MATERIAL SAFETY DATA SHEET
N,N-Diethylethanolamine, 99%
96856
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: N,N-Diethylethanolamine, 99%
2-Diethylaminoethanol, Beta-Diethylaminoethanol
Company Identification: Acros Organics N.V.
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in the US, call CHEMTREC: 800-424-9300
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-37-8 |N,N-Diethylethanolamine | 99% | 202-845-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Appearance: clear colorless to faint yellow. Flash Point: 60 deg C.
Warning! Flammable liquid. May cause respiratory tract irritation.
Hygroscopic. May be harmful if swallowed. May cause eye and skin
irritation. May cause respiratory and digestive tract irritation.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation. May cause eye injury.
Skin:
May cause severe skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Vapors may cause dizziness or suffocation. May cause nausea and
possible vomiting.
Chronic:
Not available.
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**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Flammable Liquid. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Water may be ineffective. Use dry chemical, carbon dioxide, or
alcohol-resistant foam.
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 60 deg C ( 140.00 deg F)
NFPA Rating: health-3; flammability-2; reactivity-0
Explosion Limits, Lower: 6.70 vol %
Upper: 11.7 vol %
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Avoid runoff into storm
sewers and ditches which lead to waterways.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Avoid
contact with heat, sparks and flame. Avoid ingestion and inhalation.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
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**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
+--------------------+-------------------+-------------------+-----------------+
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|--------------------|-------------------|-------------------|-----------------|
| N,N-Diethylethanola|10 ppm ; 48 mg/m3 |10 ppm TWA; 50 |10 ppm TWA; 50 |
| mine | | mg/m3 TWA | mg/m3 TWA |
+--------------------+-------------------+-------------------+-----------------+
OSHA Vacated PELs:
N,N-Diethylethanolamine:
10 ppm TWA; 50 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear colorless to faint yellow
Odor: unpleasant odor
pH: Not available.
Vapor Pressure: 1.9 mbar @ 20 C
Vapor Density: 4.04
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 161 deg C @ 760.00mm Hg
Freezing/Melting Point: -70 deg C
Decomposition Temperature: Not available.
Solubility: soluble
Specific Gravity/Density: .8840g/cm3
Molecular Formula: C6H15NO
Molecular Weight: 117.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to air, metals.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, copper, copper alloys, zinc.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-37-8: KK5075000
LD50/LC50:
CAS# 100-37-8: Inhalation, mouse: LC50 =5000 mg/m3; Oral, rat: LD50
= 1300 mg/kg.
Carcinogenicity:
N,N-Diethylethanolamine -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Neurotoxicity:
No data available.
Mutagenicity:
No data available.
Other Studies:
No data available.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Not available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants: Not listed.
RCRA D-Series Chronic Toxicity Reference Levels: Not listed.
RCRA F-Series: Not listed.
RCRA P-Series: Not listed.
RCRA U-Series: Not listed.
Not listed as a material banned from land disposal according to RCRA.
**** SECTION 14 - TRANSPORT INFORMATION ****
US DOT
Shipping Name: DIETHYLAMINOETHANOL
Hazard Class: 3
UN Number: UN2686
Packing Group: III
IMO
Shipping Name: DIETHYLAMINOETHANOL
Hazard Class: 3.3
UN Number: 2686
Packing Group: III
IATA
Shipping Name: 2-DIETHYLAMINOETHANOL
Hazard Class: 8
UN Number: 2686
Packing Group: II
RID/ADR
Shipping Name: DIETHYLAMINOETHANOL
Dangerous Goods Code: 3(31C)
UN Number: 2686
Canadian TDG
Shipping Name: 2 DIETHYLAMINOETHANOL
Hazard Class: 3
UN Number: UN2686
Other Information: FLASHPOINT 60 C
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**** SECTION 15 - REGULATORY INFORMATION ****
US FEDERAL
TSCA
CAS# 100-37-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 100-37-8: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
N,N-Diethylethanolamine can be found on the following state right to
know lists: California, New Jersey, Florida, Pennsylvania,
Minnesota, Massachusetts.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 100-37-8: 1
Canada
CAS# 100-37-8 is listed on Canada's DSL/NDSL List.
This product does not have a WHMIS classification.
CAS# 100-37-8 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 100-37-8:. OEL-AUSTRALIA:TWA 10 ppm (50 mg/m3);Skin. OEL-AUSTRIA
:TWA 10 ppm (50 mg/m3);Skin. OEL-BELGIUM:TWA 10 ppm (48 mg/m3);Skin. O
EL-DENMARK:TWA 10 ppm (50 mg/m3);Skin. OEL-FINLAND:STEL 10 ppm (50 mg/
m3);Skin. OEL-FRANCE:TWA 10 ppm (50 mg/m3);Skin. OEL-GERMANY:TWA 10 pp
m (50 mg/m3);Skin. OEL-THE NETHERLANDS:TWA 10 ppm (50 mg/m3);Skin. OEL
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-THE PHILIPPINES:TWA 10 ppm (50 mg/m3);Skin. OEL-RUSSIA:STEL 5 mg/m3;S
kin. OEL-SWITZERLAND:TWA 10 ppm (50 mg/m3);Skin. OEL-UNITED KINGDOM:TW
A 10 ppm (50 mg/m3);Skin. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA che
ck ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/01/1996 Revision #1 Date: 9/02/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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