Product Name: KEROSENE
Revision Date: 08May2007
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SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
As of the revision date above, this (M)SDS meets the regulations in the United Kingdom & Ireland.
PRODUCT
Product Name: KEROSENE
Product Description: Petroleum Hydrocarbons
Product Code: 7033158-60
Intended Use: Fuel
COMPANY IDENTIFICATION
Supplier: Esso Petroleum Company, Limited
ExxonMobil House
Ermyn Way
KT22 8UX Leatherhead, Surrey
United Kingdom
24 Hour Environmental / Health Emergency 01372 222 000 (UK) / +44 1372 222 000 (Ireland)
Telephone
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
This material is regulated as a complex substance.
Reportable Hazardous Substance(s) or Complex Substance(s)
Name CAS# EINECS / Concentration* Symbols/Risk
ELINCS Phrases
KEROSENE 8008-20-6 232-366-4 > 99% R10, Xi;R38, Xn;R65,
N;R51/53, Note H
Reportable Hazardous Constituent(s) Contained in Complex Substance(s)
Name CAS# EINECS / Concentration* Symbols/Risk
ELINCS Phrases
ETHYL BENZENE 100-41-4 202-849-4 0.1 - 1% F;R11, Xn;R20
Naphthalene 91-20-3 202-049-5 < 1% Xn;R22, Xn;Carc. Cat.
3;R40, N;R50/53
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
SECTION 3 HAZARDS IDENTIFICATION
This material is dangerous according to regulatory guidelines (see (M)SDS Section 15).
CLASSIFICATION: | R10 | Xn; R65 | Xi; R38 | N; R51/53 |
PHYSICAL / CHEMICAL HAZARDS
Flammable. Material can release vapours that readily form flammable mixtures. Vapour accumulation could
flash and/or explode if ignited. Material can accumulate static charges which may cause an incendiary
electrical discharge.
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HEALTH HAZARDS
Harmful: may cause lung damage if swallowed. Irritating to skin. May be irritating to the eyes, nose, throat,
and lungs. Breathing of high vapour concentrations may cause dizziness, light-headedness, headache, nausea
and loss of co-ordination. Continued inhalation may result in unconsciousness. High-pressure injection under
skin may cause serious damage.
ENVIRONMENTAL HAZARDS
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from
person to person.
SECTION 4 FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be evaluated immediately by a physician as a
surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early
surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Hydrocarbon Solvents/Petroleum Hydrocarbons- Skin contact may aggravate an existing dermatitis.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams,
Product Name: KEROSENE
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sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Unusual Fire Hazards: FLAMMABLE. Hazardous material. Firefighters should consider protective equipment
indicated in Section 8. Vapour is flammable and heavier than air. Vapour may travel across the ground and
reach remote ignition sources, causing a flashback fire danger.
Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon, Smoke, Fume,
Aldehydes, Sulphur Oxides
FLAMMABILITY PROPERTIES
Flash Point [Method]: >38C (100F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 5.0
Autoignition Temperature: 250?(482?br>
C F)
SECTION 6 ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See Section
3 for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment.
SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if
you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or
walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-
suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills:
Water spray may reduce vapour, but may not prevent ignition in enclosed spaces.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. If the Flash Point exceeds
the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by
skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient
Temperature by 10 deg C or is less than the Ambient Temperature, use booms as a barrier to protect
shorelines and allow the material to evaporate. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
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SECTION 7 HANDLING AND STORAGE
HANDLING
Avoid all personal contact. Do not siphon by mouth. Use proper bonding and/or earthing procedures. Do not
use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other
electronic devices etc) in or around any fuelling operation or storage area unless the devices are certified
intrinsically safe by an approved national testing agency and to the safety standards required by national and/or
local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate
static charges which may cause an electrical spark (ignition source).
Static Accumulator: This material is a static accumulator.
STORAGE
Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release.
Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Drums must be
earthed and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name Form Limit/Standard Note Source Year
ETHYL BENZENE STEL 552 mg/m3 125 ppm Skin UK EH40 2005
ETHYL BENZENE TWA 441 mg/m3 100 ppm Skin UK EH40 2005
ETHYL BENZENE STEL 125 ppm ACGIH 2006
ETHYL BENZENE TWA 100 ppm ACGIH 2006
KEROSENE Stable TWA 5 mg/m3 ExxonMobil 2006
Aerosol.
KEROSENE Total TWA 500 mg/m3 ExxonMobil 2006
vapour
and
aerosol.
KEROSENE Vapour TWA 500 mg/m3 100 ppm ExxonMobil 2006
and
aerosol.
KEROSENE [total hydrocarbon Non- TWA 200 mg/m3 Skin ACGIH 2006
vapour] Aerosol
Naphthalene STEL 15 ppm Skin ACGIH 2006
Naphthalene TWA 10 ppm Skin ACGIH 2006
Information about recommended monitoring procedures can be obtained from the following agency(ies)/institute(s):
France L'Institut National de Recherche et de S閏urit?(INRS) Germany Berufsgenossenschaftliches
Institut f黵 Arbeitssicherheit (BIA) UK Health and Safety Executive (HSE)
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
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PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Type A filter material
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
gloves. Nitrile, Viton, CEN standards EN 420 and EN 374 provide general requirements and lists of
glove types.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Liquid
Colour: Pale yellow
Odour: petroleum/solvent
Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.775 - 0.83
Flash Point [Method]: >38C (100F) [ ASTM D-93]
Product Name: KEROSENE
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Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 5.0
Autoignition Temperature: 250?(482?br>
C F)
Boiling Point / Range: > 200C (392F)
Vapour Density (Air = 1): N/D
Vapour Pressure: < 0.133 kPa (1 mm Hg) at 20?C
Evaporation Rate (N-Butyl Acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 1.1 cSt (1.1 mm?sec) at 40?br>
C
Oxidising properties: See Sections 3, 15, 16.
OTHER INFORMATION
Freezing Point: -47?(-53?br>
C F)
Melting Point: N/A
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
MATERIALS TO AVOID: Halogens, Strong Acids, Alkalies, Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity
Route of Exposure Conclusion / Remarks
INHALATION
Toxicity: LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: No end point data. Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs. Based on assessment of the components.
INGESTION
Toxicity: LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Skin
Toxicity: LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: Data available. Moderately irritating to skin with prolonged exposure. Based on
test data for structurally similar materials.
Eye
Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.
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CHRONIC/OTHER EFFECTS
For the product itself:
Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory
tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous
system effects including death. Small amounts of liquid aspirated into the lungs during ingestion or from
vomiting may cause chemical pneumonitis or pulmonary edema.
Contains:
Kerosene: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is
due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in
humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation
of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high
concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung
function. Non-sensitizing in animal tests. NAPHTHALENE: Exposure to high concentrations of naphthalene
may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory
animal studies, but the relevance of these findings to humans is uncertain. Ethylbenzene: Caused cancer in
laboratory animal studies. The relevance of these findings to humans is uncertain.
Additional information is available by request.
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
MOBILITY
More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and
wastewater solids.
High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Majority of components -- Expected to be inherently biodegradable
Atmospheric Oxidation:
More volatile component -- Expected to degrade rapidly in air
BIOACCUMULATION POTENTIAL
Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
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laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 13 07 03
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).
This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and
subject to the provisions of that Directive unless Article 1(5) of that Directive applies.
Empty Container Warning (where applicable): Empty containers may retain residue and can be dangerous. DO NOT
PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE
INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should
be completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be
disposed of in an environmentally safe manner and in accordance with governmental regulations.
SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID)
Proper Shipping Name: KEROSENE
Hazard Class: 3
Classification Code: F1
UN Number: 1223
Packing Group: III
Label(s) / Mark(s): 3
Hazard ID Number: 30
CEFIC Tremcard: 30S1223
Hazchem EAC: 3Y
Transport Document Name: UN1223, KEROSENE, 3, PG III
INLAND WATERWAYS (ADNR)
Proper Shipping Name: KEROSENE
Hazard Class: 3
Hazard ID Number: 30
UN or ID Number: 1223
Packing Group: III
Label(s) / Mark(s): 3
Transport Document Name: UN1223, KEROSENE, 3, PG III
SEA (IMDG)
Proper Shipping Name: KEROSENE
Hazard Class & Division: 3
UN Number: 1223
Packing Group: III
Label(s): 3
Product Name: KEROSENE
Revision Date: 08May2007
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EMS Number: F-E, S-E
Transport Document Name: UN1223, KEROSENE, 3, PG III, (38?c.c.)
C
AIR (IATA)
Proper Shipping Name: KEROSENE
Hazard Class & Division: 3
UN Number: 1223
Packing Group: III
Label(s): 3
Transport Document Name: UN1223, KEROSENE, 3, PG III
SECTION 15 REGULATORY INFORMATION
Material is dangerous as defined by the EU Dangerous Substances/Preparations Directives.
CLASSIFICATION: Flammable. Harmful. Irritant. Dangerous for the environment.
EU LABELING:
Symbol: Xn, N
Harmful. Dangerous for
the environment.
Nature of Special Risk: R10; Flammable. R65; Harmful: may cause lung damage if swallowed. R38; Irritating
to skin. R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Advice: S23; Do not breathe vapour. S24; Avoid contact with skin. S36/37; Wear suitable protective
clothing and gloves. S43; In case of fire use carbon dioxide (CO2), foam, dry chemical, or water fog. S61;
Avoid release to the environment. Refer to special instructions/safety data sheets. S62; If swallowed, do not
induce vomiting: seek medical advice immediately and show this container or label.
Contains: KEROSENE
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS
Complies with the following national/regional chemical inventory requirements: AICS, DSL, EINECS,
ENCS, KECI, PICCS, TSCA
SECTION 16 OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
R10; Flammable.
R11; Highly flammable.
R20; Harmful by inhalation.
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R22; Harmful if swallowed.
R38; Irritating to skin.
R40; Limited evidence of a carcinogenic effect.
R50/53; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65; Harmful: may cause lung damage if swallowed.
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
No revision information is available.
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
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Internal Use Only
MHC: 1A, 0, 0, 0, 3, 1 PPEC: C
DGN: 2028424XGB (1013454)
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