Material Safety Data Sheet
CORAVOL 1903
Section 1. Chemical product and company identification
: CORAVOL 1903
Trade name
: Water Treatment
Product use
: Ecolab Co.
Supplier
5105 Tomken Road
Mississauga ON L4W 2X5
1-800-352-5326
: 918391
Code
: 17-October-2007
Date of issue
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Composition, information on ingredients
CAS number % by weight
Name
2-diethylaminoethanol 100-37-8 10 - 30
cyclohexylamine 108-91-8 7 - 13
morpholine 110-91-8 7 - 13
Section 3. Hazards identification
Physical state : Liquid. [Liquid.]
Emergency overview : DANGER!
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
HARMFUL IF SWALLOWED.
COMBUSTIBLE LIQUID AND VAPOUR.
Do not ingest. Do not get in eyes, on skin or on clothing. Do not breathe vapour or
mist. Keep away from heat, sparks and flame. Keep container closed. Use only
with adequate ventilation. Wash thoroughly after handling.
: Skin contact, Eye contact, Inhalation, Ingestion
Routes of entry
Potential acute health effects
Eyes : Corrosive to eyes.
Skin : Corrosive to the skin.
Inhalation :
Corrosive to the respiratory system.
:
Ingestion Harmful if swallowed. Causes burns to mouth, throat and stomach.
See toxicological information (section 11)
Section 4. First-aid measures
Eye contact : In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention
immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
Skin Contact
removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Get medical attention immediately.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion : Rinse mouth; then drink one or two large glasses of water. Do not induce vomiting. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
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CORAVOL 1903
Section 5. Fire-fighting measures
: Not available.
Auto-ignition temperature
: 65 癈 (Closed cup)
Flash point
Flammable limits
Upper: Not available.
Lower: Not available.
Products of combustion : Not available.
Fire-fighting media and : In case of fire, use water spray (fog), foam, dry chemical, or CO2.
instructions
Dyke liquid for later disposal.
Combustible liquid and vapour.
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
for fire-fighters
mode.
Risk of explosion of the product in the presence of mechanical impact: Not available.
Risk of explosion of the product in the presence of static discharge: Not available.
Section 6. Accidental release measures
Personal : Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment (Section 8). Stop leak if without risk. Do not allow to
Precautions
enter drains or watercourses.
Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
precautions
waterways, soil or air).
Methods for : If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent
(soil may be used in the absence of other suitable materials) and use a non-sparking or
cleaning up
explosion-proof means to transfer material to a sealable, appropriate container for disposal.
For large spills, dyke spilt material or otherwise contain material to ensure runoff does not
reach a waterway. Place spilt material in an appropriate container for disposal.
Section 7. Handling and storage
Handling : Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Keep
container closed. Use only with adequate ventilation. Keep away from heat, sparks and flame.
To avoid fire, eliminate ignition sources. Wash thoroughly after handling.
Storage : Keep out of the reach of children. Store in a segregated and approved area. Keep container in
a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid
all possible sources of ignition (spark or flame).
Do not store below the following temperature: 0癈
Section 8. Exposure controls, personal protection
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. Provide eyewash and
safety shower in area if contact or splash hazard exists.
Personal protection :
Eyes : Use chemical splash goggles. For continued or severe exposure wear a face shield over the
goggles.
Hands : Use chemical-resistant, impervious gloves.
Skin : Use synthetic apron, other protective equipment as necessary to prevent skin contact.
Respiratory : Wear appropriate respirator when ventilation is inadequate and occupational exposure limits
are exceeded.
Name Exposure limits
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CORAVOL 1903
2-diethylaminoethanol ACGIH TLV (United States, 1/2006). Skin
TWA: 9.6 mg/m?8 hour(s).
TWA: 2 ppm 8 hour(s).
cyclohexylamine ACGIH TLV (United States, 1/2006).
TWA: 41 mg/m?8 hour(s).
TWA: 10 ppm 8 hour(s).
morpholine ACGIH TLV (United States, 1/2006). Skin
TWA: 71 mg/m?8 hour(s).
TWA: 20 ppm 8 hour(s).
Section 9. Physical and chemical properties
: Liquid. [Liquid.]
Physical state
: Colourless to light yellow.
Colour
: Amine-like.
Odour
: 12.74 [Conc. (% w/w): 100%]
pH
: 100癈 (212癋)
Boiling/condensation point
: Not available.
Melting/freezing point
Specific gravity : 0.98
: Not available.
Vapour pressure
: Not available.
Vapour density
: Not available.
Odour threshold
: Not available.
Evaporation rate
LogKow : Not available.
: Easily soluble in cold water, hot water.
Solubility
Section 10. Stability and reactivity
: The product is stable.
Stability
: Not available.
Conditions of instability
: Reactive with acids.
Reactivity
Slightly reactive to reactive with organic materials.
: Not available.
Hazardous Decomposition
Products
Section 11. Toxicological information
Potential acute health effects
: Corrosive to eyes.
Eyes
Skin : Corrosive to the skin.
: Corrosive to the respiratory system.
Inhalation
: Harmful if swallowed. Causes burns to mouth, throat and stomach.
Ingestion
Irritancy of Product : Hazardous by WHMIS criteria.
Potential chronic health effects
: No known significant effects or critical hazards.
Carcinogenic effects
Mutagenic effects : No known significant effects or critical hazards.
Teratogenic effects : No known significant effects or critical hazards.
Reproductive effects : No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Sensitization to Product
Synergistic products : Not available.
(toxicologically)
Toxicity data
Ingredient name Route Result Species
Test
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CORAVOL 1903
2-diethylaminoethanol LD50 Dermal 1 mL/kg Guinea pig
LD50 Dermal 1260 uL/kg Rabbit
LD50 Oral 1300 mg/kg Rat
cyclohexylamine LD50 Dermal 277 mg/kg Rabbit
LD50 Dermal 320 uL/kg Rabbit
LD50 Oral 224 mg/kg Mouse
LD50 Oral 11 mg/kg Rat
morpholine LD50 Dermal 500 uL/kg Rabbit
LD50 Oral 1220 mg/kg Mammal
LD50 Oral 525 mg/kg Mouse
LD50 Oral 1450 mg/kg Rat
LDLo Oral 100 mg/kg Guinea pig
: Contains material which causes damage to the following organs: kidneys, liver, mucous
Target organs
membranes, upper respiratory tract, skin, central nervous system (CNS), eye, lens or
cornea, throat.
Section 12. Ecological information
Ecotoxicity
Ingredient name Species Period Result
2-diethylaminoethanol Fish 96 hours Acute LC50 1780 mg/L
cyclohexylamine Fish 96 hours Acute LC50 90 mg/L
Fish 96 hours Acute LC50 44 mg/L
morpholine Fish 96 hours Acute LC50 380 mg/L
Fish 96 hours Acute LC50 350 mg/L
Section 13. Disposal considerations
Waste disposal : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Consult your local or regional authorities.
Section 14. Transport information
Regulatory UN number Proper shipping name Class Packing Additional information
information
group
Explosive Limit and Limited Quantity
TDG UN3267 CORROSIVE LIQUID, 8 II
BASIC, ORGANIC, Index
Classification
N.O.S. 1
(Diethylaminoethanol,
Morpholine) Passenger Carrying Road or Rail
Index
1
Special provisions
16
APPLIES ONLY DURING ROAD TRANSPORT
Any variation of the shipping description based on the packaging is not addressed.
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CORAVOL 1903
Section 15. Regulatory information
WHMIS : Class B-3: Combustible liquid with a flash point between 37.8癈 (100癋) and 93.3癈
(200癋).
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Class E: Corrosive material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
Section 16. Other information
Date of issue : 17-October-2007.
Responsible name : Regulatory Affairs
1-800-352-5326
Date of previous issue : 17-October-2007.
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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