11652 Monarch Street
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562-598-3966 Fax 598-8096.
Material Safety Data Sheet EzNails Monomer Page 1 of 1
Revised Date:07/20/2005 | Replaces Date: 10/27/04
MSDS#: KIM012501-R2L
Section 1 ?Identification of the Substance/Preparation and of the
Company/Undertaking
Product Name: R-2 Acrylic Liquid MSDS Approval
Date:
01/25/01
Chemical Name: N/A MSDS Prepared by: BSQ
Family: Monomer Manufacturer: KEYSTONE INDUSTRIES
616 Hollywood Ave, Cherry Hill, NJ 08002
Product Use: Nail Liquid Emergency Phone Numbers: (800) 535 - 5053
Product #:1000699-700-701 Information Contacts: ( 856 ) 663 - 4700
Section 2 - Composition/Information on Ingredients
Chemical Identity CAS EINECS# INCI Name Exposure Limits Carcinogen %
Numbers OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Ethyl Methacrylate 97-63-2 202-597-5 Ethyl methacrylate N/E N/E Not Listed 70-80
Tetraethylene glycol
dimethacrylate
109-17-1 203-653-1 PEG-4 Dimethacrylate N/E N/E Not Listed 10-15
2-hydroxyethyl methacrylate 868-77-9 212-782-2 HEMA N/E N/E Not Listed 10-13
N,N-Dimethyl-p-toluidine 99-97-8 202-805-4 Dimethyltolyamine N/E N/E Not Listed 0-1
D&C Violet #2 81-48-1 201-353-5 CI 60725 N/E N/E Not Listed 0-1
N/E - None Established
N/R - Not Reviewed
N/DA - No Data Available
N/A - Not Applicable
Hazard Symbols: Xi F Risk Phrases: R11, R36/37/38, R43 Safety Phrases: S9, S16, S29, S33,
S36/37/39, S45
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
? Flammable liquid and vapor!
? May cause eye irritation.
? May cause skin irritation.
? Avoid prolonged or repeated breathing of gases, vapors or mists.
? Please read entire MSDS for additional information.
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry Inhalation , skin , eyes
Eye Vapor concentrations may cause irritation of eyes. Liquid contact with eyes can cause irritation
and possible corneal damage.
Skin Liquid concentration may cause moderate skin irritation. Repeated or prolonged contact may
cause allergic skin rashes, itching and swelling which becomes evident on re-exposure to this
product.
Ingestion Causes irritation, a burning sensation of the mouth, throat and respiratory tract and abdominal
pain.
Inhalation High vapor concentrations may irritate the respiratory system. Prolonged exposure can lead to
headaches , nausea , drowsiness and unconsciousness.
Sub-Chronic Effects
Unlikely to present a cancer hazard in man.
NOTE: Refer to Section 11, Toxicological Information for Details
Section 4 - First Aid Measures
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
First Aid for Eye Flush with water for 15 minutes, including under eyelids. Seek medical help if discomfort
persists.
First Aid for Skin Wash thoroughly with soap and water. Remove contaminated clothing and wash before
reuse. Seek
medical attention if discomfort persists.
First Aid for Inhalation Remove to fresh air. If having breathing difficulty, give oxygen. If breathing has
stopped, give
artificial respiration. Get medical help if discomfort persists.
First Aid for Ingestion Rinse mouth out with water. Only induce vomiting if directed by a physician. Never
give anything
by mouth to an unconscious person. Seek prompt medical attention.
Material Safety Data Sheet R-2 ACRYLIC LIQUID Page 2 of 2
Revised Date:07/20/2005 | Replaces Date: 10/27/04
MSDS#: KIM012501-R2L
Section 5 - Fire Fighting Measures
Flash Point Flammable Limit Auto-ignition Temperature
(癋/癈) (vol%) (vol%)
Tag Closed Cup: 68癋/20篊 LEL : 2% ; UEL : 2.5% 392.8 ?C
Method:
Extinguishing Media: Foam, Carbon Dioxide, Dry Chemical or Carbon Tetrachloride.
Fire Fighting Instructions: Wear self-contained breathing apparatus and full protective gear. Water may be
ineffective
unless used as a fine spray or fog. Use water spray to cool the exposed containers of
methacrylate monomer.
Unusual Hazards: Vapors may travel to source of ignition and flash back. Avoid ignition sources or
excessive
temperatures. Heat can induce polymerization with rapid release of energy. Closed containers
may rupture explosively. Spontaneous polymerization may occur with prolonged aging.
Section 6 - Accidental Release Measures
Spill or Release
Procedures
Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill material
into
retaining containers. Place containers in a well ventilated area. Consult an expert on disposal of recovered
material and ensure conformity to local disposal regulations. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect
liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and
place in a chemical waste container. Do not use combustible materials, such as sawdust. Do not flush to
sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-
8802. EU Regulations require the consultation of Directive 98/24/EC. If a leak or spill has not ignited, use
water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away
from
exposures.
Section 7 - Handling and Storage
Handling Keep away from heat, sparks, flames and other sources of ignition. Avoid contact with eyes, skin
and
clothing. Avoid breathing vapor or mist . Use with adequate ventilation. Ground all metal containers when
transferring and use explosion-proof equipment. Follow all MSDS/label precautions even after the
container is emptied because it may retain product residues. Wash thoroughly after handling.
Storage Store in a cool, dry area. Keep container closed when not in use. Store at ambient temperatures out
of direct sunlight. Store in a well ventilated place. Store in accordance with National Fire Protection
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Association recommendations. Maintain air space inside storage containers . Inhibitor requires air (
oxygen ) contact to function. Check inhibitor levels after 3 months and return to original level.
Explosion Hazard Avoid ignition sources or excessive temperatures. Heat can induce polymerization with
rapid release
of energy. Closed containers may rupture explosively. Spontaneous polymerization may occur with
prolonged aging.
Section 8 - Exposure Controls / Personal Protective Equipment
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to
control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
General To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that
a
hazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132) be conducted
before using this product. Provide eye wash stations and safety showers. Wear impervious
clothing to prevent ANY contact with this product, such as gloves, apron, boots, or whole body
suit. Nitrile rubber is better than PVC.
Eye/ Face Protection Wear safety glasses. Wear coverall chemical splash goggles and face shield when
possibility exists for eye
and face contact due to splashing or spraying material.
Material Safety Data Sheet R-2 ACRYLIC LIQUID Page 3 of 3
Revised Date:07/20/2005 | Replaces Date: 10/27/04
MSDS#: KIM012501-R2L
Skin Protection Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron,
boots, or
whole body suit. Neoprene and Nitrile rubber is better than PVC.
Respiratory Protection A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge
or canister may be
permissible under certain limited circumstances where airborne concentrations are expected to exceed
exsposure limits. Protection provided by air purifying respirators is limited. Wear a NIOSH/MSHA or
European Standard EN 149 approved full-facepeice airline respirator in the positive pressure mode with
emergency escape provisions. Follow OSHA repsirator regulations found in 29 CFR 1910.134 or Eurpean
Standard EN 149.
Section 9 - Physical and Chemical Properties
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile
Clear, colorless liquid sharp ester-like odor N/A (H20=1): 0.95 Very viscous W/W %: 99+
Boiling Point/
Freezing Point
Decomposition
Temperature
Octanol/Water
Partitioning Coefficient
Log Po/w
Vapor Pressure: Vapor
Density
Evaporation
Rate
Ignition Solubility
In Water
(20癈)
EM A=243篎 N/A EMA=1. 25 EMA= mm Hg:
0.69 kPa @ 38篊
(Air=1)
EMA: 3.9
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
N/DA N/A N/DA
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
Tag Closed Cup: 68癋/20篊 LEL : 2% ; UEL : 2.5% 392.8 ?C
Section 10 - Stability and Reactivity
Stability: Incompatibility (Materials to Avoid):
Stable Reducing and oxidizing agents and UV light.
Hazardous Decomposition Products: Hazardous Polymerization:
Oxides of carbon when burned. May occur
Conditions to Avoid:
Temperatures above 60 F, oxidizing or reducing agents, peroxides and amines, storage in absence of
inhibitor, and inadvertent
addition of catalyst.
Section 11 - Toxicological Information
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
Oral (Rat) LD50 :
13300mg/kg
Dermal(Rabbit) LD50 : >
9100 mg/kg
Inhalation (Rabbit) LD 50: 3800 ppm N/DA N/DA
Since this product contains a very low concentration of active components, the primary toxicological information is
from the monomers.
Further hazardous properties cannot be excluded. The product should be handled with care when dealing with
chemicals.
Sensitization Mutagenicity Sub-chronic Toxicity
N/DA Test positive as a mutagen on laboratory animals N/DA
Section 12 - Ecological Information
Ecotoxicological Information
Acute Toxicity to Fish Acute Toxicity to Invertebrates Acute Toxicity to Algae Bioconcentration Toxicity to
Sewage Bacteria
N/DA N/DA N/DA N/DA N/DA
Chemical Fate Information
Biodegradability N/DA
Chemical Oxygen Demand N/DA
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
Section 13 - Disposable Considerations
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations.
Residual vapors may explode
on ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less
flammable
and incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a
RCRA approved waste
facility. Processing, use or contamination of this product may change the waste management options. State
and local disposal
regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state
Material Safety Data Sheet R-2 ACRYLIC LIQUID Page 4 of 4
Revised Date:07/20/2005 | Replaces Date: 10/27/04
MSDS#: KIM012501-R2L
and local requirements. For EU Member States, please refer to any relevant Community provisions relating
to waste. In their
absence, it is useful to remind the user that national or regional provisions may be in force.
Section 14 - Transport Information
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
DOT (49 CFR 172)
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, tetraethylene glycol dimethacrylate), 3,
UN1993,
PGII
Identification Number: UN1993
Marine Pollutant: No
Special Provisions: T8, T31
Emergency Response Guidebook (ERG) #: 128
IATA (DGR):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, tetraethylene glycol dimethacrylate), 3,
UN1993,
PGII
Class or Division: 3
UN or ID Number: UN1993
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, tetraethylene glycol dimethacrylate), 3,
UN1993,
PGII
Class or Division: 3.3
UN or ID Number: UN1993
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point = 20篊
Section 15 - Regulatory Information
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) as defined
by the
U. S. Clean Air Act:
?NONE
This product does not contain any Class1 or Class 2 ODS.
Clean Water Act: This product contains the following Hazardous Substances as defined by the CWA:
?NONE
This product does not contain any substances that are a Priority Pollutant or Toxic
Pollutant under the CWA.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging
and/or
other applications as an indirect food additive.
Occupational Safety and Health Act This product is considered to be a hazardous chemical under the
OSHA Hazard
Communication Standard. Its hazards are:
?Immediate (acute) health hazard
?Fire hazard.
RCRA This product is considered to be a hazardous waste under RCRA (40 CFR 261) RCRA
Code:
?Ethyl methacrylate, CAS# 97-63-2, RCRA Code: U118
?Characteristic of Ignitability, RCRA Code: D001
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as
extremely hazardous
substances that carry a TPQ.
SARA Title III: Section 302 (RQ) This product contains chemicals regulated under Section 304 as
extremely hazardous
chemicals for emergency release notification ("CERCLA" List).
?Ethyl Methacrylate, CAS# 97-63-2, RQ (Lbs): 1000
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
SARA Title III: Section 311-312: This product is considered hazardous under the OSHA Hazard
Communication Standard
and is regulated under Section 311-312 (40 CFR 370). Its hazards are:
?Immediate (acute) health hazard
?Fire hazard
Material Safety Data Sheet R-2 ACRYLIC LIQUID Page 5 of 5
Revised Date:07/20/2005 | Replaces Date: 10/27/04
MSDS#: KIM012501-R2L
SARA Title III: Section 313: This product contains the following substances subject to the reporting
requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372:
?NONE
TSCA Section 8(b): Inventory:
TSCA Significant New Use Rule:
This product contains chemicals listed on the TSCA inventory or otherwise complies with TSCA
premanufacture notification requirements.
None of the chemicals in this material have a SNUR under TSCA.
State Regulations
CA Right-to-Know Law:
California No Significant Risk Rule:
NONE
NONE
MA Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
NJ Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
PA Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
FL Right-to-Know Law: Ethyl Methacrylate CAS #97-63-2
MN Right-to-Know Law: None
International Regulations
CDSL: Canadian Inventory
(on Canadian Transitional List)
Ethyl methacrylate: DSL regulatory status: Included, WHMIS: B2: flammable liquid D-2B: Toxic
Tetraethylene glycol dimethacrylate: DSL regulatory status: Included, WHMIS: N/DA
2-Hydroxypropyl methacrylate: DSL regulatory status: Included, WHMIS: N/DA
N,N,-Dimethyl-p-toluidine: DSL regulatory status: Included, WHMIS: None
EINECS: European Inventory: R-2 Acrylic Liquid:
?HAZARD SYMBOLS: Xi, F: Irritant, Highly Flammable
?RISK PHRASES: R11: highly flammable, R36/37/38: Irritating to eyes, respiratory
system and skin, R43: May cause sensitization by skin contact
?SAFETY PHRASES: S9: keep container in a well ventilated place, S16: keep away from
sources of ignition- no smoking, S29: do not empty into drains, S33: take precautionary
measures against static discharges, S36/37/39: wear suitable protective clothing, gloves
and eye/face protection, S45: In case of accident or if you feel unwell, seek medical
advise immediately (show the label where possible)
Section 16 - Other Information
Hazard Rating System (Pictograms)
NFPA: HMIS:
13
1
Revised Sections since Last Version: Section 9 ?Flash Pt Overall Format Update
The information presented herein was obtained from sources considered to be reliable. However, this
information is provided without
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use
and/or application. For this and
other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense
arising out of any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared expressly
for this product. Use the
materials only as directed. If the product is used as a component of another product, the information
contained within the MSDS may
not be applicable. If one could have any concerns with or problems understanding this MSDS form, please
direct all questions to
INFOTRAC, Chemical Emergency Resources System at 1(800) 535-5053.
3
11
Flammability
Reactivity Health
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