D61
MATERIAL SAFETY DATA SHEET Syrgis Performance
Initiators, Inc.
R-5 RED CONCENTRATE Helena, AR
SECTION 1 - IDENTIFICATION OF THE PRODUCT AND THE COMPANY
870-572-2935
PRODUCT NAME R-5 Red Concentrate TELEPHONE
Syrgis Performance Initiators, Inc. 800-424-9300
MANUFACTURER CHEMTREC (24hr) (USA)
334 Phillips 311 Rd., Helena, AR 72342 703-527-3887
ADDRESS (Maritime/International)
Mixture of 2-Napththalenol [(phenyl azo)
CHEMICAL NAME See section 2.
CAS NO.
phenyl] azo alkyl derivatives and 1,3- Mixture.
CHEMICAL FORMULA
Benzenediol, 2,4-bis [(alkylphenyl) azo] in
dimethyl phthalate and xylene
Diazo dye in xylene and DMP
CHEMICAL FAMILY
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NO. %
Dimethyl Phthalate 131-11-3 45
Xylene (mixed) 1330-20-7 19
Ethyl Benzene 100-41-4 3.5
2-Naphthalenol [(phenyl azo) phenyl] azo alkyl derivatives 32.5 for remaining
1,3-Benzenediol, 2,4-bis [(alkylphenyl) azo-] 2 ingredients
SECTION 3 - HAZARD IDENTIFICATION OF THE PREPARATION
Fire hazard, combustible liquid.
PHYSICAL HAZARDS
Irritant.
HEALTH HAZARDS
3
TWA - Xylene (mixed) 100 ppm, dimethyl phthalate 5 mg/m .
EXPOSURE LIMITS
ROUTES OF EXPOSURE
May cause irritation, and will stain the skin red.
Skin Contact
Eye contact may cause inflammation.
Eye Contact
May cause human systemic effects by ingestion.
Ingestion
May cause respiratory distress. May affect the brain or nervous system causing
Inhalation
dizziness, headache or nausea.
Reports have associated repeated and prolonged occupational overexposure to
EFFECTS OF OVER-EXPOSURE
solvents with permanent brain and nervous system damage.
SECTION 4 - FIRST-AID MEASURES
Wash contaminated area thoroughly with soap and water.
SKIN
Remove any contact lenses at once. Flush eyes with water for at least 15 minutes
EYES
and seek medical attention.
INGESTION Contact a physician, hospital or Poison Control Center at once. DO NOT INDUCE
VOMITING.
Immediately remove to fresh air, if coughing, breathing becomes labored, irritation
INHALATION
develops or other symptoms develop, seek medical attention at once, even if
symptoms develop several hours after the exposure.
SECTION 5 - FIRE-FIGHTING MEASURES
104癋 (40癈), SETA CC
FLASH POINT
LEL 1% - UEL 7%
FLAMMABLE LIMITS
Not established.
AUTOIGNITION POINT
Water from a safe distance - preferably with a fog nozzle. In case of very small fires,
EXTINGUISHING MEDIA
other means such as carbon dioxide, foam or dry chemical extinguishers may be
effective.
Firemen should be equipped with protective clothing and SCBA's. In case of fire
SPECIAL FIRE FIGHTING
near storage area, cool the containers with water spray.
PROCEDURES
During a fire, irritating and highly toxic gases may be generated by combustion.
UNUSUAL FIRE AND EXPLOSION
Residue from fire or spill is a red dye.
HAZARDS
Revised on: 9/18/07 Printed On: 9/18/2007 Page 1 of 4
MATERIAL SAFETY DATA SHEET
R-5 Red Concentrate
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Evacuate area of all unnecessary personnel. Remove all sources of ignition. Refer
STEPS TO BE TAKEN IN EVENT
to protective measures listed in sections 7 and 8. Spilled material should be swept
OF SPILL OR RELEASE
up with an inert, moist diluent such as perlite, vermiculite, or sand. Keep spilled
material from entering drains, sewers, streams, etc. Carefully collect the material
using non-sparking tools and transfer into a clean polyethylene lined or a
polyethylene drum disposal container. Label container and store in a secure area for
proper disposal. Prevent material from entering drains, sewers, streams, etc.
SECTION 7 - HANDLING AND STORAGE
Keep containers tightly closed. Rotate stock using the oldest material first. Take
HANDLING
precautionary measures against static discharge. DO NOT USE NEAR FOOD OR
DRINK. Avoid skin and eye contact. Avoid breathing vapors and use with adequate
ventilation. Wear personal protection equipment recommended in section 8. Reseal
containers immediately after use.
Keep material in its original container away from any incompatible materials, direct
STORAGE
sunlight or other sources of heat. DO NOT STORE WITH FOOD OR DRINK. Store
in an isolated, cool and well-ventilated area.
Containers of this material may be hazardous when empty since they retain product
OTHER PRECAUTIONS
residues, observe all warnings and precautions listed. Use good personal hygiene
practices. Wash hands before eating, drinking, smoking, or using toilet facilities.
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
Use with adequate ventilation.
VENTILATION
If airborne concentrations are expected to exceed acceptable levels wear a NIOSH
RESPIRATORY PROTECTION
approved air-purifying respirator with an organic vapor cartridge or canister. When
using respirators refer to OSHA' 29CFR 1910.134. In case of spill or leak of
s
unknown concentration, use NIOSH approved supplied air respirator.
Safety goggles recommended, goggles with a face shield are preferred.
EYE PROTECTION
Protective gloves recommended, solvent resistant.
HAND PROTECTION
A safety shower and eyewash is highly recommended when the risk of a significant
OTHER
exposure exits.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Intensely red liquid, slight aromatic odor.
APPEARANCE AND ODOR:
280癋 (138癈) 1.1 (Water = 1)
BOILING POINT: SPECIFIC GRAVITY:
5mmHG @ 65癋
VAPOR PRESSURE: FLASH POINT: 104癋 (40癈),SETA CC
>1 LEL 1% - UEL 7%
VAPOR DENSITY: FLAMMABLE LIMITS:
9.5 (ethyl ether = 1) Not applicable.
EVAPORATION RATE: SADT:
67 Not applicable.
% VOLATILE BY VOLUME: pH:
Insoluble.
SOLUBILITY IN WATER:
SECTION 10 - STABILITY AND REACTIVITY
Stable under normal conditions of use.
STABILITY
Storage in direct sunlight, high temperatures, flames, sparks. Prevent product
CONDITIONS TO AVOID
contamination.
Oxidizers, acids. May react with reducing agents to liberate free amine(s).
MATERIALS TO AVOID
Unknown.
HAZARDOUS DECOMPOSITION
PRODUCTS
Will not occur.
HAZARDOUS POLYMERIZATION
Syrgis Performance Initiators, Inc. Page 2 of 4
MATERIAL SAFETY DATA SHEET
R-5 Red Concentrate
SECTION 11 - TOXICOLOGICAL INFORMATION
Dimethyl Phthalate
Hazard Data:
Inhalation: Cat--LCLo: 9300 mg/m 3/6.5 hr.
Intraperitoneal: Mouse--LD50: 1380 mg/kg.
Oral: Rat & Mouse--LD50: 6800 mg/kg, somnolence behavioral, withdrawal nutritional and gross metabolic, weight
loss or decreased weight gain; Dog--LD: >1400 mg/kg; Rabbit--LD50: 4400 L/kg.
Subcutaneous: Mouse--LDLo: 6500 mg/kg, dyspnea lung, thorax, respiration, or cyanosis.
Xylene
Hazard Data:
Inhalation: Rat--LC50: 5000 ppm/4-hours
Oral: Rat--LD50: 4300 mg/kg
Ethyl Benzene
Hazard Data:
Dermal: Rabbit--LD50: 17800 mg/kg.
Oral: Rat--LD50: 3500 mg/kg,.
SECTION 12 - ECOLOGICAL INFORMATION
No data is available on the preparation itself. The product should be prevented from entering drains, sewers, streams, etc.
SECTION 13 - DISPOSAL CONSIDERATIONS
Prevent material from entering drains, sewers, streams, etc.
Immediately dispose of waste material at a RCRA approved hazardous waste management facility in accordance with
federal, state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
By Ground By Air or Sea
DOT Shipping Name: COMBUSTIBLE LIQUID, N.O.S. DOT Shipping Name: FLAMMABLE LIQUID, N.O.S.
(XYLENE) (XYLENE)
DOT Hazard Class: NA DOT Hazard Class: 3
UN/NA ID No.: NA1993 UN/NA ID No.: UN1993
DOT Packing Group: PG III DOT Packing Group: PG III
2004 ERG GUIDE NO.: 128
SECTION 15 - REGULATORY INFORMATION
The following chemicals are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR Part 372.
Chemical Name CAS Number Percent
Dimethyl Phthalate 131-11-3 45
Xylene 1330-20-7 19
Ethyl Benzene 100-41-4 3.5
Reportable Quantities
Xylene: 100 lbs (45.4 kg)
Ethyl Benzene: 1000 lbs (454 kg)
Australian Inventory of Chemical Substances (AICS)
The ingredients in this product are listed in the Australian AICS Inventory.
Canadian Domestic Substances List (DSL)
The ingredients in this product are listed in the Canadian DSL Inventory.
Chinese Inventory of Existing Chemical Substances Manufactured or Imported in China (IECSC)
The ingredients in this product are listed in the Chinese IECSC Inventory.
European Inventory of Existing Commercial Chemical Substances (EINECS)
The ingredients in this product are listed in the European EINECS Inventory.
Syrgis Performance Initiators, Inc. Page 3 of 4
MATERIAL SAFETY DATA SHEET
R-5 Red Concentrate
US Toxic Substances Control Act (TSCA)
The ingredients in this product are listed in the US TSCA Inventory.
Status of Carcinogicity
Not recognized as a carcinogen by the IARC, NTP or OSHA.
SECTION 16 - OTHER INFORMATION
VOC Information
Using ASTM Test Method D-2369-87, R-5 Red Concentrate contains 51.9% VOC, by weight, or 571 grams per liter. For
more information, call Syrgis Performance Initiators, Inc.
NFPA 704 Rating HMIS Rating
Health Flammability Reactivity Health Flammability Reactivity
2 2 0 2 2 0
MSDS Reference: R-5 MSDS 0709
DISCLAIMER OF LIABILITY
The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly
disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Syrgis Performance Initiators, Inc. Page 4 of 4
|