MATERIAL SAFETY DATA SHEET
ELASTUFF 120A CLEAR 55'S Page:1
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PRODUCT NAME: ELASTUFF 120A CLEAR 55'S
PRODUCT CODE: EL-120-A-CL-55
~~~~ SECTION 1 ~~~~ MANUFACTURER IDENTIFICATION ~~~~
Manufacturer's Name : UNITED COATINGS MANUFACTURING CO
Address : 19011 EAST CATALDO AVE.
: SPOKANE VALLEY, WASHINGTON 99016-9423
: INITIAL(FIRST CALL)CHEMTREC(800)424-9300
INFORMATION PHONE : (509)926-7143
TOLL FREE : BACKUP(800)541-4383
DATE PRINTED : 10/28/2005
DATE REVISED : October 2005
~~~~ SECTION 2 ~~~~ HAZARDOUS INGREDIENTS/SARA III INFORMATION ~~~~
Reportable Components CAS Number MM HG @ Temp Weight %
* 4,4'-diphenylmethane diisocyanate (MDI)101-68-8<0.0001 77F/25C 58
4,4'-diphenylmethane diisocyanate (MID) (CAS#101-68-8) Contains: 20-30%
Diphenylmethane diisocyanate (MDI) homopolymer (CAS# 25686-28-6) and
Diphenylmethane diisocyanate (MDI) mixed isomers (CAS# 26447-40-5)
The following OEL's are for CAS# 101-68-8.
ACGIH TLV TWA: 0.005ppm, OSHA PEL, ceiling: 0.02ppm.
~
1,3-Butadiene homopolymer hydroxy-terminated69102-90-5N/DN/A 27
1,3-butadiene, homopolymer, Hydroxy terminated CAS#69102-90-5
No exposure guidelines have been established for this chemical.
4-Vinylcyclohexene, (<20ppm%) CAS#100-40-3, ACGIH/TWA 0.1ppm, 0.44mg/m3;
1,3-butadiene (<1ppm%) CAS#106-99-0, ACGIH /TWA 2ppm, 4.4mg/m3.
~
Phthalate acid ester MIXTURE <0.075 68F/20C 15
Contains:
1,2-Benzenedicarboxylic acid, diheptyl ester,
branched and linear CAS# 68515-44-6
1,2-Benzenedicarboxylic acid, dinonyl ester,
branched and linear CAS# 68515-45-7
Diundecyl phthalate, branched and linear CAS# 85507-79-5
1,2-Benzenedicarboxylic acid, heptyl nonyl ester,
branched and linear CAS# 111381-89-6
1,2-Benzenedicarboxylic acid, heptyl undecyl ester,
branched and linear CAS# 111381-90-9
1,2-Benzenedicarboxylic acid, nonyl undecyl ester,
branched and linear CAS# 111381-91-0
No OEL's established for any of these chemicals.
~
* Indicates toxic chemical(s) subject to the reporting
requirements of section 313 of Title III and of 40 CFR 372.
# Indicates carcinogenic chemical.
NOTE: If tinted may contain Carbon Black CAS#1333-86-4 AND/OR
Crystalline Silica CAS#14808-60-7. If tinted DARK GRAY or BLACK
consider these levels to be reportable.
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This MSDS may be used for other container sizes of this product. When parts
A & B are combined, the hazard warnings for both components are present.
~~~~ SECTION 3 ~~~~ HAZARDS IDENTIFICATION ~~~~
Potential Health Effects
Eyes:
Eye exposure, will cause intense burning of the eyes,
photophobia, blepharospasm, profuse lacrimation, lid edema, and
superficial corneal ulceration with a resulting reversible blindness.
Contact with isocyanates may result in conjunctival irritation and
mild corneal opacity. Isocyanate is reported to induce chemical burns
in rabbit eye studies. A similar degree of eye injury may develop
after contact with human eyes.
Skin:
Skin absorption is believed to generally be too slow to
produce signs of acute systemic poisoning. However, animal studies
have shown that respiratory sensitization can be induced by skin
contact with known respiratory sensitizers, including isocyanates.
Isocyanates are a primary skin irritant--they react with skin protein
and moisture and can cause irritation. Symptoms can include: redness,
swelling, rash, scaling or blistering. Isocyanates are also strong
skin sensitizers. Experience indicates that direct skin contact is
the route of exposure most likely to cause skin sensitization. Once
sensitized, an individual may react even to airborne levels below the
TLV with the following symptoms; itching and tingling of the earlobes
and neck, rash, hives, swelling of the arms and legs or other
symptoms common to allergic dermititus. These symptoms may be
immediate or delayed several hours. Prolonged contact can cause
reddening, swelling, rash, scaling or blistering. In those who have
developed a skin sensitization, these symptoms can develop as a
result of contact with very small amounts of liquid material or even
as a result of vapor-only exposure.
Ingestion:
Swallowing may result in local irritation. Vomiting may also
result. Do not allow vomit to be breathed into the lungs, as chemical
pneumonitis and pulmonary edema/hemorrhage is possible. The
isocyanate in this product is classified as "practically non-toxic"
by ingestion. In humans, irritation or chemical burns and corrosive
action in the mouth, pharynx, esophagus, stomach & digestive tract
can develop following ingestion. Symptoms can include sore throat,
abdominal pain, nausea, vomiting and diarrhea. Injury may be severe
and cause death.
Inhalation:
Repeated or prolonged exposure to vapors or mists are
irritating to the respiratory tract. Inhalation of vapors and mists
of isocyante at concentrations above recommended exposure limits can
irritate the mucous membranes in the respiratory tract (nose, throat,
lungs) causing runny nose,sore throat, coughing, chest discomfort,
shortness of breath and reduced lung function. Persons with a
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preexisting,nonspecific bronchial hyperreactivity can respond to
concentrations below the intended recommended exposure level with
similar symptoms as well as an asthma attack. Exposure to higher
levels may lead to bronchitis, bronchial spasm and pulmonary edema
(fluid in the lungs). These effects are usually reversible. Chemical
or hypersensitive pneumonitis,with flu-like symptoms (e.g., fever,
chills) has also been reported.
~~~~ SECTION 4 ~~~~ FIRST AID MEASURES ~~~~
Eyes:
For eye exposure, irrigate the exposed eyes with copious
amounts of tepid water for at least 15 minutes. If the victim is
wearing contact lenses, they should be removed, provided such removal
does not cause further damage to the eyes. Consult a physician or
ophthalmologist immediately.
Skin:
Remove product and immediately flush affected area with
water for at least 15 minutes. Cover the affected area with a sterile
dressing or clean sheeting and consult a physician immediately,
except for the most minor, superficial and localized burns. Do not
apply greases or ointments. Control shock if present. Discard or
launder contaminated clothing before reuse. Contaminated leatherwear
should be discarded.
Ingestion:
Do not induce vomiting. Give 1 to 2 cups milk or water. If
vomiting occurs, keep victim's head below the hips to prevent
breathing vomit into the lungs. Consult a physician immediately.
Inhalation:
Move to fresh air; administer oxygen by a qualified
individual or artificial respiration as needed. Consult a physician
immediately. Asthmatic-type symptoms may develop and may be
immediate or delayed several hours. Treatment is essentially symptomatic.
Note to Physician:
Eyes - Stain for evidence of corneal injury. If cornea is
burned, instill antibiotic/steroid preparation frequently. Workplace
vapors could produce reversible corneal epithelial edema impairing
vision.
Skin- this compound is a potent skin sensitizer. Treat
symptomatically as for contact dermatitis or thermal burn.
Ingestion - Treat symptomatically. There is no specific antidote.
Inducing vomiting is contraindicated because of the irritating nature
of the compound.
Inhalation- treatment is essentially symptomatic. An individual
having a dermal or pulmonary sensitization reaction to this material
should be removed from any exposure to Issocyanate. Throughout a
symptomatic victim's treatment course, monitor the ECG, chest x-ray,
pulse oximetry, peak airflows, arterial blood gases, serum
electrolytes, and renal and hepatic function.
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~~~~ SECTION 5 ~~~~ FIRE FIGHTING MEASURES ~~~~
Flammable Properties
Flash Point: 200C/392F
Lower Flammable Limits: N/A
Upper Flammable Limit: N/A
Auto Ignition Temperature: Not available
Extinguishing Media:
Carbon dioxide, dry chemical, or appropriate foam. If water
is used, very large quantities are required. Reaction between water
and hot isocyanate may be vigorous. Contain run-off water with
temporary barriers.
Special Fire Fighting Procedures:
Isolate fire area and deny unnecessary entry. Move container
from fire area if this is possible without hazard. Stay upwind. Keep
out of low areas where gases (fumes) can accumulate.
Personnel engaged in fighting Issocyanate fires must be protected
against nitrogen dioxide fumes as well as Issocyanate vapors.
Firefighters must wear self-contained breathing apparatus and turnout gear.
~~~~ SECTION 6 ~~~~ ACCIDENTAL RELEASE MEASURES ~~~~
Small Spill:
Clean up personnel must be equipped with self contained breathing apparatus
and butyl rubber protective clothing. Evacuate area of all non-essential
personnel. Ventilate area as vapors are heavier than air.
Clear the area of unnecessary personnel. Insure a trained response
team is in emergency protective equipment. Prevent further spillage
and contain the spill using dikes made of sand, earth or spill
pillows. Cover the spill area with a non-combustable absorbant
material (e.g., absorbant clay, earth, sand) to absorb as much liquid
as possible. Shovel the absorbant into open top containers. Do not
fill to the top or cover the containers. Prepare a decontaminating
solution as follows:
Option 1: consists of a solution 90% water, 8% concentrated ammonia
solution and 2% liquid detergent.
Option 2: consists of a solution 90-95% water, 5-10% sodium carbonate
and 0.2-0.5% liquid detergent.
Pour the liquid decontaminant liberally over the remaining spill area
and spread with a broom or squeegee to insure contact. Let stand 10-
15 minutes @25c(77f), longer at lower temperatures. Then wash down
the area with plenty of water. In a well ventilated area, add enough
liquid decontaminent solution to the containers with the absorbed
spill material to obtain an approximate 10:1 ratio of decontaminate
solution to spill material. Mix the liquid-absorbant slurry and let
stand for 12-24 hours. Stir periodically, or the liquid-absorbant
slurry may solidify. Leave the lids on loosely. After decontamination
solution has been in contact with the spilled material for 24-48
hours, and the evolved carbon dioxide has vented away, tighten down
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the lids and dispose of the mixture in accordance with local, state
and federal regulations. Test the area for residual isocyanate vapors
before allowing workers to re-enter the area. When safe working
conditions have been re-established, remove and decontaminate all
equipment used.
Large Spill:
Use same procedure as small spill.
~~~~ SECTION 7 ~~~~ HANDLING AND STORAGE ~~~~
Handling & Storage:
Handling: Vapors can be evolved when material is heated
during processing operations. See SECTION 8, Exposure
Controls/Personal Protection, for types of ventilation required. Wash
after handling and shower at end of work period. Avoid eye
contact.Avoid skin contact.Do not breathe vapor. Material is
hydroscopic and may absorb atmospheric moisture. Use dry nitrogen to
purge opened, partially filled containers before resealing.
~
Storage conditions: Store in a cool, dry and well ventilated place.
Isolate from incompatible materials. Store in a tightly closed
container. Avoid contact with water, or moist air.
Other Precautions:
Avoid prolonged or repeated breathing of vapor or spray
mist. If used indoors, provide mechanical exhaust ventilation. Use
only in a well ventilated area. Wash thoroughly with soap and water
before eating or smoking. Keep out of the reach of children. Do not
get in eyes, on skin or on clothing. Avoid prolonged or repeated
breathing of vapor.
Unused product remaining in opened containers must be purged with dry
nitrogen before resealing to prevent CO2 pressure build-up due to
moisture contamination. If moisture or water contamination is
suspected, do not reseal. Open sealed drums slowly to release any
pressure due to possible CO2 pressure build-up.
~~~~ SECTION 8 ~~~~ EXPOSURE CONTROLS/PERSONAL PROTECTION ~~~~
Engineering Controls:
In outside spray, mixing and rolling applications situate
workers upwind of operation & provide airflow in a downwind direction
so as to carry fumes and residual spray away from workers.
Hazard control from vapor or spray mist is ideally performed by the
use of engineering controls. Effective engineering controls should be
used whenever possible to eliminate and/or reduce worker exposure to
all respiratory hazards. General ventilation, local ventilation, or
isolation may prove adequate to keep airborne concentraions of
diisocyanate below the expsure limit. Exhaust air may need to be
cleaned by scrubbers or filters to reduce environmental
concentrations.
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Respiratory Protection:
The hazards of both part A and part B will be exhibited when
combined.
Good industrial hygiene practice dictates that when Isocyanate-based
coatings are mixed/sprayed and applied, some Type of respiratory
protection should be worn.
A properly fitted air-purifying (combination organic vapor and
particulate) respirator, proven by test to be effective in isocyanate
containing spray/vapors during coating operations, and used in
accordance with the recommendations of the manufacturer, can be used
when the following conditions are met:
-concentration of vapors is unknown.
-or concentrations exceed those in section II.
-or the airborne Isocyanate (polymeric, oligomeric) concentration
exceeds 5mg/m3 Averaged Over 8 Hours) OR 10mg/m3 average over 15
Minutes
-or operations are being performed in confined space.
-and a NIOSH certified end of service life indicator or a change
schedule based upon objective information or data is used to ensure
that cartridges are replaced before the end of their service life.
In addition, pre-filters should be changed whenever breathing
resistance increases due to particulate buildup.
if a NIOSH certified end of service life indicator or a change
schedule based upon objective information or data cannot be met, then
a supplied air respirator must be used.
Monitoring: Refer To Patty's Industrial Hygiene And Toxicology-Volume
1(3rd Edition) Chapter 17 Volume III (First Edition) Chapter 3, for
guidance concerning appropriate air sampling strategy to determine
airborne concentrations of Isocyanate.
Medical surveillance: Supervision of all employees who handle or come
in contact with this product is recommended. This should include pre-
employment and periodical medical examinations with respiratory
function test (fev, fvc as a minimum). Persons with asthma-type
conditions, chronic bronchitis, other chronic respiratory diseases or
recurrent skin eczema or sensitization should be excluded from
working with Isocyanate. Once a person is diagnosed as sensitized to
Isocyanate, no further exposure can be permitted
Additional protective measures safety showers and eyewash stations
should be readily available to work area. Educate and train employees
in safe use of product. Follow all MSDS and label instructions.
Skin Protection:
Chemical resistant gloves determined to be impervious under the conditions
of use. The use of Tyvek suits are recommended to prevent skin exposure.
Eye Protection:
Chemical goggles. If splashing may occur or during spray
operations wear a face shield, unless a full-face piece respirator is
used. Do not wear contact lenses as they may contribute to the
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severity of injury to the eye from contact with liquid and spray mist.
~~~~ SECTION 9 ~~~~ PHYSICAL AND CHEMICAL PROPERTIES ~~~~
Boiling Range: 150C@ 5mmHg - 235-278C
Melting Point: N/A
Specific Gravity(H2O=1): 1.0846
Vapor Density(Air=1): Heavier than air
Vapor Pressure: .00001 mmHG @77F/25C.
Evaporation Rate(N-Butyl Acetate=1) : Unknown
Coating V.O.C.: 0.0 lb/gl Coating V.O.C.: 0 g/l
Material V.O.C.: 0.0 lb/gl Material V.O.C.: 0 g/l
Solubility in Water: Reacts slowly to liberate CO2, slightly soluble
Appearance: CLEAR LIQUID.Odor: Aromatic odor. pH: N/A
~~~~ SECTION 10 ~~~~ STABILITY & REACTIVITY DATA ~~~~
Stability:
This product is stable under normal storage conditions
Conditions To Avoid:
Avoid extreme heat conditions and water contact. Reaction
with water can result in pressure buildup of the container resulting
in rupture of the container. Avoid heat, open flames, welding arcs or other
ignition sources which induce thermal decomposition and/or combustion.
Incompatible Materials:
Avoid contamination with oxidizing materials and/or water.
Hazardous Decomposition Products
Products of combustion include isocyanate vapor & mist,
carbon monoxide, carbon dioxide, hydrogen cyanide, nitrogen oxides
and sulfur oxides and unidentified products in fumes and smoke.
Hazardous Polymerization:
Not expected to occur
~~~~ SECTION 11 ~~~~ TOXICOLOGICAL INFORMATION ~~~~
*Data is for individual components of preparation.
Materials having a known chronic/acute effects on eyes:
Can cause eye irritation. Symptoms include stinging,
tearing, redness, and swelling of eyes.
Materials having a known dermal toxicity.
Dermal LD50: greater than 6,200mg/kg (rabbit)
Materials having a known oral toxicity.
For MDI, Oral LC50: >10,000mg/kg (rat)
Materials having a known Inhalation hazard:
Diphenylmethane diisocyanate (MDI), CAS 101-68-8 The 4-hour
LC50 for polymeric MDI in rats ranges from 370 to 490 mg/m3. The 4-
hour LC50 for monomeric MDI in rats was estimated 172-187mg/m3. The
1-hour LC50 for monomeric MDI aerosol was >2240mg/m3 (rat).
Identified Acute/ Short-term Effects:
Eye contact may result in conjunctival irritation and mild
corneal opacity. Skin contact may result in dermatitis, either
irritative or allergic.
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Inhalation of MDI vapors may cause irritation of the mucous membranes
of the nose, throat or trachea, breathlessness, chest discomfort,
difficult breathing and reduced pulmonary function. Airborne
overexposure well above the PEL may result additionally in eye
irritation, headache, chemical bronchitis, asthma-like findings or
pulmonary edema. Isocyanates have also been reported to cause
hypersensitivity pneumonitis, which is characterized by flu-like
symptoms, the onset of which may be delayed. Gastrointestinal
symptoms include nausea, vomiting and abdominal pain.
Identified Carcinogens/Longterm Effects:
Results from a lifetime inhalation study in rats indicate
that MDI aerosol was carcinogenic at 6mg/m3, the highest dose tested.
This is well above the recommended TLV of 5ppb (0.05 mg/m3). Only
irritation was noted at the lower concentration of 0.2 and 1 mg/m3.
As a result of previous repeated over exposures or a single large
dose, certain individuals will develop isocyanate sensitization
(chemical asthma) which will cause them to react to a later exposure
to isocyanate at levels well below the PEL/TLV. These symptoms,
which include chest tightness, wheezing, cough, shortness of breath,
or asthmatic attack, could be immediate or delayed up to several
hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can
experience these symptoms upon exposure to dust, cold air, or other
irritants. This increased lung sensitivity can persist for weeks and
in severe cases for several years. Chronic overexposure to
isocyanates has also been reported to cause lung damage, including a
decrease in lung function, which may be permanent. Sensitization may
be either temporary or permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering. In those who have
developed a skin sensitization, these symptoms can develop as a
result of contact with very small amounts of liquid material, or even
as a result of vapor-only exposure.
Identified Teratogens:
NOT TERATOGENIC
Identified Reproductive toxins :
NO DATA.
Identified Mutagens:
NO DATA.
~~~~ SECTION 12 ~~~~ ECOLOGICAL INFORMATION ~~~~
Ecotoxicological effects on plants and animals:
Ecology data for: diphenylmethane diisocyanate (monomeric
and polymeric)
Aquatic toxicity: LC50-24hr (static): greater than 500 mg/liter for
Daphnia magna, Limnea stagnalis, and zebra fish (Brachydanio rerio)
for both polymeric and monomeric MDI.
Chemical Fate :
This product is not expected to be biodegradable. Avoid
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spillage into the environment.
~~~~ SECTION 13 ~~~~ DISPOSAL CONSIDERATIONS ~~~~
Instructions:
Dispose of contaminated product and materials used in
cleaning-up, spills or leaks in a manner approved for this material.
Consult appropriate federal, state and local regulatory agencies to
ascertain proper disposal procedures. Empty containers will retain
product residue and vapors and are subject to proper waste disposal,
as above.
MDI: Empty containers must be handled with care due to product
residue. Decontaminate containers prior to disposal. Empty
decontaminated containers should be crushed to prevent reuse. DO NOT
HEAT OR CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. Gases may be
highly toxic and flammable.
~~~~ SECTION 14 ~~~~ TRANSPORT INFORMATION ~~~~
Shipping Information:
DOT INFORMATION - 49 CFR 172.101
DOT DESCRIPTION:
<793 GALLONS IN A SINGLE CONTAINER IS; NON-HAZARDOUS BY GROUND AND
AIR. >793 GALLONS IS; DOT DESCRIPTION: ISOCYANATE, SOLUTION, TOXIC,
N.O.S.(CONTAINS 4,4-DIPHENYLMETHANE DIISOCYANATE),6.1, UN 2206, PG III
FOR SEA: ISOCYANATE, SOLUTION, TOXIC, N.O.S.(CONTAINS 4,4-
DIPHENYLMETHANE DIISOCYANATE),6.1, UN 2206, PG III.
~~~~ SECTION 15 ~~~~ REGULATORY INFORMATION ~~~~
(Not meant to be all inclusive-selected regulations represented)
US Regulations:
Status Of Substances Lists:
The Concentrations Shown In Section II Are Maximum Ceiling Levels
(Weight %) to be used for calculations for regulations.
A reportable quantity is a quantity of a hazardous substance that
triggers reporting requirements under the Comprehensive Environmental
Response Compensation And Liability Act (CERCLA).
If a spill of a substance exceeds it's reportable quantity (RQ) in
CFR 302.3,Table 40 302.4 Appendix A & 302.4 Appendix B,
the release must be reported to The National Response Center
At (800) 424-8802, The State Emergency Response Commission
(SERC), And community emergency coordinators likely to be affected.
Components present that could require reporting under the statute are:
SEE SECTION II FOR PERCENTAGES
*TOXIC: NOT REPORTABLE IN QUANTITIES LESS THAN 1%
#CARCINOGEN: NOT REPORTABLE IN QUANTITIES LESS THAN .1%
DIPHENYLMETHANE-4,4-DIISOCYANATE CAS #101-68-8 RQ 5000#.
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Superfund Amendments And Reauthorization Act Of 1986 (SARA) Title III
Requires emergency planning based on the Threshold Quantities(TPQ'S)and
release reporting based on Reportable Quantities (RQ'S) In 40 CFR 355
Appendix A&B Extremely Hazardous Substances. The emergency planning and
release requirements of 40 CFR 355 apply to any facility at which there is
present any amount of any extremely hazardous substance(EHS)
equal to or in excess of it's Threshold Planning Quantity(TPQ).
Components present that could require reporting under the statute are:
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL THAT COULD
REQUIRE REPORTING UNDER THE STATUTE ARE:
DIPHENYLMETHANE-4,4-DIISOCYANATE CAS #101-68-8 RQ 5000#.
1,3-BUTADIENE CAS #106-99-0 RQ 10#.
EPCRA 40 CFR 372(Section 313) Requires EPA and the States to
annually collect data on releases of certain toxic materials from
industrial facilities, and make the data available to the public in the
Toxics Release Inventory(TRI). This information must be included in all
MSDS'S that are copied and distributed or compiled for this material.
Reporting Threshold: Standard: A facility must report if it manufactures
(including imports) or processes 25,000 pounds or more or otherwise uses
10,000 pounds or more of a listed toxic chemical during the calendar year.
Components present that could require reporting under the statute are:
See Section II
The components of this product are listed or excluded from listing on the
US Toxic Substance Control Act (TSCA) chemical substance inventory.
Mixtures shall be assumed to present the same health hazards as do the
Components Which Comprise One Percent(By Weight Or Volume) or
greater of the mixture,except that the mixture shall be assumed to present
carcinogenic hazard if it has a component in concentrations of 0.1 percent
greater. The remaining percentage of unspecified ingredients, if any, are n
contained in above DeMinimis concentrations and/or are believed to
be non-hazardous under the OSHA Hazard Communication Standard
(29 CFR 1910.1200), and may consist of pigments, fillers, defoamers,
wetting agents, resins, dryers,anti-bacterial agents, water and/or solvents
in varying concentrations.
International Regulations:
Canadian WHMIS:
CLASS D - POISONOUS AND INFECTIOUS MATERIALS
Division 2 Materials Causing Other Toxic Effects
Subdivision B - Toxic Materials
Canadian Environmental Protection Act (CEPA):
All of the components of this product are exempt or listed
on the DSL.See Section II For Composition/Information on Ingredients.
EINECS:
All of the components of this product are listed in the
EINECS inventory or are exempt from notification requirements.
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State Regulations:
California:
California Proposition 65: The following Statement is made in order
to comply with The California Safe Drinking Water and Toxic
Enforcement Act of 1986
"WARNING:This product contains the chemical(s) appearing below known to the
State of California to:
A: Cause Cancer
NONE KNOWN
*If tinted contains Carbon Black:CAS#1333-86-4 and may also contain trace
amounts of Crystalline Silica:CAS#14808-60-7
B: Cause Birth Defects or other Reproductive Harm :
NONE KNOWN
In addition to the above named chemical(s)(if any),this product may contain
trace amounts of chemicals, known to the State of California, to cause
Cancer or Birth Defects and other Reproductive Harm
Delaware:
Listed on the Delaware Air Quality Management List:
METHYLENEBIS(PHENYLISOCYANATE) CAS#101-68-8 DRQ 5000#
Florida:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS# 101-68-8 LISTED AS TOXIC
Massachusetts:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS#101-68-8 SUBSTANCECODES:2,4,F8,F9
Michigan:
NONE KNOWN
Minnesota:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS#101-68-8
LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST:
CODES: A
HAZARDS: --
CARNINOGEN? NO
New Jersey:
NONE KNOWN
New York:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS#101-68-8 RQ--AIR 1, RQ--LAND 1
Pennsylvania:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS#101-68-8 CODE:E
Washington:
DIPHYLMETHANE DIISOCYANATE HOMOPOLYMER CAS#101-68-8
WASHINGTON AIR CONTAMINANT: ppm mg/Cubic Meter
TWA UNK 5
STEL UNK UNK
CEILING .02 .2
SKIN:UNK
~~~~ SECTION 16 ~~~~ OTHER INFORMATION ~~~~
HMIS?III
Health :3
Flammability :1
Physical Hazard :1
*Following Health rating Indicates Chronic/Carcinogenic Effects
HMIS?III Personal Protection :K
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This rating is for the product as it is packaged. This rating will need
to be adjusted by the user based on conditions of use.
The information contained herein relates only to the
specific material identified. United Coatings believes that such
information is accurate and reliable as of the date of this material
safety data sheet, but no representation, guarantee or warranty,
expressed or implied, is made as to the accuracy, reliability, or
completeness of the information. To assure proper use & disposal of
these materials & the safety & health of employees & customers,United
Coatings urges persons receiving this information to make their own
determination as to the information's suitability and completeness
for their particular application.
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