MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
PRODUCT NAME: RL620
OTHER NAMES: NONE
RECOMMENDED USE: Boiler return line treatment.
SUPPLIER NAME: CAMPBELL CLEANTEC (ABN 92 009 657 489)
AUSTRALIA: NEW ZEALAND:
ADDRESS: 32 PERIVALE STREET, LEVEL 3, 52 SWANSON STREET,
DARRA, QLD, 4076 AUCKLAND, 1010
TELEPHONE: GENERAL ENQUIRIES: + 61 7 3710 3200 NZ: (09) 379 8745
CUSTOMER SERVICE: 1800 077 240 NZ: (09) 379 8745
FAX: GENERAL ENQUIRIES: + 61 7 3710 3210 NZ: (09) 336 1354
CUSTOMER SERVICE: + 61 7 3710 3207 NZ: (09) 336 1354
EMERGENCY TELEPHONE NUMBER: AUSTRALIA: 1800 628 724 (ALL HOURS)
NEW ZEALAND: 0800 734 607 (ALL HOURS)
ALL OTHER INTERNATIONAL: + 61 7 3710 3184 (ALL HOURS)
2. HAZARDS IDENTIFICATION
Classified as hazardous according to the criteria of ASCC.
HAZARD
Classified as a dangerous good UN 3267 according to the criteria of ADG Code (see section 14).
CLASSIFICATION:
Not classified as a scheduled poison according to the criteria of SUSDP (see section 15).
HAZARD CATEGORY: Xn ?Harmful; C ?Corrosive; Xi - Irritant
R20/21/22 ?Harmful by inhalation, in contact with skin and if swallowed.
RISK PHRASES:
R34 ?Causes burns.
R37 ?Irritating to respiratory system.
R41 ?Risk of serious eye damage.
S1/2 ?Keep locked up and out of the reach of children.
SAFETY PHRASES:
S7 ?Keep container tightly closed.
S16 ?Keep away from sources of ignition ?No smoking.
S23 ?Do not breathe vapour.
S24/25 ?Avoid contact with eyes and skin.
S26 ?In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 ?After contact with skin, wash immediately with plenty of soap and running water.
S36/37/39 ?Wear suitable protective clothing, gloves and eye/face protection.
S45 ?In case of accident or if you feel unwell, seek medical advice immediately (show the label
whenever possible).
The information contained in this MSDS is specific to the product when handled and used neat. This product when diluted may not require the
same control measures as the neat product. Check with your technical representative if in doubt.
3. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT CAS No. PROPORTION (% w/w)
The ingredients below are considered either hazardous, dangerous goods or poison scheduled according to the criteria of ASCC, ADG
Code and SUSDP (respectively) at the levels used in the product.
Morpholine 110-91-8 <10%
Cyclohexylamine 108-91-8 10 - <30%
Diethylaminoethanol 100-37-8 10 - <30%
The ingredients below are not considered either hazardous, dangerous goods or poison scheduled according to the criteria of ASCC,
ADG Code and SUSDP (respectively) at the levels used in the product.
Water 30 - 60%
Product Name: RL620 Page: 1 of 6
MATERIAL SAFETY DATA SHEET
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone Australia 131126, New Zealand
INGESTION:
0800 764 766) or a doctor. If swallowed, do NOT induce vomiting. Give a glass of water.
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing
EYE CONTACT:
until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
If skin or hair contact occurs, remove contaminated clothing and wash skin and hair thoroughly with
SKIN CONTACT:
soap and water. Flush continuously with running water until advised to stop by the Poisons
Information Centre or a doctor.
Remove from source of exposure to fresh air. Seek medical assistance if the effects persist.
INHALATION:
** SHOW THIS SAFETY DATA SHEET TO A DOCTOR **
Potable water should be available to rinse eyes or skin. Provide eye baths, safety showers and
FIRST AID FACILITIES:
soap.
Treat symptomatically.
NOTES TO PHYSICIAN:
5. FIRE FIGHTING METHODS
Water spray, foam, carbon dioxide or dry chemical powder.
SUITABLE EXTINGUISHING MEDIA:
Explosive air-vapour mixture may form. Explosive when mixed with oxidising
HAZARDS FROM COMBUSTION:
agents. Avoid all ignition sources. Keep away from heat, naked flames or sparks
and oxidising agents. Heating can cause expansion or decomposition of the
material, which can lead to the containers exploding. If safe to do so, remove
containers from the path of fire. On burning will emit toxic fumes such as carbon
oxides and nitrogen oxides.
Fire fighters should wear self-contained breathing apparatus and chemical splash
PRECAUTIONS FOR FIRE FIGHTERS AND
unit to minimise risk of exposure.
SPECIAL PROTECTIVE EQUIPMENT:
2X
HAZCHEM CODE:
6. ACCIDENTAL RELEASE MEASURES
Shut off leak if safe to do so. Eliminate all sources of ignition (no smoking, flares, sparks or flame).
EMERGENCY
Spillages are slippery. Vapours are heavier than air and may travel along the ground, gathering in
PROCEDURES:
depressions, resulting in Oxygen deficiency. Ensure adequate ventilation, work up wind or increase
ventilation. Keep spectators away ?rope off the area. Avoid accidents, clean up immediately. Wear
protective equipment to prevent skin and eye contamination and inhalation of mists or vapour.
Contain the spill and prevent run off into confined areas, drains and waterways.
METHODS AND
Absorb with dry earth, sand or other non-combustible material. Use clean non-sparking tools to collect
MATERIALS FOR
and seal in properly labelled drums for disposal in an area approved by local authority by-laws. Wash
CONTAINMENT AND
area down with excess water to remove residual material. DO NOT flush to drain.
CLEAN UP:
DO NOT incinerate: the by-products may be hazardous.
7. HANDLING AND STORAGE
Keep containers closed at all times - check regularly for leaks or spills. Transport and store upright.
PRECAUTIONS FOR
Avoid eye contact and repeated or prolonged skin contact and breathing in mists. Do not eat, drink or
SAFE HANDLING:
smoke in contaminated areas. Always remove contaminated clothing and wash hands before eating,
drinking, smoking or using the toilet. Wash contaminated clothing and other protective equipment
before storage or re-use.
Store in the original container, in a cool dry well-ventilated area out of sunlight and away from heat,
CONDITIONS FOR
incompatible materials and foodstuffs. Keep away from oxidising agents, may form explosive mixtures.
SAFE STORAGE:
Keep containers closed when not in use to ensure contamination does not occur- check regularly for
leaks. Do not combine part drums of the same product, as this may be a source of contamination. Do
not mix with other chemicals.
Classified as a C1 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance
with the requirements of AS1940. Refer to State Regulations for storage and transport requirements.
Product Name: RL620 Page: 2 of 6
MATERIAL SAFETY DATA SHEET
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
No value assigned for this specific material by the ASCC, however for the hazardous
NATIONAL EXPOSURE
ingredients, as published by the ASCC:
STANDARDS:
T.W.A. for Cyclohexylamine = 41 mg/m3
T.W.A. for Morpholine = 71 mg/m3
T.W.A. for Diethylaminoethanol = 48 mg/m3
No biological limit allocated.
BIOLOGICAL LIMIT VALUES:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards.
ENGINEERING CONTROLS:
If inhalation risk exists then use with local exhaust ventilation or while wearing a suitable
respirator. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter
confined spaces where vapour may have collected. Keep containers closed when not in use.
Protective equipment must be worn at all times. Risk assessments should always be
PERSONAL PROTECTIVE
conducted to identify the hazards and in turn determine the appropriate personal protective
EQUIPMENT:
equipment for the hazard.
Protective gloves: elbow-length laminate film or supported PVA impervious gloves. Always
check with the glove manufacturer or your personal protective equipment supplier regarding
the correct type of glove to use. Consult AS/NZS 2161 for further information.
Eye protection: safety glasses/goggles with side shield protection and/or full-face shield.
Consult AS/NZS 1336 and AS/NZS 1337 for further information.
Clothing and footwear: waterproof apron, coveralls, trousers, long sleeved shirt, closed in
shoes and/or safety footwear. Consult AS/NZS 2210 and AS/NZS 2919 for further information.
Respiratory Protection: Avoid breathing mist, sprays or vapours. Where ventilation is not
adequate, respiratory protection may be required. Any air-supplied respirator or combination
organic vapour respirator with a dust and mist pre-filter with an organic vapour cartridge(s)
providing protection against the compounds of concern meeting the requirements of AS/NZS
1715 and AS/NZS 1716.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Clear, yellow liquid.
APPEARANCE:
Amine odour.
ODOUR:
12 - 13
PH (NEAT):
0.96
SPECIFIC GRAVITY OR DENSITY:
No information available.
VAPOUR PRESSURE:
Volatile organic compounds: Approx. 40%.
PERCENT VOLATILES:
BP: > 95癈
BOILING POINT / RANGE:
No information available.
FREEZING / MELTING POINT:
No information available.
SOLUBILITY:
>84癈 (COC)... C1 Combustible liquid
FLASH POINT:
No information available.
FLAMMABILITY LIMITS:
No information available.
IGNITION TEMPERATURE:
2 years from manufacturing date (when stored as directed).
SHELF LIFE:
EVAPORATION RATE: < 1
OTHER:
10. STABILITY AND REACTIVITY
Stable under normal conditions of use. The shelf life is 2 years.
CHEMICAL STABILITY:
Do not combine part drums of the same product, as this may be a source of contamination.
CONDITIONS TO AVOID:
Keep material away from sparks, flames and other ignition sources. Keep away from
sources of excess heat (boilers, heaters, hot pipes). Keep away from oxidising agents.
Oxidising agents, strong acids and acid-forming substances, copper, aluminium, zinc and
INCOMPATIBLE MATERIALS:
galvanised steel.
Carbon oxides, nitrogen oxides, amine vapours, ammonia, soot, smoke and other organic
HAZARDOUS DECOMPOSITION
compounds. The packaging material may burn to emit noxious fumes.
PRODUCTS:
Explosive when mixed with oxidising substances. Strong exothermic reaction with acids.
HAZARDOUS REACTIONS:
Corrosive to copper, aluminium, zinc and galvanised steel.
Product Name: RL620 Page: 3 of 6
MATERIAL SAFETY DATA SHEET
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.
Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE EFFECTS
Harmful if swallowed. Swallowing can result in nausea, vomiting, abdominal pain and chemical
INGESTION:
burns to the mouth throat and stomach.
Corrosive to eyes. May cause severe and permanent corneal damage.
EYE CONTACT:
Harmful in contact with skin. Causes severe burns upon skin contact, resulting in tissue damage
SKIN CONTACT:
and dermatitis. Risk of absorption through skin.
Harmful by inhalation. Vapours, mists and sprays are capable of causing irritation and possible
INHALATION:
harmful corrosive effects to the mucous membranes and respiratory tract, including lesions of the
nasal septum, pulmonary oedema, pneumonitits, and emphysema. High concentrations may result
in headaches, nausea, vomiting, light-headedness, restlessness, anxiety, and rapid heartbeat.
Vapours may be harmful with repeated exposure.
No information available for the product.
LONG TERM EFFECTS:
No toxicity data for this specific product, however toxicity data for the hazardous ingredients is listed
ACUTE TOXICITY /
below.
CHRONIC TOXICITY:
TOXICITY DATA FOR MORPHOLINE:
Oral LD50 (rat) 1450 mg/kg Dermal LD50 (rabbit) 500 uL/kg
Inhalation LC50 (rat) 8000 ppm/8 hour
TOXICITY DATA FOR DIETHYLAMINOETHANOL:
Oral LD50 (rat) 1320 mg/kg Dermal LD50 (rabbit) 1100 mg/kg
Primary skin irritation/rabbit/OECD test ?Corrosive
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways. The product is highly alkaline. If large spills occurred
ECOTOXICITY:
a water pH rise could be responsible for an environmental effect on aquatic
organisms. If not neutralised this product could potentially be toxic for aquatic
organisms because of its alkalinity (pH> 9 can have an effect on fish, with possible
fish death). pH> 8.5 could be destroying for algae.
ECOTOXICITY DATA FOR DIETHYLAMINOETHANOL:
LC50 Leuciscus idus (96 hr) 100-220 mg/L
LC50 Daphnia magna (48 hr) 83.6 mg/L
EC50 Scenedesmus subspicatus (72 hr) 30 mg/L
EC50 Pseudomonas putida 375 mg/L
No information available.
PERSISTENCE AND DEGRADABILITY:
No information available.
MOBILITY:
None.
OTHER:
13. DISPOSAL CONSIDERATIONS
Dispose of material under the requirements of state environmental authority. Do not
DISPOSAL METHODS:
contaminate stream, rivers or watercourses. Inform local authority if liquid enters drains,
sewers, streams, etc. Empty containers should be forwarded to an approved agent for
recycling.
Dispose of material through a licensed waste contractor. Incinerate under controlled
SPECIAL PRECAUTIONS FOR
conditions if permitted by local authorities.
LANDFILL OR INCINERATION:
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MATERIAL SAFETY DATA SHEET
14. TRANSPORT INFORMATION
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods
ROAD AND RAIL TRANSPORT:
Code (ADG Code) for transport by Road and Rail.
3267
UN NUMBER:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (CONTAINS
UN PROPER SHIPPING NAME:
CYCLOHEXYLAMINE, DIETHYLAMINOETHANOL AND MORPHOLINE)
8
CLASS AND SUBSIDIARY RISK(S):
II
PACKAGING GROUP:
2X
HAZCHEM CODE:
Guide 36
INITIAL EMERGENCY RESPONSE GUIDE:
Not to be loaded with explosives (class 1), dangerous when wet substances
SEGREGATION DANGEROUS GOODS:
(class 4.3), oxidising agents (class 5.1), organic peroxides (class 5.2), radioactive
substances (class 7), corrosives (strong acids of class 8), foodstuffs and foodstuff
empties, however exemptions may apply.
Classified as Dangerous Goods by the criteria of the International Maritime
MARINE TRANSPORT:
Dangerous Goods Code (IMDG Code) for transport by sea.
3267
UN NUMBER:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (CONTAINS
UN PROPER SHIPPING NAME:
CYCLOHEXYLAMINE, DIETHYLAMINOETHANOL AND MORPHOLINE)
8
CLASS AND SUBSIDIARY RISK(S):
II
PACKAGING GROUP:
Category B. Clear of living quarters. "Separated from" acids.
STOWAGE AND SEGREGATION:
Classified as Dangerous Goods by the criteria of the International Air Transport
AIR TRANSPORT:
Association (IATA) for transport by air.
3267
UN NUMBER:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (CONTAINS
UN PROPER SHIPPING NAME:
CYCLOHEXYLAMINE, DIETHYLAMINOETHANOL AND MORPHOLINE)
8
CLASS AND SUBSIDIARY RISK(S):
II
PACKAGING GROUP:
8L
ERG CODE:
15. REGULATORY INFORMATION
POISONS SCHEDULE (AUST.): NONE
Not relevant.
APVMA STATUS:
Not relevant.
TGA STATUS:
All the constituents of this product are listed.
AICS STATUS:
IOA is available on request.
AQIS STATUS:
Not relevant.
OTHER:
16. OTHER INFORMATION
This product is a corrosive liquid. Use good industrial hygiene.
GENERAL INFORMATION:
004
MSDS ISSUE NUMBER:
05 MARCH 2009
MSDS ISSUE DATE:
In any event, the review and, if necessary, the re-issue of a MSDS shall be no longer than 5 years after the last date of issue.
Electronic versions of the MSDS's in a PDF format are also available on our Websites at www.cleantec.com.au/products.htm
and www.cleantec-nz.co.nz/products.htm
REASON(S) FOR ISSUE: 004: Reclassified as non-flammable. Addition of New Zealand contact details. Addition of New
Zealand website address.
THIS ISSUE NUMBER REPLACES ALL PREVIOUS ISSUES.
LITERARY REFERENCE:
SOURCES FOR DATA:
Product Name: RL620 Page: 5 of 6
MATERIAL SAFETY DATA SHEET
LEGEND:
AICS Australian Inventory of Chemical Substances
APVMA Australian Pesticides and Veterinary Medicines Authority
AQIS Australian Quarantine and Inspection Service
AS Australian Standard (as issued by Standards Australia)
ASCC Australian Safety and Compensation Council (formerly NOHSC)
ERP Code Emergency Response Drill Code as found in the ICAO (International Civil Aviation Organisation) Doc 9481
MSDS Material Safety Data Sheet
NOHSC National Occupational Health and Safety Commission
STEL Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a
working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the
STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There
should be at least 60 minutes between successive exposures at the STEL.
TGA Therapeutic Goods Administration
TLV Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental
Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical
agents to which it is believed that nearly all workers may be repeatedly exposed day after day without
adverse effect.
TWA Time Weighted Average - The average airborne concentration of a particular substance when calculated
over a normal eight-hour working day, for a five-day working week.
This MSDS has been prepared from current technical data and summarises at the date of issue our best knowledge of the health and safety
information of the product, and in particular how to safely handle and use the product in the workplace.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also
available upon request.
This MSDS may only be reproduced in full. Summaries or excerpts from this MSDS may not contain all the relevant information and thus are
not permitted.
End of MSDS
Product Name: RL620 Page: 6 of 6
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