Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMBOND (CURATIVE) 1 US GAL
Product code : 156347 801
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Curative
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Clear. Liquid. May cause slight irritation to the respiratory system. Move to fresh air. If required, artificial
respiration or administration of oxygen can be performed by trained personnel. Remove to fresh air. Get
immediate medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause gastrointestinal irritation, nausea, and vomiting. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause itching, reddening, inflammation. May cause severe burns, blistering and skin
:
damage. May cause sensitization resulting in irritation, itching and redness. May cause a
rash.
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
May cause sensitization by contact. Prolonged skin contact may cause irritation, burns or dermatitis. Repeated
overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless suitable
engineering controls and/or personal protective equipment are used. May aggravate persons sensitized to
amines. Diethylenetriamine is a skin and eye irritant. Prolonged and repeated exposure can cause skin
sensitization, dermatitis, asthma. Fillers are encapsulated and not expected to be released from product under
normal conditions of use.
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Epoxy-fatty acid modified polyethylene
NJ TSRN# 51721300-5148P > 60.0
polyamines
Furfuryl alcohol 98-00-0 15.0 - 40.0
Bisphenol A 80-05-7 5.0 - 10.0
Diethylaminoethanol 100-37-8 3.0 - 7.0
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Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
Tetraethylene pentamine 112-57-2 3.0 - 7.0
Diethylenetriamine 111-40-0 3.0 - 7.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Remove to fresh air. Get immediate medical
attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : 79 ?174 ?br>
C, F
Method : Pensky-Martens Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke, fumes.Nitrogen
products oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Vapors may
travel to sources of ignition and flashback.Vapor concentrations in
enclosed areas may ignite explosively.Empty containers may contain
ignitable vapors.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when
not in use. Precautions also apply to emptied containers. Do not smoke, weld, generate sparks, or use flame
near container. Do not use in confined or poorly ventilated areas. Personal protective equipment must be worn
during maintenance or repair of contaminated mixer, reactor, or other equipment. Store under dry warehouse
conditions away from heat and all ignition sources.
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Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear NIOSH/MSHA approved vapor respirator with appropriate cartridge
when the vapor concentration is expected to exceed exposure limits indicated
on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Skin and body protection : Prevent contact with shoes and clothing. Use rubber apron and overshoes.
Protective measures : Inspect and replace equipment at regular intervals.Use professional judgment
in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Furfuryl alcohol 98-00-0 ACGIH TWA: 10 ppm
ACGIH STEL: 15 ppm
OSHA PEL: 200 mg/m3
Diethylaminoethanol 100-37-8 ACGIH TWA: 2 ppm
OSHA PEL: 50 mg/m3
Diethylenetriamine 111-40-0 ACGIH TWA: 1 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Clear
Odor : Oxime
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Partially soluble
Specific Gravity :1
% Volatile Weight : 0%
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Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Oxidizing agents.Epoxies.Isocyanates.Acids.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Furfuryl alcohol, CAS-No.: 98-00-0
Acute oral toxicity (LD-50 oral) 275 mg/kg ( Rat )
Bisphenol A, CAS-No.: 80-05-7
Acute oral toxicity (LD-50 oral) 3,300 mg/kg ( Rat )
Diethylaminoethanol, CAS-No.: 100-37-8
Acute oral toxicity (LD-50 oral) 1,300 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 1,260 mg/kg ( Rabbit )
Tetraethylene pentamine, CAS-No.: 112-57-2
Acute oral toxicity (LD-50 oral) 2,100 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 660 mg/kg ( Rabbit )
Diethylenetriamine, CAS-No.: 111-40-0
Acute oral toxicity (LD-50 oral) 1,080 mg/kg ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Subject to hazardous waste treatment, storage, and disposal requirements under
RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in
compliance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Contains Aliphatic Amine), 8, UN3267, PG III
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
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Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
U.S. Federal Regulations:
SARA 313 Components : Bisphenol A 80-05-7
SARA 311/312 Hazards : Acute Health Hazard
Fire Hazard
OSHA Hazardous Components :
Furfuryl alcohol 98-00-0
Bisphenol A 80-05-7
Diethylaminoethanol 100-37-8
Diethylenetriamine 111-40-0
OSHA Status: Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : IIIA
Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : 0%
U.S. State Regulations:
MASS RTK Components : Furfuryl alcohol 98-00-0
Bisphenol A 80-05-7
Diethylaminoethanol 100-37-8
Tetraethylene pentamine 112-57-2
Diethylenetriamine 111-40-0
Penn RTK Components : Epoxy-fatty acid modified polyethylene NJ TSRN# 51721300-5148P
polyamines
Furfuryl alcohol 98-00-0
Bisphenol A 80-05-7
Diethylaminoethanol 100-37-8
Tetraethylene pentamine 112-57-2
Diethylenetriamine 111-40-0
NJ RTK Components : Epoxy-fatty acid modified polyethylene NJ TSRN# 51721300-5148P
polyamines
Furfuryl alcohol 98-00-0
Bisphenol A 80-05-7
Diethylaminoethanol 100-37-8
Tetraethylene pentamine 112-57-2
Diethylenetriamine 111-40-0
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
None known.
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Material Safety Data Sheet
TREMBOND (CURATIVE) 1 US GAL
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 3 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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