AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
Section 1. Material Identification and Information
Hazardous Ingredients:
Component TOXICOLOGICAL DATA
CAS # %
Ethyl Methacrylate 97-63-2 < 10% OSHA TWA/STEL:
100ppm
ACGIH TWA/STEL:
100ppm
Section 2. Physical / Chemical Characteristics
Boiling Point: N/A Specific Gravity: 1.15
< 0.01 @ 20oC
Vapor Pressure: (H2O =1)
(mm Hg and Temperature) Melting Point: N/A
Vapor Density: No Data Evaporation Rate: N/A
(Air = 1) Water Reactive: N/A
Solubility in Water: Insoluble % Volatile: By Volume: < 0.5
Appearance: Clear, Semi-Viscous Liquid
Odor: Characteristic Acrylate Odor
Section 3. Fire and Explosion Hazard Data
110oF / 43oC (Penske-Martin)
Flash Point and Method Used:
Auto-Ignition Temperature: No Data
Flammability Limits in Air % by Volume: LEL: No Data
UEL: No Data
Use carbon dioxide or dry chemical for small fires; aqueous foam or
Extinguisher Media:
water for large fires.
Remove all ignition sources. Wear self-contained breathing
Special Fire Fighting Procedures:
apparatus and complete personal protective equipment when
entering confined areas where potential for exposure to vapors or
products of combustion exists.
High temperatures and fire conditions may cause rapid and
Unusual Fire and Explosion Hazards:
uncontrolled polymerization which can result in explosions and the
violent rupture of storage vessels or containers. Avoid the use of a
stream of water to control fires since frothing can occur.
Section 4. Reactivity Hazard Data
Unstable
Stability: Stable
Page 1 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
Storage < 100oF / 38oC, exposure to light, loss of dissolved air, loss of polymerization
Conditions to Avoid:
inhibitor, contamination with incompatible materials.
Incompatibility (Materials to Avoid):
Polymerization initiators including peroxides, strong oxidizing agents, copper, copper alloys,
carbon steel, iron, rust, and string bases.
Hazardous Decomposition:
Fumes produced when heated to decomposition may include: carbon monoxide, carbon
dioxide.
Hazardous Polymerization:
Will Not Occur
May Occur
Section 5. Health Hazard Data
Emergency Overview: Flammable liquid and vapor!
May be slightly toxic.
May cause moderate skin injury (reddening & swelling).
May cause chemical burn in eye.
Primary Routes of Entry:
Inhalation Ingestion
Skin Absorption Eye Contact
Carcinogen Listed In:
NTP OSHA
IARC Monograph Not Listed
Eye Contact: Contains materials that are essentially nonirritating, but contact may
Health Hazards:
cause slight transient irritation. Material may act as a Lachrymator
(a substance which increases the flow of tears).
Skin Contact: Contains materials that may cause moderate skin injury (reddening
and swelling) and/or sensitization. Prolonged contact may cause
blister formation (burns). Since irritation may not occur immediately,
contact can go unnoticed.
Inhalation: May cause respiratory tract irritation with presence of monomer.
Vapors may causes dizziness or suffocation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Sub-Chronic Effects: No specific information available. Limited tests showed no evidence
of teratogenicity in animals. A lifetime skin painting study with mice
showed no evidence of carcinogenicity.
Emergency First Aid Procedures:
Eye Contact: Flush with plenty of water for 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid. Do NOT allow victim to
rub or keep eyes closed.
Skin Contact: Remove contaminated clothing and wash contact area with soap and
water for 15 minutes. Get medical aid if system persist. Wash
clothing before reuse.
Page 2 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
Inhalation: In case of exposure to a high concentration of vapor or mist, remove
person to fresh air. If breathing has stopped, administer artificial
respiration and seek medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get
medical aid. Do NOT induce vomiting. If conscious and alert, rinse
mouth and drink 2 to 4 cupfuls of milk or water.
Section 6. Control and Protective Measures
Engineering Controls: Local exhaust recommended to control exposure which may result from operations
generating aerosols and hot operations generating vapors.
Personal Protective Equipment:
General: To identify additional Personal Protective Equipment (PPE)
requirements, it is recommended that a hazard assessment in
accordance with the OSHA PPE Standard (29 CFR 1910.132), or
European Standard EN166 be conducted before using this product.
Provide eye wash stations and safety showers. Wear impervious
clothing to prevent ANY contact with this product, such as gloves,
apron, boots, or whole body suit. Nitrile rubber is better than PVC.
Eye/Face Protection: Wear safety glasses. Wear coverall chemical splash goggles and
face shield when possibility exists for eye and face contact due to
splashing or spraying material.
Skin Protection: Use impermeable clothing to prevent ANY contact with this product,
such as gloves, apron, boots, or whole body suit. Nitrile rubber is
better than PVC.
Respiratory Protection: A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge or canister may be permissible under certain limited
circumstances where airborne concentrations are expected to
exceed exposure limits. Protection provided by nuisance level
organic vapor dust mask can be used, however the use of the
respirator is limited. Follow OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149.
Hygienic Work Practices:
Good Manufacturing Practices.
Page 3 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
Section 7. Precautions for Safe Handling and Use / Leak Procedures
Steps to be Taken if Material is Spilled or Released:
Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash
spill material into retaining containers. Place containers in a well ventilated area. Consult
an expert on disposal of recovered material and ensure conformity to local disposal
regulations. Keep unnecessary and unprotected personnel from entering. Contain and
remover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an
appropriate container or absorb with an inert material (e.g., vermiculite, dry sand, earth),
and place in a chemical waste container. Do not use combustible materials, such as
sawdust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and
releases to soil, water, and air in excess of reportable quantities. The toll free number for
the US Coast Guard National Response Center is (800) 424-8802. If a leak or a spill has
not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop
leak, and to flush away from exposures.
Waste Disposal Methods:
Dispose of diking materials and absorbent in compliance with State, Local, and Federal
regulations. Residual vapors may explode on ignition; do not cut, drill, or weld on or near
the container. Mix with compatible chemical which is less flammable and incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste
and sent to a RCRA approved waste facility. Processing, use or contamination of this
product may change the waste management options. State and local disposal regulations
may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state, and local requirements.
Precautions to be taken in Handling and Storing:
Ground and bond containers when transferring material. Avoid contact with skin and eyes,
and clothing. Use with adequate ventilation and avoid breathing in vapor. Keep container
closed when not in use. Avoid contact with heat, sparks and flame. Remove all
contaminated clothing, shoes, belts, and other leather goods immediately. Incinerate
leather goods (including shoes). Wash contaminated clothing thoroughly before reuse.
Wash skin thoroughly with soap and water after handling. Solvents should not be used to
clean skin because of increased penetration potential. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks, or open flames. Material is
extremely light sensitive. Use extreme care and do not expose to natural or UV light, unless
using material for it's intended use. Since the material is very photosensitive any type of
light may initiate the curing process.
Other Precautions and/or Special Hazards:
High temperatures and fire conditions may cause rapid and uncontrolled polymerization
which can result in explosions and the violet rupture of storage vessels or containers.
Page 4 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
Section 8. Toxicological Information
Acute Oral Toxicity: No Data Available
Acute Dermal Toxicity: No Data Available
Acute Inhalation Toxicity: No Data Available
Irritation - Skin: No Data Available
Irritation - Eye: No Data Available
Sensitization: No Data Available
Mutagenicity: No Data Available
Sub-Chronic Toxicity: No Data Available
Section 9. Ecological Information
Ecotoxicological Information:
Acute Toxicity to Fish: No Data Available
Acute Toxicity to Invertebrates: No Data Available
Acute Toxicity to Algae: No Data Available
Bioconcentration: No Data Available
Toxicity to Sewage Bacteria: No Data Available
Chemical Fate Information:
Biodegradability: No Data Available
Chemical Oxygen Demand: No Data Available
Section 10. Transport Information
DOT (49 CFR 172): Proper Shipping Name: Flammable Liquids, n.o.s., (ethyl methacrylate, acrylic
esters), 3, UN1993, PGIII
Identification Number: UN 1993
Marine Pollutant: No
Special Provisions: N/A
128
Emergency Response
Guidebook (ERG) #:
IATA (DRG): Proper Shipping Name: Flammable Liquids, n.o.s., (ethyl methacrylate, acrylic
esters), 3, UN1993, PGIII
Class or Division: 3.2
UN or ID Number: UN 1993
Packaging Instructions:
Emergency Response
Guidebook (ICAO) #:
Page 5 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
IMO (IMDG): Proper Shipping Name: Flammable Liquids, n.o.s., (ethyl methacrylate, acrylic
esters), 3, UN1993, PGIII
Class or Division: 3
UN or ID Number: UN 1993
None
Special Provisions &
Stowage/Segregation:
Emergency Schedule (Ems)#:
Section 11. Regulatory Information
US Federal Regulations
Clean Air Act HAP/ODS:
This product contains no hazardous air pollutants (HAP) or ODS's, as defined by the US
Clean Air Act. They are as follows:
Benzophenone, CAS #: 119-61-9
This product does not contain any Class 1 or Class 2 ODS.
Clean Water Act Priority Pollutant:
This product contains no chemicals listed under the US Clean Water Act Priority Pollutant
List.
FDA: Food Packaging Status:
This product has not been cleared by the FDA for use in food packaging and/or other
applications as an indirect food packaging additive.
Occupational Safety and Health Act:
This product is considered to be hazardous under the OSHA Hazard Communication
Standard. It's hazards are:
Immediate (acute) Health Hazard
Delayed (chronic) Health Hazard
Reactive Hazard
RCRA:
This product is considered to be hazardous waste under RCRA (40 CFR 261) RCRA Code:
Ethyl Methacrylate, CAS #: 97-63-2, RCRA Code: U118
Characteristic of Ignitability:, RCRA Code: D001
SARA Title III: Section 302 (TPQ)
This product contains no chemicals regulated under Sec. 302 as extremely hazardous
substances that carry a TPQ.
SARA Title III: Section 304 (RQ)
This product contains chemicals regulated under Sec. 304 as extremely hazardous
chemicals for emergency release notification ("CERCLA" List):
Ethyl Methacrylate CAS #: 97-63-2, RQ(lbs.): 1000
Page 6 of 7
AMERICAN INTERNATIONAL INDUSTRIES
2220 GASPAR AVENUE
LOS ANGELES, CA 90040
CHEM-TEL: (800) 255-3924
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: IBD Intense Seal DATE: 7/26/2004
FORMULA: 30-0018 REV. NEW
SARA Title III: Section 311-312:
This product is considered to be hazardous under the OSHA Hazard Communication
Standard and is regulated under Section 311-312 (40 CFR 370 ). Its hazards are:
Immediate (acute) health hazard
Delayed (chronic) health hazard
Reactive hazard
SARA Title III: Section 313:
This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and
40 CFR Part 372:
NONE
TSCA Section 8(b):
This product contains the following chemicals listed on the TSCA inventory or otherwise
complies with TSCA premanufacture notification requirements.
State Regulations
CA Right-to-Know Law: NONE
MA Right-to-Know Law: Ethyl Methacrylate CAS #: 97-63-2
NJ Right-to-Know Law: Ethyl Methacrylate CAS #: 97-63-2
PA Right-to-Know Law: Ethyl Methacrylate CAS #: 97-63-2
FL Right-to-Know Law: Ethyl Methacrylate CAS #: 97-63-2
MN Right-to-Know Law: Ethyl Methacrylate CAS #: 97-63-2
International Regulations
CDSL: Canadian Inventory (on Canadian Transitional List):
Ethyl Methacrylate CAS #: 97-63-2 is on the DSL List. WHMIS = B2, D2B.
Tetraethylene Glycol Dimethacrylate CAS #: 109-17-1 is not on the DSL List. WHMIS: N/A.
Benzophenone CAS # 119-61-9 is on the DSL List. WHMIS: Not Determined
D&C Violet #2 CAS #81-48-1, is not on the DSL List. WHMIS: Not Determined
EINECS: European Inventory:
QF2: Hazard Symbols: Xi: Irritant, F: Flammable
Risk Phrases: R22: Harmful if swallowed, R36/37/38: Irritating to eyes, respiratory
system, and skin, R43: May cause sensitization by skin contact.
Safety Phrases: S18: Handle and open container with care, S24/25: Avoid contact
with skin and eyes, S36/37: Wear suitable protective clothing and
gloves, S38: In case of insufficient ventilation, wear suitable
respiratory equipment, S46: If swallowed seek medical advice
immediately and show container or label.
Section 13. Other Information
Hazard Rating System:
NFPA: Health = 2/Flammability = 2/Reactivity = 1
NFPA: Health = 2/Flammability = 2/Reactivity = 1
Page 7 of 7
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