Material Safety Data Sheet
Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile /
Nitrogen
Section 1. Chemical product and company identification
: Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
Product Name
: AIRGAS INC., on behalf of its subsidiaries
Supplier
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
: Synthetic/Analytical chemistry.
Product use
: 007551
MSDS#
: 9/21/2007.
Date of
Preparation/Revision
: 1-866-734-3438
In case of emergency
Section 2. Hazards identification
: Gas.
Physical state
: Warning!
Emergency overview
CANCER HAZARD
CONTAINS MATERIAL WHICH CAN CAUSE CANCER
CONTENTS UNDER PRESSURE.
Do not puncture or incinerate container. Risk of cancer depends on duration and level of
exposure.
Contact with rapidly expanding gases can cause frostbite.
: Inhalation
Routes of entry
Potential acute health effects
No known significant effects or critical hazards.
Eyes :
No known significant effects or critical hazards.
Skin :
Acts as a simple asphyxiant.
Inhalation :
Ingestion is not a normal route of exposure for gases
:
Ingestion
CARCINOGENIC EFFECTS Classified A3 (Proven for animal.) by ACGIH, 2B
:
Potential chronic health :
(Possible for human.) by IARC [1-cyclohexene, 4-vinyl-]. Classified + (Proven.) by
effects
OSHA+ (Proven.) by NIOSH [acrylonitrile]. Classified A3 (Proven for animal.) by ACGIH,
2B (Possible for human.) by IARC [acrylonitrile]. Classified 2 (Reasonably Anticipated To
Be Human Carcinogens.) by NTP, 2 (Suspected for human.) by European Union
[acrylonitrile]. Classified 1 (Known To Be Human Carcinogens.) by NTP, + (Proven.) by
NIOSH, 1 (Proven for human.) by European Union [1,3-butadiene]. Classified A2
(Suspected for human.) by ACGIH, 2A (Probable for human.) by IARC [1,3-butadiene].
MUTAGENIC EFFECTS Classified 2 by European Union [1,3-butadiene].
:
TERATOGENIC EFFECTS Not available.
:
: Repeated exposure to a highly toxic material may produce general deterioration of health
Medical conditions
aggravated by overexposure by an accumulation in one or many human organs.
See toxicological Information (section 11)
Section 3. Composition, Information on Ingredients
Name CAS number % Volume Exposure limits
Nitrogen 7727-37-9 97 - 99
4-Vinyl-1-Cyclohexene 100-40-3 0.00001 - 0.9 ACGIH TLV (United States, 1/2007).
TWA: 0.1 ppm 8 hour(s).
AIHA WEEL (United States, 1/2007).
TWA: 5 ppm 8 hour(s).
ACGIH TLV (United States, 1/2007).
TWA: 0.44 mg/m 3 8 hour(s).
Acrylonitrile 107-13-1 0.0001 - 0.9 ACGIH TLV (United States, 1/2007). Skin
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Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
TWA: 2 ppm 8 hour(s).
NIOSH REL (United States, 12/2001). Skin
CEIL: 10 ppm 15 minute(s).
TWA: 1 ppm 10 hour(s).
OSHA PEL (United States, 11/2006). Skin
CEIL: 10 ppm
TWA: 2 ppm 8 hour(s).
ACGIH TLV (United States, 1/2007). Skin
TWA: 4.3 mg/m 3 8 hour(s).
1,3-Butadiene 106-99-0 0.0001 - 0.9 ACGIH TLV (United States, 1/2007).
TWA: 2 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
STEL: 5 ppm 15 minute(s).
TWA: 1 ppm 8 hour(s).
ACGIH TLV (United States, 1/2007).
TWA: 4.4 mg/m 3 8 hour(s).
Section 4. First aid measures
No action shall be taken involving any personal risk or without suitable training.If fumes are still suspected to be present,
the rescuer should wear an appropriate mask or a self-contained breathing apparatus.It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Eye contact
Get medical attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Remove contaminated
Skin contact
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Get medical attention.
: Try to warm up the frozen tissues and seek medical attention.
Frostbite
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give
Inhalation
artificial respiration. Get medical attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give
Ingestion
anything by mouth to an unconscious person. Get medical attention if symptoms
appear.
Section 5. Fire fighting measures
Flammability of the product : Non-flammable.
: These products are nitrogen oxides (NO, NO 2...).
Products of combustion
: Use an extinguishing agent suitable for surrounding fires.
Fire fighting media and
instructions
If involved in fire, shut off flow immediately if it can be done without risk. Apply water
from a safe distance to cool container and protect surrounding area.
No specific hazard.
: Fire fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full facepiece operated in positive pressure mode.
equipment for fire-fighters
Section 6. Accidental release measures
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
Personal precautions
suitable protective equipment (Section 8). Shut off gas supply if this can be done safely.
Isolate area until gas has dispersed.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
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Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
Section 7. Handling and storage
: Do not puncture or incinerate container. High pressure gas. Use equipment rated for
Handling
cylinder pressure. Close valve after each use and when empty. Protect cylinders from
physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder
movement.
: Keep container tightly closed. Keep container in a cool, well-ventilated area. Cylinders
Storage
should be stored upright, with valve protection cap in place, and firmly secured to
prevent falling or being knocked over. Cylinder temperatures should not exceed 52 癈
(125 癋).
Section 8. Exposure Controls, Personal Protection
: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or
Engineering controls
mist, use process enclosures, local exhaust ventilation, or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Personal protection
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before handling
this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary.Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
: Chemical-resistant, impervious gloves or gauntlets complying with an approved standard
Hands
should be worn at all times when handling chemical products if a risk assessment
indicates this is necessary.
Personal protection in case : A self-contained breathing apparatus should be used to avoid inhalation of the product.
of a large spill
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
Not applicable.
Molecular weight :
Not applicable.
Molecular formula :
Not available.
Boiling/condensation point :
-210癈 (-346癋) based on data for: nitrogen.
Melting/freezing point :
The lowest known value is -146.9癈 (-232.4癋) (nitrogen).
Critical temperature :
The highest known value is 0.967 (Air = 1) (nitrogen).
Vapor density :
Specific Volume (ft3/lb) Not applicable.
:
Gas Density (lb/ft3) The only known value is 0.072 (nitrogen).
:
Section 10. Stability and reactivity
: The product is stable.
Stability and reactivity
: Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions of instability
Unstable. ( at high temperature ) (1,3-butadiene)
Incompatibility with various : Reactive with oxidizing agents.
Slightly reactive to reactive with acids, alkalis.
substances
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Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
Section 11. Toxicological information
Ingredient name Test Result Route Species
Acrylonitrile LD50 78 mg/kg Oral Rat
LD50 27 mg/kg Oral Mouse
LD50 50 mg/kg Oral Guinea pig
LD50 63 mg/kg Dermal Rabbit
LD50 148 mg/kg Dermal Rat
LD50 202 mg/kg Dermal Guinea pig
LDLo 2015 mg/kg Dermal child
1,3-Butadiene LD50 5480 mg/kg Oral Rat
LD50 3210 mg/kg Oral Mouse
: CARCINOGENIC EFFECTS Classified A3 (Proven for animal.) by ACGIH, 2B
:
Chronic effects on humans
(Possible for human.) by IARC [1-cyclohexene, 4-vinyl-]. Classified + (Proven.) by
OSHA+ (Proven.) by NIOSH [acrylonitrile]. Classified A3 (Proven for animal.) by ACGIH,
2B (Possible for human.) by IARC [acrylonitrile]. Classified 2 (Reasonably Anticipated To
Be Human Carcinogens.) by NTP, 2 (Suspected for human.) by European Union
[acrylonitrile]. Classified 1 (Known To Be Human Carcinogens.) by NTP, + (Proven.) by
NIOSH, 1 (Proven for human.) by European Union [1,3-butadiene]. Classified A2
(Suspected for human.) by ACGIH, 2A (Probable for human.) by IARC [1,3-butadiene].
MUTAGENIC EFFECTS Classified 2 by European Union [1,3-butadiene].
:
: No specific information is available in our database regarding the other toxic effects of
Other toxic effects on
this material for humans.
humans
Specific effects
: Contains material which can cause cancer. Risk of cancer depends on duration and
Carcinogenic effects
level of exposure.
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
Section 12. Ecological information
Ingredient name Species Period Result
Acrylonitrile Daphnia magna (EC50) 48 hour(s) 7.38 mg/l
Daphnia magna (EC50) 48 hour(s) 10.25 mg/l
Daphnia magna (EC50) 48 hour(s) 10.95 mg/l
Pimephales promelas (LC50) 96 hour(s) 8.4 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 9.3 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 10 mg/l
: These products are nitrogen oxides (NO, NO 2...).
Products of degradation
: The products of degradation are less toxic than the product itself.
Toxicity of the products of
biodegradation
: Not available.
Environmental fate
: No known significant effects or critical hazards.
Environmental hazards
Toxicity to the environment : Not available.
Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.
Section 14. Transport information
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Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
Regulatory UN number Proper shipping Class Packing group Label Additional
information name information
DOT Classification UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). -
N.O.S. NON-FLAMMABLE GAS
2
TDG Classification UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). Explosive
N.O.S. Limit and
Limited
2
Quantity
Index
0.125
Passenger
Carrying
Road or Rail
Index
75
UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). -
Mexico
N.O.S.
Classification NON-FLAMMABLE GAS
2
Section 15. Regulatory information
United States
: TSCA 8(a) PAIR: 1-cyclohexene, 4-vinyl-
U.S. Federal regulations
TSCA 8(b) inventory: 1-cyclohexene, 4-vinyl-; nitrogen; acrylonitrile; 1,3-butadiene
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: nitrogen
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: nitrogen:
Sudden Release of Pressure
Clean Water Act (CWA) 307: acrylonitrile
Clean Water Act (CWA) 311: acrylonitrile
Clean air act (CAA) 112 accidental release prevention: acrylonitrile; 1,3-butadiene
Clean air act (CAA) 112 regulated flammable substances: 1,3-butadiene
Clean air act (CAA) 112 regulated toxic substances: acrylonitrile
SARA 313
Product name CAS number Concentration
: Acrylonitrile 107-13-1 0.0001 - 0.9
Form R - Reporting
1,3-Butadiene 106-99-0 0.0001 - 0.9
requirements
: Acrylonitrile 107-13-1 0.0001 - 0.9
Supplier notification
1,3-Butadiene 106-99-0 0.0001 - 0.9
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
: Pennsylvania RTK: 1-cyclohexene, 4-vinyl-: (generic environmental hazard); nitrogen:
State regulations
(generic environmental hazard); acrylonitrile: (special hazard, environmental hazard,
generic environmental hazard); 1,3-butadiene: (special hazard, environmental hazard,
generic environmental hazard)
Massachusetts RTK: 1-cyclohexene, 4-vinyl-; nitrogen; acrylonitrile; 1,3-butadiene
New Jersey: nitrogen; acrylonitrile; 1,3-butadiene
: WARNING: This product contains a chemical known to the State of California to cause
California prop. 65
cancer and birth defects or other reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
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Nonflammable Gas Mixture: 1,3 Butadiene / 4-Vinyl-1-Cyclohexene / Acrylonitrile / Nitrogen
4-Vinyl-1-Cyclohexene Yes. No. No. No.
Acrylonitrile Yes. No. Yes. No.
1,3-Butadiene Yes. Yes. Yes. No.
Canada
: Class A: Compressed gas.
WHMIS (Canada)
Class D-2A: Material causing other toxic effects (VERY TOXIC).
CEPA DSL: 1-cyclohexene, 4-vinyl-; nitrogen; acrylonitrile; 1,3-butadiene
Section 16. Other information
United States
: CANCER HAZARD
Label Requirements
CONTAINS MATERIAL WHICH CAN CAUSE CANCER
CONTENTS UNDER PRESSURE.
Canada
: Class A: Compressed gas.
Label Requirements
Class D-2A: Material causing other toxic effects (VERY TOXIC).
*1
Hazardous Material : Health
Information System (U.S.A.)
0
Fire hazard
0
Reactivity
C
Personal protection
National Fire Protection :
Flammability
0
Association (U.S.A.)
1 0
Health Instability
Special
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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