MATERIAL SAFETY DATA SHEETS
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SECTION I: SUBSTANCE IDENTIFICATION AND COMPANY INFORMATION
USA/CANADA EMERGENCY TELEPHONE: 1.800.535.5053
MANUFACTURER'S NAME: ENTITY BEAUTY INC. INTERNATIONAL EMERGENCY TELEPHONE: 1.352.323.3500
INFORMATION CONTACT: INFOTRAC
ADDRESS: 440 W. ONTARIO STREET ENTITY'S FORMULA NUMBER: CONFIDENTIAL
PRODUCT CODE: 4022234 / 4022235
CHICAGO, IL 60654 USA
FAMILY: MONOMER
PRODUCT TYPE: ACRYLIC LIQUID
TRADE NAME: SIGNATURE SCULPTING LIQUID
PRODUCT USE: NAIL LIQUID ISSUED: JULY 30, 2005 (REVISION 1)
SECTION II: COMPOSITION AND INGREDIENT INFORMATION
Hazard Symbols: Xi F Safety Phrases: S9, S16, S29, S33, S36/37/39, S45 Risk Phrases: R11, R36/37/38, R43
CAS Number EINECS# U. S. INCI EU INCI
97-63-2 202-597-5 Ethyl Methacrylate Ethyl Methacrylate
97-90-5 202-617-2 Glycol HEMA-Methacrylate Glycol HEMA-Methacrylate
868-77-9 212-782-2 HEMA HEMA
119-61-9 204-337-6 Benzophenone Benzophenone
99-97-8 202-805-4 Dimethyltolylamine Dimethyltolylamine
81-48-1 201-353-5 Violet 2 CI 60725
Chemical Identity Exposure Limits Carcinogen %
OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Ethyl Methacrylate N/E N/E Not Listed 70-75
Ethylene Glycol N/E N/E Not Listed 10-15
Dimethacrylate Esters
2-hydroxyethyl methacrylate N/E N/E Not Listed 10-15
Benzophenone N/E N/E Not Listed 0-1
N,N-Dimethyl-p-toluidine N/E N/E Not Listed 0-1
D&C Violet #2 N/E N/E Not Listed 0-1 N/E =None
Established
SECTION III: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
Flammable liquid and vapor!
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May cause eye irritation.
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May cause skin irritation.
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Avoid prolonged or repeated breathing of gases, vapors or mists.
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Please read entire MSDS for additional information.
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Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry: Inhalation , skin , eyes
Eye: Vapor concentrations may cause irritation of eyes. Liquid contact with eyes can cause irritation
and possible corneal damage.
Skin: Liquid concentration may cause moderate skin irritation. Repeated or prolonged contact may cause
allergic skin rashes, itching and swelling which becomes evident on re-exposure to this product.
MATERIAL SAFETY DATA SHEETS
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Ingestion: Causes irritation, a burning sensation of the mouth, throat and respiratory tract and abdominal pain.
Inhalation: High vapor concentrations may irritate the respiratory system. Prolonged exposure can lead to
headaches , nausea , drowsiness and unconsciousness.
Sub-Chronic Effects: Unlikely to present a cancer hazard in man.
NOTE: Refer to Section 11, Toxicological Information for Details
SECTION IV: FIRST AID MEASURES
First Aid for Eye: Flush with water for 15 minutes, including under eyelids. Seek medical help if discomfort persists.
First Aid for Skin: Wash thoroughly with soap and water. Remove contaminated clothing and wash before reuse. Seek
medical attention if discomfort persists.
First Aid for Inhalation: Remove to fresh air. If having breathing difficulty, give oxygen. If breathing has stopped, give
artificial respiration. Get medical help if discomfort persists.
First Aid for Ingestion: Rinse mouth out with water. Only induce vomiting if directed by a physician. Never give anything
by mouth to an unconscious person. Seek prompt medical attention.
SECTION V: FIRE FIGHTING METHODS
Flash Point Flammable Limit Auto-ignition Temperature
(癋/癈) (vol%) (vol%)
LEL : 2% ; UEL : 2.5%
Tag Closed Cup: 68癋/20篊 392.8 ?C
Method:
Extinguishing Media: Foam, Carbon Dioxide, Dry Chemical or Carbon Tetrachloride.
Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective gear. Water may be ineffective
unless used as a fine spray or fog. Use water spray to cool the exposed containers of
methacrylate monomer.
Unusual Hazards: Vapors may travel to source of ignition and flash back. Avoid ignition sources or excessive
temperatures. Heat can induce polymerization with rapid release of energy. Closed containers
may rupture explosively. Spontaneous polymerization may occur with prolonged aging.
SECTION VI: ACCIDENTAL RELEASE MEASURES
Spill or Release Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill material into
Procedures: retaining containers. Place containers in a well ventilated area. Consult an expert on disposal of recovered
material and ensure conformity to local disposal regulations. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid
in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a
chemical waste container. Do not use combustible materials, such as sawdust. Do not flush to sewer! US
Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable
quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. EU
Regulations require the consultation of Directive 98/24/EC. If a leak or spill has not ignited, use water spray to
disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.
MATERIAL SAFETY DATA SHEETS
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SECTION VII: HANDLING AND STORAGE
Handling: Keep away from heat, sparks, flames and other sources of ignition. Avoid contact with eyes, skin and
clothing. Avoid breathing vapor or mist . Use with adequate ventilation. Ground all metal containers when
transferring and use explosion-proof equipment. Follow all MSDS/label precautions even after the
container is emptied because it may retain product residues. Wash thoroughly after handling.
Storage: Store in a cool, dry area. Keep container closed when not in use. Store at ambient temperatures out
of direct sunlight. Store in a well ventilated place. Store in accordance with National Fire Protection
Association recommendations. Maintain air space inside storage containers . Inhibitor requires air (
oxygen ) contact to function. Check inhibitor levels after 3 months and return to original level.
Explosion Hazard: Avoid ignition sources or excessive temperatures. Heat can induce polymerization with rapid release
of energy. Closed containers may rupture explosively. Spontaneous polymerization may occur with
prolonged aging.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
Engineering Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
Controls: levels below recommended exposure limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
General: To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that a
hazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132) be conducted before
using this product. Provide eye wash stations and safety showers. Wear impervious clothing to
prevent ANY contact with this product, such as gloves, apron, boots, or whole body suit. Nitrile
rubber is better than PVC.
Eye/ Face Protection: Wear safety glasses. Wear coverall chemical splash goggles and face shield when possibility exists for eye and
face contact due to splashing or spraying material.
Skin Protection: Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron, boots, or whole
body suit. Neoprene and Nitrile rubber is better than PVC.
Respiratory A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permis-
Protection: sible under certain limited circumstances where airborne concentrations are expected to exceed exsposure limits.
Protection provided by air purifying respirators is limited. Wear a NIOSH/MSHA or European Standard EN
149 approved full-facepeice airline respirator in the positive pressure mode with emergency escape provisions.
Follow OSHA repsirator regulations found in 29 CFR 1910.134 or Eurpean Standard EN 149.
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity <1mPas @ 20篊 % Volatile - W/W %: 99+
Clear to Blue- sharp ester-like odor N/A (H20=1): 0.918
violet liquid
Ignition
Boiling Point/ Decomposition Octanol/Water Vapor Vapor Evaporation Solubility In
Freezing Point Temperature Partitioning Coefficient Pressure: Density Rate Water (20癈)
Log Po/w 1. 25
243篎/117篊 N/A mm Hg: 0.69 (Air =1) : ButylAcetate N/A 0.5g/100g
N/DA kPa @ 38篊 3.9 =1: 1.5 @20篊
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
LEL : 2% ; UEL : 2.5%
Tag Closed Cup: 68癋/20篊 392.8 ?C
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SECTION X: STABILITY AND REACTIVITY
Stability: Incompatibility (Materials to Avoid):
Stable Reducing and oxidizing agents and UV light.
Hazardous Decomposition Products: Hazardous Polymerization:
Oxides of carbon when burned. May occur
Conditions to Avoid:
Temperatures above 60 F, oxidizing or reducing agents, peroxides and amines, storage in absence of inhibitor, and inadvertent
addition of catalyst.
SECTION XI: TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
Oral (Rat) LD50 : Dermal(Rabbit) LD50 : > Inhalation (Rabbit) LD 50: 3800 ppm N/DA N/DA
13300mg/kg 9100 mg/kg
Sensitization Mutagenicity Sub-chronic Toxicity
N/DA Test positive as a mutagen on laboratory animals N/DA
SECTION XII: ECOLOGICAL INFORMATION
Ecotoxicological Information
Acute Toxicity to Fish Acute Toxicity to Invertebrates Acute Toxicity to Algae Bioconcentration Toxicity to Sewage Bacteria
N/DA N/DA N/DA N/DA N/DA
Chemical Fate Information
N/DA
Biodegradability
N/DA
Chemical Oxygen Demand
SECTION XIII: DISPOSABLE CONSIDERATION
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors may explode
on ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less flammable and
incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.
Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may
differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements. For EU Member States, please refer to any relevant Community provisions relating to waste. In their absence, it is useful
to remind the user that national or regional provisions may be in force.
SECTION XIV: TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, ethylene glycol dimethacrylate), 3, UN1993, PGII
Identification Number: UN1993
Marine Pollutant: No
Special Provisions: T8, T31
Emergency Response Guidebook (ERG) #: 128
IATA (DGR):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, ethylene glycol dimethacrylate), 3, UN1993, PGII
Class or Division: 3
MATERIAL SAFETY DATA SHEETS
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UN or ID Number: UN1993
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, ethylene glycol dimethacrylate), 3, UN1993, PGII
Class or Division: 3.2
UN or ID Number: UN1993
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point = 20篊
SECTION XV: REGULATORY INFORMATION
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) as defined by the
U. S. Clean Air Act:
?Benzophenone CAS #119-61-9 (HAP).
This product does not contain any Class1 or Class 2 ODS.
Clean Water Act: This product contains the following Hazardous Substances as defined by the CWA:
?NONE
This product does not contain any substances that are a Priority Pollutant or Toxic
Pollutant under the CWA.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/or
other applications as an indirect food additive.
Occupational Safety and Health Act This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard. Its hazards are:
?Immediate (acute) health hazard
?Fire hazard.
RCRA This product is considered to be a hazardous waste under RCRA (40 CFR 261) RCRA
Code:
?Ethyl methacrylate, CAS# 97-63-2, RCRA Code: U118
?Characteristic of Ignitability, RCRA Code: D001
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely hazardous
substances that carry a TPQ.
SARA Title III: Section 302 (RQ) This product contains chemicals regulated under Section 304 as extremely hazardous
chemicals for emergency release notification ("CERCLA" List).
?Ethyl Methacrylate, CAS# 97-63-2, RQ (Lbs): 1000
SARA Title III: Section 311-312: This product is considered hazardous under the OSHA Hazard Communication Standard
and is regulated under Section 311-312 (40 CFR 370). Its hazards are:
?Immediate (acute) health hazard
?Fire hazard
SARA Title III: Section 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372:
?NONE
TSCA Section 8(b): Inventory: This product contains chemicals listed on the TSCA inventory or otherwise complies
with TSCA premanufacture notification requirements.
MATERIAL SAFETY DATA SHEETS
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State Regulations
CA Right-to-Know Law: NONE
California No Significant Risk Rule: NONE
MA Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
NJ Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
PA Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
FL Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
MN Right-to-Know Law: Benzophenone CAS #119-61-9 (HAP).
International Regulations
CDSL: Canadian Inventory Ethyl Methacrylate DSL regulatory status: Included, WHMIS: B2: flammable liquid D-2B: Toxic
(on Canadian Transitional N,N-dimethyl-p-toluidine DSL regulatory status: Included, WHMIS: n/da
List) Hydroxypropyl methacrylate DSL regulatory status: Included, WHMIS: D2B
Tetraethylene glycol dimethacrylate, n/da
EINECS: European Inventory: J-2 Acrylic Liquid:
?HAZARD SYMBOLS: Xi, F: Irritant, Highly Flammable
?RISK PHRASES: R11: highly flammable, R36/37/38: Irritating to eyes, respiratory system
and skin, R43: May cause sensitization by skin contact
?SAFETY PHRASES: S9: keep container in a well ventilated place, S16: keep away from
sources of ignition- no smoking, S29: do not empty into drains, S33: take precautionary
measures against static discharges, S36/37/39: wear suitable protective clothing, gloves
and eye/face protection, S45: In case of accident or if you feel unwell, seek medical
advise immediately (show the label where possible)
SECTION XVI: OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
1
Flammability
3
3
1 1
Reactivity
Health
1
The information presented herein was obtained from sources considered to be reliable. However, this information is provided without
any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and
other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected
with the handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials only
as directed. If the product is used as a component of another product, the information contained within the MSDS may not be
applicable. If one could have any concerns with or problems understanding this MSDS form, please direct all questions to INFOTRAC,
Chemical Emergency Resources System at 1(800) 535-5053.
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