MATERIAL SAFETY DATA SHEETS Page
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SECTION I: PREPARATION IDENTIFICATION AND COMPANY INFORMATION
MANUFACTURER'S NAME: ENTITY BEAUTY INC. EMERGENCY TELEPHONE NO: 1 800 535 5053
INFORMATION CONTACT: INFOTRAC
ADDRESS: 440 W. ONTARIO STREET
ENTITY'S FORMULA NUMBER:
CHICAGO, IL 60654 USA CONFIDENTIAL
PRODUCT CODE:
FAMILY: UV GELS
PRODUCT TYPE: NAIL COATING
TRADE NAME: ENTITY ONE GEL UV TOP COAT
PRODUCT USE: NAIL GEL ISSUED: 22 JUNE 2007 (REVISION 1)
SECTION II: COMPOSITION AND INGREDIENT INFORMATION
CAS EINECS# U. S. INCI EU INCI R Phrase S
Number Phrase
Not known Polyurethane acrylate Polyurethane acrylate none none
None
oligomer oligomer
109-17-1 203-653-1 PEG-4 dimethacrylate PEG-4 dimethacrylate none none
97-63-2 202-597-5 Ethyl methacrylate Ethyl methacrylate 11,36/37/38, 2,9,16,
43 29,33
none none
947-19-3 213-426-9 Hydroxycyclohexyl Hydroxycyclohexyl
phenyl ketone phenyl ketone
81-48-1 201-353-5 Violet 2 Violet 2 none none
Hazard Symbols: Xi F
Safety Phrases: S2, S9, S16, S29, S33 Risk Phrases: R11, R36/37/38, R43
Chemical Identity Exposure Limits Carcinogen %
OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Polyurethane acrylate oligomer N/E N/E Not listed 70-75
PEG-4 dimethacrylate N/E N/E Not listed 15-20
100 ppm 100 ppm Not listed 5-10
Ethyl methacrylate
Hydroxycyclohexyl phenyl N/E N/E Not listed 1-3
ketone
N/E N/E Not listed 0-1
Violet 2
N/E =None
Established
SECTION III: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
Flammable liquid and vapour!
?br>
May cause eye irritation. May cause respiratory irritation.
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May cause skin irritation.
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May cause skin sensitization
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Risk phrases - R11: highly flammable, R36/37/38: Irritating to eyes, respiratory system and skin, R43:
?br>
may cause sensitization by skin contact
Please read entire MSDS for additional information.
?br>
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Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry: Inhalation, skin, eyes, ingestion
Eye: Vapour or liquid exposure may cause irritation of eyes. Symptoms of exposure
may include stinging, tearing and/or redness.
Skin: Liquid concentration may cause skin irritation. Repeated or prolonged contact
may cause skin sensitization.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: High vapour concentrations may irritate the respiratory system. Prolonged
exposure can lead to dizziness and suffocation.
Chronic Health Effects Unlikely to present a cancer hazard in man.
NOTE: Refer to Section 11, Toxicological Information for Details
SECTION IV: FIRST AID MEASURES
First Aid for Eye: Flush with water for 15 minutes, including under eyelids. Seek medical
attention if discomfort persists.
First Aid for Skin: Wash thoroughly with soap and water. Remove contaminated clothing and
wash before re-use. Seek medical attention if discomfort persists.
First Aid for Inhalation: Remove to fresh air. Seek medical attention immediately. If having breathing
difficulty, give oxygen.
First Aid for Ingestion: Seek medical advice immediately. Remove to fresh air. Rinse out mouth with
water or induce vomiting only if directed by a physician. Never give anything
by mouth to an unconscious person. If vomiting occurs spontaneously, keep
head below hips to avoid aspiration into lungs.
SECTION V: FIRE FIGHTING MEASURES
Flash Point Flammable Limit Auto-ignition Temperature
(癋/癈) (vol%) (vol%)
No data No data
Pensky-Martin: 110癋/43癈
UN number: UN1263
Method:
Extinguishing Media: Foam, carbon dioxide, dry chemical
Fire Fighting Instructions: Remove all ignition sources. Wear self-contained breathing apparatus and full
protective clothing. Water spray or running water may be used to keep fire-
exposed containers cool.
Unusual Hazards: Flammable. High temperatures and fire conditions may cause rapid and
uncontrolled polymerization which can result in explosions and violent
rupture of storage vessels or containers. Avoid the use of a stream of water to
control fires since frothing can occur.
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SECTION VI: ACCIDENTAL RELEASE MEASURES
Spill or Release Eliminate all sources of heat and ignition. Use suitable protective clothing. Use
Procedures: absorbent material for spills and dike it, wash spill material into retaining containers.
Place containers in a well ventilated area. Consult an expert on disposal of recovered
material and ensure conformity to local disposal regulations.
Keep unnecessary and unprotected personnel from entering. Contain and recover
liquid when possible. Use non-sparking tools and equipment. Collect liquid in an
appropriate container or absorb with an inert material (e. g., vermiculite, dry sand,
earth), and place in a chemical waste container. Do not use combustible materials,
such as sawdust. Do not flush to sewer - although product is not labelled as dangerous
to the environment
EU Regulations require the consultation of Directive 98/24/EC. If a leak or spill has
not ignited, use water spray to disperse the vapours, to protect personnel attempting to
stop leak, and to flush spills away from exposures.
US Regulations (CERCLA) require reporting spills and releases to soil, water and air
in excess of reportable quantities. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802. .
SECTION VII: HANDLING AND STORAGE
Handling: Keep away from heat, sparks and other sources of ignition. Avoid contact with eyes,
skin and clothing. Avoid breathing vapour or mist. Use with adequate ventilation.
Follow all MSDS/label precautions even after container is emptied because it may
retain product residues. Wash thoroughly after handling.
Storein a cool, dry area. Keep container closed when not in use. Store at ambient
Storage: temperatures out of direct sunlight. Store in a well ventilated place. Store in
accordance with National Fire Protection Association recommendations.
Explosion Hazard: Avoid ignition sources or excessive temperatures. Closed containers may rupture
explosively.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
Engineering Use process enclosures, local exhaust ventilation, or other engineering controls to
Controls: control airborne levels below recommended exposure limits. Use explosion-proof
ventilation equipment.
Personal Protective Equipment
General: To identify additional Personal Protective Equipment (PPE) requirements, it is
recommended that a hazard assessment in accordance with the OSHA PPE
Standard (29CFR1910.132) or UK CoSHH regulations (or other appropriate EU
legislation) be conducted before using this product.
Provide eye wash stations and safety showers. Wear impervious clothing to
prevent ANY contact with this product, such as gloves, apron, boots, or whole
bodysuit. Nitrile rubber is better than PVC.
For professional use in beauty salons, the use of a fan is recommended to provide
fresh air supplies to operator.
Always check suitability of equipment with the supplier.
Eye/ Face Protection: Wear safety glasses. Wear coverall chemical splash goggles and face shield when
possibility exists for eye and face contact due to splashing or spraying material.
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Skin Protection: Use impermeable clothing to prevent any contact with this product, such as
gloves, apron, boots, or a whole body suit. Neoprene and nitrile rubber is better
than PVC.
Respiratory A NIOSH/MSHA approved air purifying respirator with an organic vapour
Protection: cartridge or canister may be permissible under certain limited circumstances where
airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-face piece airline respirator in the
positive pressure mode with emergency escape provisions.
Follow OSHA respirator regulations found in 29 CFR 1910.134 or Eurpean Standard
149.
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odour & Odour PH Specific Viscosity % Volatile - Solubility
Threshold Gravity In Water
(20癈)
Clear, semi- Acrylate odour N/A (H2O=1): N/A <0.5% by insoluble
viscous liquid 1.15 volume
Boiling Point/ Decomposition Octanol/Water Vapour Vapour Evaporation Ignition
Freezing Temperature Partitioning Pressure: Density Rate
Point Coefficient
N/DA N/DA N/A mm Hg: (Air=1): Isopropyl N/A
<0.01 @ N/DA alcohol = 1 :
20癈 N/DA
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
No data No data
Pensky-Martin: 110癋/ 43篊
SECTION X: STABILITY AND REACTIVITY
Stability: Incompatibility (Materials to Avoid):
Chemically stable under normal conditions Polymerization initiators including peroxides, strong
oxidizing agents, copper alloys, carbon steel, iron, rust
and strong bases.
Hazardous Decomposition Products: Hazardous Polymerization:
Oxides of nitrogen, carbon. May occur ?Uncontrolled polymerization may cause
rapid evolution of heat and increased pressure that could
result in violent rupture of sealed storage vessels or
containers.
Conditions to Avoid:
Storage < 100癋/38癋, exposure to light, loss of dissolved air, loss of polymerization inhibitor,contminations
with incompatible materials.
SECTION XI: TOXICOLOGICAL INFORMATION
Acute Oral Acute Dermal Acute Inhalation Toxicity Irritation - skin Irritation - Eye
Toxicity Toxicity
No data No data No data
ethyl acrylate is ethyl acrylate is an
an irritant irritant
Sensitisation Mutagenicity Sub-chronic Toxicity
ethyl acrylate may cause skin No data No data
sensitization
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SECTION XII: ECOLOGICAL INFORMATION
Ecotoxicological Information
Acute Toxicity to Acute Toxicity to Acute Toxicity to Bioconcentration Toxicity to
Fish Invertebrates Algae Sewage
Bacteria
No data No data No data No data No data
Chemical Fate Information
No data
Biodegradability
No data
Chemical Oxygen Demand
To the best of our knowledge, the ecotoxicological and chemical fate properties have not been thoroughly investigated. Do not allow
to enter drinking water supplies, wastewater, or soil.
SECTION XIII: DISPOSAL CONSIDERATIONS
Dispose of diking and absorbent materials in compliance with State, Local, and Federal regulations. Residual vapors
may explode on ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less
flammable and incinerate.
For EU Member States, please refer to any relevant Community provisions relating to waste. In their absence, it is
useful to remind the user that national or regional provisions may be in force.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to an approved
waste facility. Processing, use or contamination of this product may change the waste management options. State and
local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state and local requirements
SECTION XIV: TRANSPORT INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, PGIII
Identification Number: UN1993
Marine Pollutant: No
Special Provisions: T8, T31
Emergency Response Guidebook 128
(ERG) #:
IATA (DGR):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, PGIII
Class or Division: 3
UN or ID Number: UN1993
Packaging Instructions: PGII
Emergency Response Guidance 305, 307
(ICAO)#:
IMO (IMDG):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, PGIII
Class or Division: 3
UN or ID Number: UN1993
Special Provisions & None
Stowage/Segregation:
Emergency Schedule (EmS)#:
Other Information: Flash point = 43篊
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SECTION XV: REGULATORY INFORMATION
International Regulations
CDSL: Canadian Inventory Ethyl methacrylate DSL regulatory status: Included, WHMIS: B2:
(on Canadian Transitional flammable liquid, D-2B:Toxic
List) Tetraethyleneglycol diacrylate DSL regulatory status: Included,
WHMIS: not listed
Hydroxycyclohexyl phenyl ketone DSL regulatory status: Included,
WHMIS: not listed
D&C Violet #2 DSL regulatory status: Included, WHMIS: not listed
EINECS: European Inventory: # UV GEL TOP COAT:
?HAZARD SYMBOLS: Xi, F: Irritant, Flammable
?RISK PHRASES:
?R11: highly flammable,
?R36/37/38: Irritating to eyes. respiratory system and skin
R43: may cause sensitization by skin contact
SAFETY PHRASES:
S2: keep container in a well ventilated place,
S9: keep container tightly closed
S16: keep away from sources of ignition- no smoking,
S29: do not empty into drains
S33: Take precautionary measures against static discharges
SECTION XVI: OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
2
Flammability
2
2
2 1
Reactivity
Health
1
The information presented herein was obtained from sources considered to be reliable. However, this information is
provided without any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use
and/or application. For this and other reasons, we assume no responsibility and expressly disclaim liability for loss,
damage or expense arising out of any way connected with the handling, storage, use or disposal of the product. This
MSDS was prepared expressly for this product. Use the materials only as directed. If the product is used as a component
of another product, the information contained within the MSDS may not be applicable. If one could have any concerns
with or problems understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency
Resources System at 1(800) 535-5053.
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