Material Safety Data Sheet
NFPA HMIS PPE Transport Symbol
Issuing Date 07-Nov-2006 Revision Date 07-Nov-2006 Revision Number 1
1. PRODUCT AND COMPANY IDENTIFICATION
Super Tech High Mileage ATF
Product Name
Lubricant
Recommended Use
Supplier Address
Warren Distribution Inc
727 South 13th Street, Omaha, NE,
68102
US
Phone:402-341-9397
Contact:Angel Lowery
Contact Phone:402-977-5786
Emergency Phone: 800-424-9300
Company Emergency Phone Number 800-424-9300
2. HAZARDS IDENTIFICATION
CAUTION!
Emergency Overview
COMBUSTIBLE LIQUID AND VAPOR.
May cause skin irritation and/or dermatitis.
High gas, vapor, mist, or dust concentrations may be harmful if inhaled
Contains a known or suspected carcinogen.
Appearance Amber Physical State Liquid Odor Petroleum distillates
Potential Health Effects
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Inhalation, Skin contact, Eye contact.
Principle Routes of Exposure
Acute Toxicity
May cause slight irritation.
Eyes
Repeated exposure may cause skin dryness or cracking.
Skin
Avoid breathing vapors or mists. May cause drowsiness and dizziness.
Inhalation
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Potential for
Ingestion
aspiration if swallowed. May cause additional affects as listed under "Inhalation".
Prolonged exposure may cause chronic effects. Intentional misuse by deliberately
Chronic Effects
concentrating and inhaling contents may be harmful or fatal. Ethylbenzene has been classified
by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to
humans (Group 2B). Prolonged or repeated overexposure to ethylbenzene may result in
adverse effects to the kidneys, liver, respiratory system, thyroid, testicles, and pituitary glands.
Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness,
Main Symptoms
cessation of breathing.
Skin disorders. Respiratory disorders. Central nervous system.
Aggravated Medical Conditions
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental Hazard
environment. See Section 12 for additional Ecological information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight %
Petroleum distillates, hydrotreated heavy paraffinic 64742-54-7 60 - 100
Diphenylamine 122-39-4 < 0.1
Xylenes (o-, m-, p- isomers) 1330-20-7 1-5
Ethyl benzene 100-41-4 0.1 - 1
Sulfur dioxide 7446-09-5 < 0.1
4. FIRST AID MEASURES
Show this safety data sheet to the doctor in attendance.
General Advice
Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a
Eye Contact
physician.
Wash off with warm water and soap. If skin irritation persists, call a physician.
Skin Contact
Remove from exposure, lie down. If not breathing, give artificial respiration. Call a physician
Inhalation
immediately.
Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting. Never
Ingestion
give anything by mouth to an unconscious person.
Treat symptomatically
Notes to Physician
5. FIRE-FIGHTING MEASURES
Combustible material: may burn but does not ignite readily.
Flammable Properties
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250癈 / 482癋
Flash Point
Use extinguishing measures that are appropriate to local
Suitable Extinguishing Media
circumstances and the surrounding environment. Dry chemical,
CO2 or water spray.
?Combustible Liquid: III-B
Uniform Fire Code
?Other Health Hazard: Carcinogen--Liquid (Note 5)
Carbon oxides
Hazardous Combustion Products
Explosion Data
Not sensitive
Sensitivity to mechanical impact
Yes
Sensitivity to static discharge
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear
NFPA Health Hazard 0 Flammability 1 Stability 0 Physical and Chemical
Hazards -
6. ACCIDENTAL RELEASE MEASURES
Remove all sources of ignition.
Personal Precautions
Absorb or cover with dry earth, sand or other non-combustible material and transfer to
Methods for Containment
containers.
Use personal protective equipment. Dam up. Cover liquid spill with sand, earth or other
Methods for Cleaning Up
noncombustible absorbent material. Take up mechanically and collect in suitable container for
disposal. Clean contaminated surface thoroughly. Ground and bond containers when
transferring material. Use clean non-sparking tools to collect absorbed material.
7. HANDLING AND STORAGE
Handle in accordance with good industrial hygiene and safety practice. Keep away from open
Handling
flames, hot surfaces and sources of ignition. Avoid contact with skin and eyes. Avoid breathing
vapors or mists. Take necessary action to avoid static electricity discharge (which might cause
ignition of organic vapors).
Keep away from open flames, hot surfaces and sources of ignition. Keep container tightly
Storage
closed in a dry and well-ventilated place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
TWA: 10 mg/m3 TWA: 10 mg/m3
Diphenylamine
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Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Xylenes (o-, m-, p- isomers) TWA: 100 ppm TWA: 100 ppm
STEL: 150 ppm
Ethyl benzene TWA: 100 ppm TWA: 100 ppm 800 ppm
STEL: 125 ppm
Sulfur dioxide TWA: 2 ppm TWA: 2 ppm 100 ppm
STEL: 5 ppm
NIOSH IDLH: Immediately Dangerous to Life or Health
Showers
Engineering Measures
Eyewash stations
Ventilation systems
Personal Protective Equipment
If splashes are likely to occur, wear:. Goggles.
Eye/face Protection
Wear protective gloves/clothing. Antistatic boots.
Skin and body protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
Respiratory Protection
protection should be worn.
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
Hygiene Measures
smoke when using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Amber Petroleum distillates
Appearance Odor
Liquid 7
Physical State pH
250癈 / 482癋 Not applicable
Flash Point Autoignition Temperature
No data available No data available
Boiling Point/Range Melting Point/Range
No data available
Flammability Limits in Air
Insoluble in water No data available
Water Solubility Solubility
3.5362%
VOC Content Partition Coefficient (n-
octanol/water)
10. STABILITY AND REACTIVITY
Stable under recommended storage conditions.
Stability
Heat, flames and sparks.
Conditions to Avoid
No information available.
Incompatible Products
Thermal decomposition can lead to release of irritating gases and
Hazardous Decomposition Products
vapors.
Hazardous polymerization does not occur
Hazardous Polymerization
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11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product does not present an acute toxicity hazard based on known or supplied information
Product Information
2075 mg/kg (rat) estimated
LD50 Oral VALUE (mg/kg)
2065 mg/kg (rat) estimated
LD50 Dermal VALUE
5146 ml/m3 (vapor) estimated
LC50 Inhalation (VAPOR) VALUE
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Petroleum distillates, hydrotreated 2000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.18 mg/L ( Rat ) 4 h
heavy paraffinic
Diphenylamine 1165 mg/kg ( Rat ) 2000 mg/kg ( Rabbit )
Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 5000 ppm ( Rat ) 4 h
Ethyl benzene 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Sulfur dioxide 2500 ppm ( Rat ) 1 h
Subchronic Toxicity (28 days)
Chronic Toxicity
Prolonged exposure may cause chronic effects. Intentional misuse by deliberately
Chronic Toxicity
concentrating and inhaling contents may be harmful or fatal. Ethylbenzene has been classified
by the International Agency for Research on Cancer (IARC) as possibly carcinogenic to
humans (Group 2B). Prolonged or repeated overexposure to ethylbenzene may result in
adverse effects to the kidneys, liver, respiratory system, thyroid, testicles, and pituitary glands.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Ethyl benzene A3 Group 2B X
Mutagenicity
Chemical Name EU - Annex I Mutagens Japan Mutagens
Diphenylamine X
Contains ingredients that are suspected reproductive hazards.
Reproductive Toxicity
Respiratory system, Eyes, Skin, Central nervous system (CNS), Kidney, Liver, Thyroid,
Target Organ Effects
Reproductive System, Endocrine System.
This product does not contain any known or suspected endocrine disruptors.
Endocrine Disruptor Information
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)
Petroleum distillates, EC50 > 1000 mg/L 48 h
hydrotreated heavy paraffinic
Diphenylamine EC50 = 0.048 mg/L 72 h EC50 = 2.81 mg/L 5 min EC50 = 2.3 mg/L 24 h
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Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)
Xylenes (o-, m-, p- isomers) EC50 = 0.0084 mg/L 24 h LC50 = 0.6 mg/L 48 h
EC50 = 3.82 mg/L 48 h
Ethyl benzene EC50 = 4.6 mg/L 72 h EC50 = 9.68 mg/L 30 min EC50 1.8 - 2.4 mg/L 48 h
Chemical Name Log Pow
Diphenylamine 3.5
Xylenes (o-, m-, p- isomers) 2.77 - 3.15
Ethyl benzene 3.118
13. DISPOSAL CONSIDERATIONS
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR
Waste Disposal Method
261). Dispose of in accordance with local regulations.
Dispose of in accordance with local regulations
Contaminated Packaging
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Diphenylamine - 122-39-4 (hazardous constituent - no Included in waste streams:
waste number) F039, K083, K104
Xylenes (o-, m-, p- isomers) - Included in waste stream: waste number U239 (Ignitable
1330-20-7 F039 waste, Toxic waste)
Ethyl benzene - 100-41-4 Included in waste stream:
F039
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Diphenylamine Toxic
Xylenes (o-, m-, p- isomers) Toxic; Ignitable
Ethyl benzene Toxic; Ignitable
14. TRANSPORT INFORMATION
Not regulated
DOT
Not regulated
TDG
Not regulated
MEX
Not regulated
ICAO
Not regulated
IATA
Not regulated
IMDG/IMO
Not regulated
RID
Not regulated
ADR
Not regulated
ADN
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15. REGULATORY INFORMATION
International Inventories
Complies
TSCA
Complies
DSL
Complies
NDSL
Complies
EINECS
Complies
ELINCS
Complies
ENCS
Complies
CHINA
Complies
KECL
Complies
PICCS
Complies
AICS
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name CAS-No Weight % SARA 313 - Threshold
Values
Diphenylamine 122-39-4 < 0.1 1.0
Xylenes (o-, m-, p- isomers) 1330-20-7 1-5 1.0
Ethyl benzene 100-41-4 0.1 - 1 0.1
SARA 311/312 Hazard Categories
No
Acute Health Hazard
Yes
Chronic Health Hazard
Yes
Fire Hazard
No
Sudden Release of Pressure Hazard
No
Reactive Hazard
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Xylenes (o-, m-, p- isomers) 100 lb X
Ethyl benzene 1000 lb X X X
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:
Chemical Name CAS-No Weight % HAPS data VOC Chemicals Class 1 Ozone Class 2 Ozone
Depletors Depletors
Diphenylamine 122-39-4 < 0.1 Group III
Xylenes (o-, m-, p- isomers) 1330-20-7 1-5 Group I
Ethyl benzene 100-41-4 0.1 - 1 Group I
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
Xylenes (o-, m-, p- isomers) 100 lb
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Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
Ethyl benzene 1000 lb
Sulfur dioxide 500 lb
Pesticide Information
.
Chemical Name FIFRA - Restricted Use FIFRA - Pesticide Product FIFRA - Listing of Pesticide California Pesticides -
Other Ingredients Chemicals Restricted Materials
Petroleum distillates, List 2 - Potentially Toxic
hydrotreated heavy paraffinic
Diphenylamine X
Xylenes (o-, m-, p- isomers) List 2 - Potentially Toxic X
Ethyl benzene List 2 - Potentially Toxic
Sulfur dioxide X
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Chemical Name CAS-No California Prop. 65
Ethyl benzene 100-41-4 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Diphenylamine X X X X
Xylenes (o-, m-, p- isomers) X X X X X
Ethyl benzene X X X X X
Sulfur dioxide X X X X
International Regulations
Slight risk, Grade 1
Mexico - Grade
Chemical Name Carcinogen Status Exposure Limits
Diphenylamine STEL: 20 mg/m?br>
TWA: 10 mg/m?br>
Xylenes (o-, m-, p- isomers) STEL: 150 ppm
STEL: 655 mg/m?br>
TWA: 435 mg/m?br>
TWA: 100 ppm
Ethyl benzene STEL: 545 mg/m?br>
STEL: 125 ppm
TWA: 435 mg/m?br>
TWA: 100 ppm
Sulfur dioxide STEL: 10 mg/m?br>
STEL: 5 ppm
TWA: 2 ppm
TWA: 5 mg/m?br>
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.
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WHMIS Hazard Class
D2A Very toxic materials
Chemical Name NPRI
Diphenylamine X
Xylenes (o-, m-, p- isomers) X
Ethyl benzene X
Sulfur dioxide X
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
07-Nov-2006
Issuing Date
07-Nov-2006
Revision Date
No information available
Revision Note
Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.
End of MSDS
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