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Common Name: HARDHT LSPR 6PK GLOSS SMOKE GRAY, V2188838
Manufacturer: RUST-OLEUM
MSDS Revision Date: 4/16/2008
Grainger Item Number(s): 4CH77
Manufacturer Model Number(s):
MSDS Table of Contents
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SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
SECTION 3 - HAZARDS IDENTIFICATION
SECTION 4 - FIRST AID MEASURES
SECTION 5 - FIRE FIGHTING MEASURES
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SECTION 7 - HANDLING AND STORAGE
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 - STABILITY AND REACTIVITY
SECTION 11 - TOXICOLOGICAL INFORMATION
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL INFORMATION
SECTION 14 - TRANSPORTATION INFORMATION
SECTION 15 - REGULATORY INFORMATION
SECTION 16 - OTHER INFORMATION
MATERIAL SAFETY DATA SHEET
24 HOUR ASSISTANCE:
1-847-367-7700
RUST-OLEUM CORP.
WWW.RUSTOLEUM.COM
SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION
PRODUCT NAME: HARDHT LSPR 6PK GLOSS SMOKE GRAY
IDENTIFICATION NUMBER: V2188838
PRODUCT USE/CLASS: TOPCOAT/AEROSOLS
REVISION DATE: 04/16/2008
SUPPLIER:
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RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS NUMBER WEIGHT % LESS THAN
LIQUEFIED PETROLEUM GAS 68476-86-8 25.0
ACETONE 67-64-1 20.0
N-BUTYL ACETATE 123-86-4 10.0
XYLENE 1330-20-7 10.0
METHYL ETHYL KETONE 78-93-3 10.0
PROPYLENE GLYCOL MONOBUTYL ETHER 5131-66-8 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
ETHYLBENZENE 100-41-4 5.0
PIGMENT BLACK 7 1333-86-4 1.0
CHEMICAL NAME ACGIH ACGHI OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL CEILING
LIQUEFIED PETROLEUM GAS 1000 PPM N.E. 1000 PPM N.E.
ACETONE 500 PPM 750 PPM 750 PPM N.E.
N-BUTYL ACETATE 150 PPM 200 PPM 150 PPM N.E.
XYLENE 100 PPM 150 PPM 100 PPM N.E.
METHYL ETHYL KETONE 200 PPM 300 PPM 200 PPM N.E.
PROPYLENE GLYCOL MONOBUTYL N.E. N.E. N.E. N.E.
ETHER
TITANIUM DIOXIDE 10 MG/M3 N.E. 10 MG/M3 N.E.
ETHYLBENZENE 100 PPM 125 PPM 100 PPM N.E.
PIGMENT BLACK 7 3.5 MG/M3 N.E. 3.5 MG/M3 N.E.
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SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
CONTAINS AROMATIC DISTILLATE, WHICH MAY CAUSE CANCER. CONTENTS UNDER
PRESSURE. HARMFUL IF INHALED. MAY AFFECT THE BRAIN OR NERVOUS SYSTEM
CAUSING DIZZINESS, HEADACHE OR NAUSEA. HARMFUL IF SWALLOWED. EXTREMELY
FLAMMABLE LIQUID AND VAPOR. VAPORS MAY CAUSE FLASH FIRE OR EXPLOSION.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. SUBSTANCE MAY
CAUSE SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND
LUNGS. HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS
MAY BE HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. SUBSTANCE
MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). CONTAINS
TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-"POSSIBLY
CARCINOGENIC TO HUMANS" BY IARC.
SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH APPLICATION OR DRYING.
RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL OF EXPOSURE TO DUST FROM
REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE ACTUAL CONCENTRATION OF
TITANIUM DIOXIDE IN THE FORMULA.
MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E,G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH LIVER
ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO METHYL ETHYL KETONE IN LABORATORY ANIMALS HAS BEEN
ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY AND LUNG DAMAGE.
FETOTOXIC/EMBRYOTOXIC EFFECTS FROM INHALATION HAVE BEEN SEEN IN RATS
EXPOSED TO >1000 PPM DURING GESTATION. CONTAINS CARBON BLACK. CHRONIC
INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME
RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE
CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES.
TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND
HAMPSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4-"NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA.
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PRIMARY ROUTE(S) OF ENTRY:
SKIN CONTACT, SKIN ABSORPTION, INHALATION, INGESTION, EYE CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE CONTACT:
HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: -156 F (SETAFLASH)
LOWER EXPLOSIVE LIMIT: 0.7%
UPPER EXPLOSIVE LIMIT: 12.8%
EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
WATER SPRAY MAY BE INEFFECTIVE. FLASH POINT IS LESS THAN 20 DEG. F.
EXTREMELY FLAMMABLE LIQUID AND VAPOR!
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM
EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND
FLASH BACK. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER
MAY CAUSE BURSTING OF THE CAN.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
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CONTAINERS.
SECTION 7 - HANDLING AND STORAGE
HANDLING:
FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED BECAUSE
IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR OR MIST. WASH
THOROUGHLY AFTER HANDLING. USE ONLY IN A WELL-VENTILATED AREA. WASH HANDS
BEFORE EATING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I
FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE
ABOVE 120 DEG. F.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE
LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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BOILING RANGE: -34 - 415 F
VAPOR DENSITY: HEAVIER THAN AIR
ODOR: SOLVENT LIKE
ODOR THRESHOLD: ND
APPEARANCE: LIQUID
EVAPORATION RATE: FASTER THAN ETHER
SOLUBILITY IN H2O: SLIGHT
FREEZE POINT: ND
SPECIFIC GRAVITY: 0.826
VAPOR PRESSURE: ND
pH: NE
PHYSICAL STATE: LIQUID
(SEE SECTION 16 FOR ABBREVIATION LEGEND)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
SECTION 11 - TOXICOLOGICAL INFORMATION
PRODUCT LD50: ND
PRODUCT LC50: ND
CHEMICAL NAME LD50 LC50
LIQUEFIED PETROLEUM GAS N.D. N.D.
ACETONE N.D. N.D.
N-BUTYL ACETATE 13100 MG/KG 2000 PPM
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(ORAL, RAT) (INH 4 HR, RAT)
XYLENE 4300, MG/KG 5000 PPM/4 HR
(ORAL RAT) (INHALATION, RAT)
METHYL ETHYL KETONE N.D. N.D.
PROPYLENE GLYCOL MONOBUTYL ETHER 2200 MG/KG N.D.
(ORAL, RAT)
TITANIUM DIOXIDE >7500 MG/KG N.D.
(ORAL, RAT)
ETHYLBENZENE 3500 MG/KG N.D.
(ORAL, RAT)
PIGMENT BLACK 7 >8000 MG/KG N.D.
(ORAL, RAT)
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
SECTION 13 - DISPOSAL INFORMATION
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: AEROSOLS
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 2.1
DOT UN/NA NUMBER: UN1950
PACKING GROUP:
HAZARD SUBCLASS:
RESP. GUIDE PAGE: 126
SECTION 15 - REGULATORY INFORMATION
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA SECTION 313:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
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SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS NUMBER
XYLENE 1330-20-7
METHYL ETHYL KETONE 78-93-3
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE
UNITED STATES:
U.S. STATE REGULATIONS: AS FOLLOWS
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.
CHEMICAL NAME CAS NUMBER
ALKYD RESIN PROPRIETARY
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.
CHEMICAL NAME CAS NUMBER
ALKYD RESIN PROPRIETARY
BARIUM SULFATE 7727-43-7
CALIFORNIA PROPOSITION 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:
AB5
D2A
D2B
SECTION 16 - OTHER INFORMATION
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HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION X
REASON FOR REVISION: REGULATORY UPDATE
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH ALL
FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.
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