantity
Review classification requirements before shipping materials at elevated temperatures.
15 Regulatory Information
-- Global Chemical Inventories --
All components of this material are on the US TSCA Inventory or are exempt.
USA
Section 8D (Benzene, ethyl-).Section 4A (Naphthalene).Section 4A (p-xylene).May be
Other TSCA Reg.
subject to export notification under TSCA Section 12(b).
All components are in compliance with the EC Seventh amendment Directive 92 /32/EEC.
EU
This product requires notification in Japan.
Japan
A component(s) of this product has been notified and assessed under the Industrial
Australia
Chemicals (Notification and Assessment) Act, 1989. This product may be imported only by
Lubrizol Australia.
May require notification before sale under New Zealand regulations.
New Zealand
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ULTRAZOL?8219CM
All components are in compliance with the Canadian Environmental Protection Act and are
Canada
present on the Domestic Substances List.
All components are in compliance with the Environmentally Hazardous Substances
Switzerland
Ordinance in Switzerland.
All components are in compliance in Korea.
Korea
All components are in compliance with the Philippines Toxic Substances and Hazardous and
Philippines
Nuclear Wastes Control Act of 1990 (R.A. 6969).
All components of this product are listed on the Inventory of Existing Chemical Substances
China
in China.
-- Other U.S. Federal Regulations --
This product does not contain greater than 1.0% of any chemical substance on the SARA
SARA Ext. Haz. Subst.
Extremely Hazardous Substances list.
28.7% Xylene (mixed isomers), CAS no. 1330-20-7; 7.2% Ethylbenzene, CAS no. 100-41-4;
SARA Section 313
1.4% Naphthalene, CAS no. 91-20-3
SARA 311 Classifications Acute Hazard Yes
Chronic Hazard Yes
Fire Hazard Yes
Reactivity Hazard No
CERCLA Hazardous
Substances Transit Reportable Quantities
Reportable Reportable
Component Units Units
Quantity RQ Quantity RQ
Naphthalene 951 gal. 3599 liters
Xylene 1857 gal. 7028 liters
Not applicable.
FDA Approval
-- State Regulations --
This product contains the following chemical(s) known to the state of California to cause
Cal. Prop. 65
cancer and/or birth defects: 0.005% Benzene, CAS no. 71-43-2 0.287% Toluene, CAS no.
108-88-3 1.4% Naphthalene, CAS no. 91-20-3 7.2% Ethylbenzene, CAS no. 100-41-4
-- Product Registrations --
This fuel additive is registered in the United States.
U.S. Fuel Registration
This product has not been filed with the USDA to support H2 approvals.
U.S. Dept of Agriculture
NSF Nonfood Compounds
This product has not been filed with the NSF to support H1 or H2 approvals.
Registration
Finnish Registration
Not Registered
Number
Swedish Registration
Not Registered
Number
Norwegian Registration
Not Registered
Number
Danish Registration
Not Registered
Number
Not Registered
Swiss Registration Number
Not Registered
Italian Registration Number
Korean Registration
Not Registered
Number
-- Other / International --
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ULTRAZOL?8219CM
None known.
TDG Regulated Limit.
16 Other Information
US NFPA Codes Health Fire Reactivity Special
2 3 0 N/E
(N/E) - None established
HMIS Codes Health Fire Reactivity
2* 3 0
Danger.
Precautionary Labels
Flammable liquid. may create a flash fire hazard.
Harmful if inhaled.
Causes skin irritation.
Causes respiratory tract irritation.
May be harmful if absorbed through skin.
May cause eye irritation.
May cause allergic skin reaction.
Contains components which may cause cancer.
May cause chronic health effects.
Revision Indicators Section: 2 Principal hazards. Changed: 24 June 2009
Section: 3 Hazardous ingredients. Changed: 1 April 2009
Section: 4 Inhalation first aid. Changed: 29 March 2009
Section: 4 Oral first aid. Changed: 29 March 2009
Section: 7 Handling procedures. Changed: 29 March 2009
Section: 7 Storage procedures. Changed: 29 March 2009
Section: 8 Clothing recommendations. Changed: 29 March 2009
Section: 8 Hazardous ingredients. Changed: 1 April 2009
Section: 8 Respiratory protection. Changed: 31 March 2009
Section: 9 Odor threshold. Changed: 1 April 2009
Section: 9 Percent volatile. Changed: 18 February 2009
Section: 11 Cacinogenicity. Changed: 24 June 2009
Section: 11 Chronic toxicity. Changed: 31 March 2009
Section: 11 Inhalation toxicity. Changed: 24 June 2009
Section: 11 Skin irritation. Changed: 24 June 2009
Section: 11 Teratogenicity. Changed: 18 February 2009
Section: 13 Waste disposal. Changed: 24 June 2009
Section: 14 IMDG Code shipping description. Changed: 29 March 2009
Section: 15 Cercla hazardous substances. Changed: 18 February 2009
Section: 15 U.S. Fuel registration. Changed: 2 September 2008
Section: 16 Principal hazards. Changed: 24 June 2009
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim
any liability for any use of this product. Information contained herein is believed to be true and accurate but all
statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the
hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all
applicable federal, state, and local regulations remains the responsibility of the user.
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