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64742-48-9 64742-94-5 100-41-4 1330-20-7 91-20-3

File Name: 64742-48-9_64742-94-5_100-41-4_1330-20-7_91-20.asp

                                        MATERIAL SAFETY DATA SHEET

Trade Name: Johnsens Diesel Lubricity Improver
MSDS NO. 5004
Revision Date: 06/15/2005
Date Printed 12/30/2008
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade Name: Johnsens Diesel Lubricity Improver
Chemical Family: PETROLEUM DISTILLATE
Synonyms: None
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300

Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033


2. COMPOSITION/INFORMATION ON INGREDIENTS

Weight % OSHA TWA OSHA STEL OSHA SKIN
Component
80-90 Not Listed Not Listed Not Listed
Naphtha, Hydrotreated Heavy
64742-48-9
5-10 Not Listed Not Listed Not Listed
Heavy Aromatic Naphtha
64742-94-5
0-9 Not Listed Not Listed Not Listed
Ethyl benzene
100-41-4
0-5 Not Listed Not Listed Not Listed
Xylene
1330-20-7
0-3 Not Listed Not Listed Not Listed
Naphthalene
91-20-3


Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling
Component
80-90 Not Listed Not Listed Not Listed
Naphtha, Hydrotreated Heavy
64742-48-9
5-10 Not Listed Not Listed Not Listed
Heavy Aromatic Naphtha
64742-94-5
435 mg/m3 100 ppm 435 mg/m3 100 ppm
0-9 Not Listed
Ethyl benzene
100-41-4
0-5 Not Listed Not Listed Not Listed
Xylene
1330-20-7
50 mg/m3 10 ppm 50 mg/m3 10 ppm
0-3 Not Listed
Naphthalene
91-20-3


ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling
Component
Not Listed Not Listed Not Listed
Naphtha, Hydrotreated Heavy
64742-48-9
Not Listed Not Listed Not Listed
Heavy Aromatic Naphtha
64742-94-5
100 ppm 125 ppm Not Listed
Ethyl benzene
100-41-4
100 ppm Not Listed Not Listed
Xylene
1330-20-7
10 ppm 15 ppm Not Listed
Naphthalene
91-20-3

3. HAZARDS IDENTIFICATION



Page 1 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsens Diesel Lubricity Improver
MSDS NO. 5004
Revision Date: 06/15/2005
Date Printed 12/30/2008
3. HAZARDS IDENTIFICATION
Emergency Overview: Danger: Harmful or fatal if liquid is aspirated into lungs. Aspiration into the lungs may occur during
ingestion or vomiting, resulting in lung injury. Combustible Liquid. Gross inhalation overexposure may
cause: Central nervous system depression with dizziness, confusion, incoordination, drowsiness or
unconsciousness or death. May irritate the skin. Possible redness and defatting may result from prolonged
skin exposure to this matieral.

HMIS Classification: Health: *3 Flammability: 3 Physical Hazard: 0
NFPA Rating: Health: 2 Flammability: 3 Reactivity: 0


4. FIRST AID MEASURES

Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower lids. Seek medical attention if irritation persists.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an
unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Pulmonary
aspiration hazard if swallowed and/oil vomiting occurs - can enter lungs and cause damage.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Get medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get
medical attention. Remove contaminated clothing and shoes, and launder before reuse.


5. FIRE FIGHTING MEASURES

Flammable Properties
Flash Point 癋(癈): 105 - 135 F
Flash Point Method: Penski Martin
Flammable Limits in Air - Lower (%): 1%
Flammable Limits in Air - Upper (%): 7.2%
Autoignition Temperature 癋(癈): 598 F
Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Closed
containers may explode if exposed to extreme heat.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Fumes and Smoke.
Aerosol Comments: Not Applicable


6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Avoid breathing
vapor. When airborne exposure limits are exceeded use NIOSH approved respiratory protection
equipment appropriate to the material and/or its components.
Spill Procedures: Wear protective equipment specified. Only trained and qualified personel should handle any spilled or
leaked product. Avoid all sources of ignition; heat, sparks and open flames.
Action to be taken if material is released Remove sources of ignition. Increase area ventilation. Stop release at source. Dike area and contain.
or spilled: Recover free product. Add sand, earth, or other suitable absorbent to spill area. Minimize skin contact.
Keep product out of sewers and watercourses by diking or impounding. Advise authorities if product has
entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable
governmental regulations.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters.


7. HANDLING AND STORAGE

Handling and Storage: Keep away from heat and open flame. Store in cool place away from flame Keep container closed when
not in use. Avoid contact with skin and eyes. Use only in a well ventilated area. Do not reuse this container.
Do not inhale vapors. Keep away from food and smoking materials. Wash hands before eating and
smoking.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Page 2 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsens Diesel Lubricity Improver
MSDS NO. 5004
Revision Date: 06/15/2005
Date Printed 12/30/2008
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Eyewash stations.
Showers.
Eyes: Wear safety glasses or goggles to protect against exposure.
Skin Protection: Avoid skin contact. Wear protective clothing and gloves.
Respiratory Protection: Wear a NIOSH approved respirator appropriate for airborne exposure at the point of use.



9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless to light yellow liquid
Odor: AROMATIC
pH Value: Not Determined
Vapor Pressure: .2 - .95 PSI
Vapor Density (Air=1): 5.1
Boiling Point (癋): 270 F
Melting/Freezing Point: -70 F
Solubility in Water: INSOLUBLE
Bulk Density at 20癈: 7.75 lb/gal
Molecular Weight: Mixture
Specific Gravity (H20=1): .92 - .94 @ 15.6 C
Viscosity: <1cSt @ 100 F
Evaporation Rate: 5.4 (BuAc=1)
VOC Content(%): <50%
Decomposition Temperature: Not Known


10. STABILITY AND REACTIVITY

Chemical Stability: Stable under normal conditions of handling, use and transportation.
Conditions to Avoid: Keep away from heat,sparks and flame. High temperatures.
Materials to Avoid: Strong oxidizing agents. Strong acids.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Aldehydes Smoke and Fumes.
Hazardous Polymerization: WILL NOT OCCUR


11. TOXICOLOGICAL INFORMATION
Toxicological Data:

Component
Route Species Dose
LC50 8.5 g/m3
Inhalation Rats
Naphtha, Hydrotreated Heavy
64742-48-9
LC50 590 mg/m3/4H
Inhalation Rats
Heavy Aromatic Naphtha
64742-94-5
Oral Rats LD50 3500 mg/kg
Ethyl benzene
100-41-4
Inhalation Rats LC50 5000 ppm
Xylene
1330-20-7
LC50 340 mg/m3/1H
Inhalation Rats
Naphthalene
91-20-3

Carcinogenicity:




Page 3 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsens Diesel Lubricity Improver
MSDS NO. 5004
Revision Date: 06/15/2005
Date Printed 12/30/2008
Component
IARC NTP OSHA
Not Listed Not Listed Not Listed
Naphtha, Hydrotreated Heavy
64742-48-9
Not Listed Not Listed Not Listed
Heavy Aromatic Naphtha
64742-94-5
Group 2B (Possible cardinogenic to Not Listed Possible Select Carcinogens
Ethyl benzene
humans)
100-41-4
Group 3 (not classifiable) Not Listed Not Listed
Xylene
1330-20-7
Not Listed Not Listed Not Listed
Naphthalene
91-20-3

12. ECOLOGICAL INFORMATION

Remarks: This material is expected to be toxic to aquatic organisms. The ecotoxicity hazard is based on data for the
components.


13. DISPOSAL CONSIDERATION

Waste Classification: Not determined.
Waste Management: Not determined.
Disposal Method: Dispose of product in accordance with federal state and local regulations.


14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: ORM-D CONSUMER COMMODITY
Hazard Class: ORM-D
UN/NA Number: Not Applicable
DOT Packing Group: Not Applicable

IMDG:
Proper Shipping Name: Petroleum Distillate, n.o.s., (Naphtha, Ethyl-Benzene, Xylene), limited quantitiy
Hazard Class: 3
Hazard Subclass: Not determined.
UN No.: UN1268
Packing Group: III
Marine Pollutant: No


15. REGULATORY INFORMATION

US Federal Regulations:

SARA 313 SARA 302 TPQ RQ
Component
Naphtha, Hydrotreated Heavy Not Listed Not Listed Not Listed Not Listed
64742-48-9
Heavy Aromatic Naphtha Not Listed Not Listed Not Listed Not Listed
64742-94-5
Listed. Not Listed Not Listed Not Listed
Ethyl benzene
100-41-4
Listed. Not Listed Not Listed Not Listed
Xylene
1330-20-7
Listed. Not Listed Not Listed Not Listed
Naphthalene
91-20-3

SARA 311/312 Hazard Catagories: Not Determined.

Page 4 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsens Diesel Lubricity Improver
MSDS NO. 5004
Revision Date: 06/15/2005
Date Printed 12/30/2008


State Regulations:

California Prop. 65 California - Prop 65 California Prop. 65 California Prop. 65
Component
Cancer list Developmental Toxicity Reproductive Female Reproductive Male
Not Listed Not Listed Not Listed Not Listed
Naphtha, Hydrotreated Heavy
64742-48-9
Not Listed Not Listed Not Listed Not Listed
Heavy Aromatic Naphtha
64742-94-5
Listed: June 11, 2004 Not Listed Not Listed Not Listed
Ethyl benzene
Carcinogenic.
100-41-4
Not Listed Not Listed Not Listed Not Listed
Xylene
1330-20-7
Listed: April 19, 2002 Not Listed Not Listed Not Listed
Naphthalene
Carcinogenic.
91-20-3


New Jersey Right-to-Know List:
Component
Substance no. 0851
Ethyl benzene
Substance no. 2422
100-41-4 Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 2014
Xylene
1330-20-7
Substance no. 1322
Naphthalene
Substance no. 3006
91-20-3

U.S. TSCA: The components of this product are listed on the TSCA Inventory.
Canadian Inventory: One or more components of this product is not listed on the Canadian DSL or NDSL Inventory.
Consumer Product Safety Improvement Act of 2008 General Conformity Certification

The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in
compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and
enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant
Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced
by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No
other testing is required to certify compliance with the above. The date of manufacture is stamped on the product
container.

16. OTHER INFORMATION

General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.
Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable.
However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness
NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions
of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or
for incidental or consequential damages, including lost profits, arising from the use of these data. No
warranty against infringement of any patent, copyright or trademark is made or implied.




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