pressurize, cut weld, braze, solder, drill, grind or expose empty containers to heat, sparks or open flames. Material is
MATERIAL SAFETY DATA SHEET extremely light sensitive. Use extreme care and do not expose to natural or UV light, unless using material for its
YOU?Switzerland VIP Gel Ice intended use. Since the material is very photosensitive any type of light may initiate the curing process.
STORAGE: Keep away from heat, sparks and flame. Store in tightly closed container. Store in cool, dry, well-ventilated
place. Keep away from any type of light. Store at temperature below 100?F/38?C.
1. IDENTIFICATION OF SUBSTANCE/PREPARATION AND COMPANY EXPLOSION HAZARD: High temperature and fire conditions may cause rapid and uncontrolled polymerization that
PRODUCT NAME: YOU Switzerland VIP Gel Ice can result in explosions and the violent rupture of storage vessel or containers.
PRODUCT TYPE: UV Gel EMERGENCY 24-HOUR PHONE NO. CHEM-TEL ENGINEERING CONTROL: Local exhaust recommended to control exposure which may result from operations
APPLICATIONS: Nail enhancement In United States 1-800-255-3924 generating aerosols and hot operations generating vapors.
Outside United States (CALL COLLECT) 1-813-248-0585 CONDITIONS TO AVOID: Storage <100?F/38?C, exposure to light, loss of dissolved air, loss of polymerization inhibitor,
SUPPLIER: contamination with incompatible materials.
BACKSCRATCHERS SALON SYSTEMS, INC. EMERGENCY CONTACT IN EUROPEAN UNION:
9068 Elkmont Way TEL + 32 2 743 1540 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Elk Grove, CA 95624 Avenue de Tervueren 300 ACUTE ORAL TOXICITY: N/DA IRRITATION-EYE: N/DA SUB-CHRONIC TOXICITY: N/DA
1-916-686-2400 B-1150 Brussels, BELGIUM ACUTE DERMAL TOXICITY: N/DA SENSITIZATION: N/DA MUTAGENICITY: N/DA
ACUTE INHALATION TOXICITY: N/DA IRRITATION-SKIN: N/DA
2. COMPOSITION/INFORMATION ON INGREDIENTS
INCI INGREDIENT NAME CAS NO. CONTENTS EXPOSURE LIMITS Carcinogen PERSONAL PROTECTION: To identify additional personal protective equipment (PPE) requirements, it is recommended
OSHA ACGIH ARC/NTP that a hazard assessment in accordance with OSHA PPE Standard (29CFR1910.132), or European Standard EN 166 be
TWA/STEL TWA/STEL /OSHA conducted before using this product. Provide eye wash stations and safety showers. Wear impervious clothing to
Acrylic Oligomer N/E 70% N/E N/E Not Listed prevent ANY contact with this product, such as gloves, apron, boots, or whole body suit. Nitrile rubber is better than
PVC.
PEG-4 Dimethacrylate 109-17-1 20% N/E N/E Not Listed
HAND PROTECTION: Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron,
Ethyl Methacrylate 97-63-2 10% 100ppm 100ppm Not Listed
boots, or whole body suit. Nitrile rubber is better than PVC.
Benzophenone 119-61-9 2% N/E N/E Not Listed EYE PROTECTION: Wear safety glasses. Wear coverall chemical splash goggles and face shield when possibility exists
CI 60725 (Violet 2) 81-48-1 1% N/E N/E Not Listed for eye and face contact due to splashing or spraying material.
VENTILATION: G
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air-purifying respirator with an organic vapor cartridge or
3. HAZARDS IDENTIFICATION
canister may be permissible under certain limited circumstances where airborne concentrations are expected to exceed
HAZARD SYMBOLS: Xi, F
exposure limits. Protection provided by nuisance level organic vapor dust masks can be used; however the use of the
This information is based on findings from related or similar materials.
respirator is limited. Follow OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN149.
HMIS: HEALTH- 2 FLAMMABILITY- 1 CHEMICAL REACTIVITY - 1
9. PHYSICAL AND CHEMICAL PROPERTIES
4. FIRST AID MEASURES
APPEARANCE: Clear/semi viscous liquid COLOR/ODOR: characteristic acrylate odor
EYES: Flush with plenty of water for 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. DO
BOILING POINT: N/A WATER SOLUBILITY: Insoluble
NOT allow victim to rub or keep eyes closed.
FLASH POINT: 110?F/43?C Penske-Martin AUTO IGNITION TEMP: N/DA
SKIN: Remove contaminated clothing and wash contact area with soap and water for 15 minutes. Get medical aid if
VISCOSITY: N/DA REFRACTIVE INDEX [68?F/20?C]: N/DA
systems persist. Wash clothing before reuse.
SOLUBILITY IN: N/DA ACID NO. [mgKOH/g]: N/DA
INGESTION: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If
SPECIFIC GRAVITY 25/25: VAPOR PRESSURE: (mm Hg) @ 20篊: <0.01
conscious and alert, rinse mouth and drink 2 to 4 cups of milk or water.
VAPOR DENSITY: N/DA pH: N/DA
INHALATION: In case of exposure to high concentration of vapor or mist, remove person to fresh air. If breathing has
SPECIAL GRAVITY (H20+1):1.15 % VOLATILE BY VOLUME: <0.5
stopped, administer artificial respiration and seek medical attention.
FREEZING POINT: N/DA DECOMPOSITION TEMPERATURE: N/DA
OCTANOL/WATER PARTITIONING COEFFICIENT LOG PO/W: EVAPORATION RATE: N/DA
5. FIREFIGHTING MEASURES
N/DA FLAMMABLE LIMIT: N/DA
FLASH POINT (癋/癈): 110?F/43?C FLAMMABLE LIMIT (vol%): N/DA
IGNITION: N/DA
AUTO-IGNITION TEMPERATURE (vol%): N/DA
EXTINGUISHING MEDIA: Use carbon dioxide or dry chemical for small fires; aqueous foam or water for large fires.
CONDITIONS TO AVOID: Storage <100?F/38?C, exposure to light, loss of dissolved air, loss of polymerization inhibitor,
SPECIAL FIREFIGHTING PROCEDURES AND PRECAUTIONS: Remove all ignition sources. Wear self-contained
contamination with incompatible materials.
breathing apparatus and complete personal protective equipment when entering confined areas where potential for
exposure to vapors or products of combustion exists.
10. STABILITY AND REACTIVITY
UNUSUAL FIRE AND EXPLOSION HAZARDS: High temperatures and fire conditions may cause rapid and uncontrolled
STABILITY: Normally stable
polymerization that can result in explosions and the violent rupture of storage vessels or containers. Avoid the use of a
INCOMPATIBILTY: Polymerization initiators including peroxides, strong oxidizing agents, copper, copper alloys,
stream of water to control fires since frothing can occur.
carbon steel, iron, rust and string bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Fumes produced when heated to decomposition may include: carbon
6. ACCIDENTAL RELEASE MEASURES
monoxide, carbon dioxide.
SPILL CLEANUP METHODS: Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it,
HAZARDOUS POLYMERIZATION: May occur. Uncontrolled polymerization may cause rapid evolution of heat and
wash spill material into retaining containers. Place containers in a well ventilated area. Consult an expert on disposal of
increased pressure that could result in violent rupture of sealed storage vessels or containers.
recovered material and ensure conformity to local disposal regulations. Keep unnecessary and unprotected personnel
NFPA REACTIVITY CODE:
from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an
CONDITION TO AVOID: Storage <100?F/38?C, exposure to light, loss of dissolved air, loss of polymerization inhibitor,
appropriate container or absorb with an inert materials (e.g. vermiculite, dry sand, earth) and place in a chemical waste
contamination with incompatible materials.
container. Do not use combustible materials, such as sawdust. Do not flush to sewer! US regulations (CERCLA) require
reporting spills and releases to soil, water and air in excess of reportable quantities. The toll-free number of the US
11. TOXICOLOGY INFORMATION
Coast Guard National Response Center is (800) 424-8802. If leak or spill has ignited, use water to spray to disperse to
ROUTE(S) OF ENTRY: No specific information available.
vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.
INGESTION: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
WASTE DISPOSAL METHOD: N/DA
EYES: Contains materials that are essentially nonirritating, but contact may cause slight transient irritation. Materials
may act as Lachrymator (a substance which increases the flow of tears).
7. HANDLING AND STORAGE
INHALATION: May cause respiratory tract irritation with presence of monomer. Vapors may cause dizziness or
HANDLING: Ground and bond containers when transferring material. Avoid contact with skin and eyes, and clothing.
suffocation.
Use with adequate ventilation and avoid breathing vapor. Keep container closed when not in use. Avoid contact with
SKIN: Contains materials that may cause moderate skin injury (reddening and swelling) and/or sensitization. Prolonged
heat, sparks and flame. Remove all contaminated clothing, shoes, belts and other leather goods immediately. Incinerate
contact may cause blister formation (burns). Since irritation may not occur immediately, contact can go unnoticed.
leather goods (including shoes). Wash contaminated clothing thoroughly before reuse. Wash skin thoroughly with soap
and water after handling. Solvents should not be used to clean skin because of increased penetration potential. Do not
HEALTH HAZARDS: TSCA Section 8 (b): Inventory: This product contains chemicals listed in the TSCA inventory or otherwise complies
SUB-CHRONIC EFFECTS: No specific information available. Limited tests showed no evidence of teratogenicity in with TSCA premanufacture notification requirements.
animals. A lifetime skin painting study with mice showed no evidence of carcinogenicity.
STATE REGULATIONS:
CA Right-to-Know Law: None
12. ECOLOGICAL INFORMATION
California No Significant Risk Rule: None
ACUTE TOXICITY: CHEMICAL FATE INFORMATION:
MA Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
TO FISH: N/DA BIODEGRADABILITY: N/DA
NJ Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
TO INVERTEBRATE: N/DA CHEMICAL OXYGEN DEMAND: N/DA
PA Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
TO ALGAE: N/DA
FL Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
BIOCONCENTRATION: N/DA
MN Right-to-Know Law: Benzophenone, CAS # 119-61-9
TOXICITY TO SEWAGE BACTERIA: N/DA
INTERNATIONAL REGULATIONS:
13. DISPOSAL CONSIDERATIONS:
CDSL: Canadian Inventory
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors
Ethyl Methacrylate, CAS # 97-63-2 is on the DSL List. WHMIS=B2, D2B.
may explode on ignition; do not cut, drill, or weld on or near container. Mix with compatible chemical which is less
Tetraethylene Glycol Dimethacrylate, CAS # 109-17-1 is not on the DSL List. WHMIS=N/DA
flammable and incinerate.
Benzophenone CAS # 119-61-9 is on the DSL List. WHMIS=N/DA
D&C Violet #2, CAS # 81-48-1 is not on the DSL List. WHMIS=N/DA
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA
approved waste facility. Processing, use or contamination of this product may change the waste management options.
EINECS: European Inventory
State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused
Permatop:
contents in accordance with federal, state and local requirements.
HAZARD SYMBOL: Xi: Irritant, F: Flammable
14. TRANSPORT INFORMATION
RISK PHRASES:
GROUND: Consumer Commodity ?ORM-D AIR: Consumer Commodity CLASS 9 ID 8006
R22: Harmful if swallowed.
OCEAN: Flammable Liquid, N.O.S. Ethyl Methacrylate UN: 1993, PG III, 43C
R/36/37/38: Irritating to eyes, respiratory system and skin.
R43: May cause sensitization by skin contact.
15. REGULATORY INFORMATION
RISK PHRASES:
SAFETY PHRASES:
R22 ?Harmful if swallowed. R38 ?Irritating to skin.
S18: Handle an open container with care.
R36 ?Irritating to eyes. R43 ?May cause sensitization by skin contact.
S24/25: Avoid contact with skin and eyes.
R37 ?Irritating to respiratory system.
S36/37: Wear suitable protective clothing and gloves.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.
SAFETY PHRASES:
S46: If swallowed, seek medical advice immediately and show the container or label.
S18 ?Handle an open container with care. S38 ?In case of insufficient ventilation, wear suitable
S24 ?Avoid contact with skin. respiratory equipment.
16. OTHER INFORMATION
S25 ?Avoid contact with eyes. S46 ?If swallowed, seek medical advice immediately
HAZARD RATING SYSTEM:
S36 ?Wear suitable protective clothing. (show the label whenever possible).
NFPA: Health 2/ Flammability 2/ Reactivity 1
S37 ?Wear suitable gloves.
HMIS: Health 2/ Flammability 2/ Reactivity 1
OSHA PEL for misance dust: 15 mg/m3 (total dust)
US FEDERAL REGULATIONS:
5 mg/m3 (respirable dust)
CLEAN AIR ACT: HAP/ODS: This product contains hazardous air pollutants (HAP's), as defined by US Clean Air Act. They
ACGIH PEL for misance dust: 10 mg/m3
are as follows: Benzophenone, CAS # 119-61-9 ODS. This product does not contain any Class 1 or Class 2 (ODS's) (Ozone
Depleting Substance).
ABBREVIATION KEY:
N/E: None established N/R: Not reviewed
CLEAN WATER ACT: PRIORITY POLLUTANT: This product contains the following Hazardous Substances as defined by
ND/A: No data available N/A: Not available
the CWA: NONE. This product does not contain any substances that are a Priority Pollutant or Toxic Pollutant under the
CWA.
GUIDANCE NOTES: The data contained herein is based upon information that Backscratchers believes to be reliable.
Users of this product have the responsibility to determine the suitability of use and to adopt all necessary precautions
FDA: FOOD PACKAGING STATUS: This product has not been cleared by the FDA for use in food packaging and/or
to ensure the safety and protection of property and persons involved in said use. All statements or suggestions are
other applications as an indirect food additive.
made without warranty, express or implied, regarding accuracy of the information, the hazards connected with the use
of the material or the results to be obtained from the use thereof. For this and other reasons, we assume no
OCCUPATIONAL SAFETY AND HEALTH ACT: This product is considered to be hazardous under the OSHA Hazard
responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with
Communication Standard. Its hazards are: Immediate (acute) health hazard; Delayed (chronic) health hazard; Reactive
handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials
hazard.
only as directed. If the product is used as a component of other products, the information contained within this MSDS
may not be applicable.
RCRA: This product is considered to be hazardous waste under RCRA (40 CFR 261) RCRA Code: Ethyl Methacrylate, CAS
# 97-63-2, RCRA Code U118; Characteristic of Ignitability, RCRA Code: D001.
REVISION COMMENTS:
DATE: 8/10/06
SARA Title III: Section 302(TPQ): This product contains no chemicals regulated under Section 302 as extremely
hazardous substances that carry a TPQ.
SARA Title III: Section 304(RQ): This product contains chemicals regulated under Section 304 as extremely hazardous
chemicals for emergency release notification (CERCLA List): Ethyl Methacrylate, CAS # 97-63-2, RQ (lbs.): 1000.
SARA Title III: Section 311-312: This product is considered hazardous under OSHA Hazard Communication Standard
and is regulated under Section 311-312 (40 CFR 370). Its hazards are: Immediate (acute) health hazard; Delayed
(chronic) health hazard; Reactive hazard.
SARA Title III: Section 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372: None
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