Huntsman Advanced Materials Americas Inc.
P.O. Box 4980
The Woodlands, TX 77387-4980
8 am to 5 pm Phone: (800) 257-5547
24-Hour Emergency Phone: (800) 328-8501
International Emergency Phone: (409) 727-0831
Asia Pacific Emergency Phone: (65) 6336-6011
MSDS No: 5634
Effective Date: 10/30/07 Material Safety Data Sheet
Health: 3
1. PRODUCT IDENTIFICATION 1
Flammability: 1
3 0
Reactivity: 0
Trade Name: Araldite 2040/B
Personal Protection:
Chemical Family: Polyol
HMIS RATING
NFPA RATING
Intended Use or Product Type: Two Part Urethane Hardener.
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 102-60-3 2-Propanol, 1,1',1'',1'''-(1,2- NE NE NE NE NE NR NR NR
ethanediyldinitrilo)tetrakis-
Common Amine based tetrol
Name:
Concentration 1.00 - 5.00 % by wt
* 14808-60-7 Quartz (SiO2) 0.05 NE 0.1 NE NE Yes Yes NR
mg/m3 mg/m3
Common Crystalline silica
Name:
Concentration 0.10 - 1.00 % by wt
* 3077-13-2 2-Propanol-1,1'-(phenylamino)bis NE NE NE NE NE NR NR NR
Common 2-Hydroxypropyl aniline
Name:
Concentration 5.00 - 10.00 % by wt
* 36890-68-3 2-Oxepanone, polymer with 2,2'- NE NE NE NE NE NR NR NR
oxybis[ethanol]
Common Polycaprolactone polyol
Name:
Concentration 5.00 - 10.00 % by wt
* 69102-90-5 Homopolymer, hydroxy terminated NE NE NE NE NE NR NR NR
1,3-butadiene
Common Polybutadiene polyol
Name:
Concentration 15.00 - 40.00 % by wt
* 694-83-7 1,2-Cyclohexanediamine NE NE NE NE NE NR NR NR
Common 1,2-Diaminocyclohexane
Name:
Concentration 1.00 - 5.00 % by wt
* 8001-79-4 Castor Oil NE NE NE NE NE NR NR NR
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
Common Castor oil
Name:
Concentration 1.00 - 5.00 % by wt
* 919-30-2 1-Propanamine, 3-(Triethoxysilyl)- NE NE NE NE NE NR NR NR
Common Aminosilane
Name:
Concentration 1.00 - 5.00 % by wt
94-96-2 2-Ethyl-1,3-hexanediol NE NE NE NE NE NR NR NR
Common 2-Ethyl-1,3-hexanediol
Name:
Concentration 3.00 - 7.00 % by wt
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Corrosive - Causes eye burns and skin irritation.
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
Chronic: Contains crystalline silica. Breathing dust may cause cancer and delayed lung injury.
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Seek immediate medical attention.
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes. Seek immediate medical attention.
Inhalation: Remove to fresh air. Seek immediate medical attention.
Eyes: Immediately flush eyes with water for at least 15 minutes. Seek immediate medical attention.
Overexposure Effects: Corrosive - causes eye burns. Causes skin irritation.
Medical Conditions Aggravated by Exposure: Skin and eye conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
> 200癋 (> 93 癈)
Flash Point:
Estimated
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Danger!
Precautions: Corrosive - causes eye burns. Can cause skin irritation. Do not get in eyes. Avoid breathing vapor or mist. Avoid
contact with skin and clothing. Keep container closed when not in use. Use with adequate ventilation. Wash thoroughly after
handling. Notice! Contains crystalline silica. Breathing dust may cause cancer and delayed lung injury.
Other Handling Information: Crystalline silica may be generated when machining cured products. Overexposure may create
possible cancer and silicosis hazard.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Grey
Color:
Mild
Odor:
Paste
Physical State:
Slight
Solubility in Water:
Not Determined
Vapor Pressure:
1.23 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Melting Point:
Not Determined
Evaporation Rate:
Not Determined
Density:
Not Determined
Vapor Density:
Not Determined
pH:
Not Determined
Coefficient of water/oil:
Percent Volatile: Not determined.
10. STABILITY AND REACTIVITY
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Carcinogenicity: This product contains crystalline silica. Repeated inhalation of respirable free crystalline silica dust may cause
delayed lung injury (silicosis) and cancer.
Skin Irritation: Irritant.
Eye Irritation: Corrosive. Causes burns.
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Not Regulated
Proper Shipping Name:
IMDG: Non-Bulk
Not Regulated
Proper Shipping Name:
TDG: Non-Bulk
Not Regulated
Proper Shipping Name:
IATA: Non-Bulk
Not Regulated
Proper Shipping Name:
Motor Freight Classification Resin compounds, N.O.I.
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical
under that standard.
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).
SARA Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic
chemical release reporting under Section 313 (40 CFR 372).
TSCA Section 8(b) - Inventory Status: All chemical components of this product are in compliance with TSCA inventory
requirements.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
International Regulations:
Canadian Inventory Status: This product contains only chemicals that are currently listed on the Canadian Domestic Substance
List.
Canadian WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations. D2A D2B
State Regulations:
California Proposition 65: The following is required composition information. This product contains the following chemical(s)
which are currently listed on the California list of Known Carcinogens and Reproductive Toxins:
Chemical Name: Quartz (SiO2)
Common Name: Crystalline silica
CAS Number: 14808-60-7
Percent in Composition: 0.1 - 1 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Benzene, methyl-
Common Name: Toluene
CAS Number: 108-88-3
Percent in Composition: 0.0034 % by wt
Comment: Warning! This chemical is known to the State of California to cause birth defects or other reproductive harm.
Chemical Name: Cyclohexene, 4-ethenyl-
Common Name: Vinyl cyclohexane
CAS Number: 100-40-3
Percent in Composition: 0.0018 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: 1,3-Butadiene
Common Name: Butadiene
CAS Number: 106-99-0
Percent in Composition: 0.0002 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Arsenic
CAS Number: 7440-38-2
Percent in Composition: 0 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer and birth defects or other reproductive
harm.
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
Chemical Name: Lead
CAS Number: 7439-92-1
Percent in Composition: 0 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer and birth defects or other reproductive
harm.
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Homopolymer, hydroxy terminated 1,3-butadiene
Common Name: Polybutadiene polyol
CAS Number: 69102-90-5
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Carbonic Acid Calcium Salt (1:1)
Common Name: Calcium carbonate
CAS Number: 471-34-1
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2-Oxepanone, polymer with 2,2'-oxybis[ethanol]
Common Name: Polycaprolactone polyol
CAS Number: 36890-68-3
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2-Propanol-1,1'-(phenylamino)bis
Common Name: 2-Hydroxypropyl aniline
CAS Number: 3077-13-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2-Ethyl-1,3-hexanediol
Common Name: 2-Ethyl-1,3-hexanediol
CAS Number: 94-96-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Titanium Oxide
Common Name: Titanium dioxide
CAS Number: 13463-67-7
Comment: Hazardous Substance
16. OTHER INFORMATION
5634
MSDS No:
Dianne Blessing
Approved By:
EHS Specialist
Title:
Disclaimer: The information and recommendations contained herein are based upon tests in controlled laboratory conditions, are
believed to be correct, and are provided for the sole purpose of hazard communication as part of Huntsman's product safety
program. This product has not been tested for, and therefore is not recommended or suitable for, uses for which prolonged contact
with mucous membranes, abraded skin, or blood is intended or likely, or for uses for which implantation within the human body is
intended, and Huntsman assumes no liability for any such uses.
The information and recommendations contained herein are not intended to constitute performance information concerning the
product, which is available in separate technical data sheets available from Huntsman upon request. Users are urged, and are urged
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Araldite 2040/B Huntsman Advanced Materials
Effective Date: 10/30/07 Americas Inc. (EL)
to urge others who may come in contact with the product, to obtain and consult data sheets prior to purchase, use, transportation or
storage of the product.
HUNTSMAN MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY, QUALITY, OR FITNESS FOR A PARTICULAR PURPOSE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED TO REIMBURSEMENT OF BUYER'S PURCHASE PRICE, OR IN HUNTSMAN'S DISCRETION
REPLACEMENT, OF THE PRODUCT IN RESPECT OF WHICH SUCH CLAIM IS MADE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED BY LEGAL NOTICES IN TECHNICAL DATA SHEETS, PRODUCT LITERATURE, AND/OR SALE
DOCUMENTS. The foregoing DISCLAIMERS and LIMITATION OF LIABILITY supercede inconsistent or contradictory
provisions in Buyer's documents.
USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENTAL AGENCY TO DETERMINE
THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT. HUNTSMAN
DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO
PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO
PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS,
WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE
MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT
THE ABOVE ADDRESS.
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