Manufacturer of Beauty Products
1950 Compton Ave. Ste. 103
Corona, CA. 92881
Phone: (951) 808 ?4730 Fax: (951) 808 ?4734
MATERIAL SAFETY DATA SHEET
Section I: Product and Company Identification
CHRISTRIO CORP.
Product name: French Topcoat Manufacturer:
Chemical Name: N/A 1950 Compton Ave. #103
Corona, CA. 92881
Family Name: Cellulose Acetate Butyrate Lacquer
Product Use: NAIL LACQUER Emergency Phone #: 800 535- 5053
International Phone #: 1-352-323-3500
Information Contact: (951) 808 ?4730
Section II: Composition/Information on Ingredients
Exposure Limits Carcinogen
Chemical Identity CAS# INCI Name %
OSHA ACGIH IARC/NTP/
OSHA
TWA/STEL TWA/STEL
141-78-6 N/E N/E Not Listed 30
ETHYL ACETATE ETHYL ACETATE
123-86-4 N/E N/E Not Listed 30
BUTYL ACETATE BUTYL ACETATE
67-63-0 N/E N/E Not Listed 20
ISOPROPYL ALCOHOL ISOPROPYL ALCOHOL
METHYL ETHYL METHYL ETHYL
N/E N/E Not Listed
78-93-3 10
KETONE KETONE
COLLODION COLLODION
N/E N/E Not Listed
9004-70-0 10
NITROCELLULOSE NITROCELLULOSE
*** No toxic chemical (s) subject to the reporting requirements of section 313 of title III and of 40 CFR 372 are present.***
N/E ?None Established Hazard Symbols: Xi, F
N/R ?Not Reviewed Risk Phrases: R22, R336/37/38, R43
ND/A ?No Data Available Safety Phrases: S18, S24/25, S36/37, S38, S46
N/A ?Not Available
Section III: Hazard Identification
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
Flammable liquid and vapor!
May be slightly toxic.
May cause moderate skin injury (reddening & swelling).
May cause chemical burn in eye.
Potential Health Effects, signs and symptoms of Exposure:
Primary Route of Entry No specific information available
Eye Contains materials that are essentially nonirritating, but contact may cause slight transient irritation. Materials
may act as Lachrymator (a substance which increases the flow tears).
Skin Contains materials that may cause moderate skin injury (reddening and swelling) and/or sensitization.
Prolonged contact may cause blister formation (burns). Since irritation may not occur immediately, contact can
go unnoticed.
Ingestion May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation May cause respiratory tract irritation with presence of monomer. Vapors may cause dizziness or suffocation.
Sub-Chronic Effects No specific information available. Limited tests showed no evidence of teratogenicity in animals. A lifetime
skin painting study with mice showed no evidence of carcinogenicity.
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NOTE: Refer to section XI, Toxicological Information for Details.
Section IV: First Aid Measures
First Aid for eye Flush with plenty of water for 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Do NOT allow victim to rub or keep eyes closed.
First Aid for Skin Remove contaminated clothing and wash contact area with soap and
water for 15 minutes. Get medical aid if systems persist. Wash clothing before reuse.
First Aid for Inhalation In case of exposure to a high concentration of vapor or mist, remove person to fresh air. If breathing has
stopped, administer artificial respiration and seek medical attention.
First Aid for Ingestion Never give any thing by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2 to 4 cupfuls of milk or water.
Section V: Fire fighting Measures
Flash Point Flammable Limit Auto-ignition Temperature
(癋/癈) (vol%) (vol%)
24篎/-4.45篊
N/D N/D
Method:
Extinguishing Media: Use carbon dioxide or dry chemical for small fires; aqueous foam or water for large fires.
Fire Fighting Instctions: Remove all ignition sources. Wear self-contained breathing apparatus and complete personal protective
equipment when entering confined areas where potential for exposure to vapors or products of combustion
exists.
Unusual Hazards: High temperatures and fire conditions may cause rapid and uncontrolled polymerization which can result in
explosions and the violent rupture of storage vessels or containers. Avoid the use of a stream of water to
control fires since frothing can occur.
Section VI: Accident Release Measures
Spill or Release Procedures Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill
material into retaining containers. Place containers in a well ventilated area. Consult an expert on
disposal of recovered material and ensure conformity to local disposal regulations. Keep unnecessary
and unprotected personnel from entering. Contain and recover liquid when possible. Use non-sparking
tools and equipment. Collect liquid in an appropriate container or absorb with an inert materials (e.g.,
vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible
materials, such as sawdust. Do not flush to sewer! US regulations (CERCLA) require reporting spills
and releases to soil, water and air in excess of reportable quantities. The toll free number of the US
Coast Guard National Response Center is (800) 424-8802. If a leak or spill has not ignited, use water
to spray to disperse to vapors, to protect personnel attempting to stop leak, and to flush spills away
from exposures.
Section VII: Handling and Storage
Handling Ground and bond containers when transferring material. Avoid contact with skin and eyes, and clothing. Use
with adequate ventilation and avoid breathing vapor. Keep container closed when not in use. Avoid contact
with heat, sparks and flame. Remove all contaminated clothing, shoes, belts and other leather goods
immediately. Incinerate leather goods (including shoes). Wash contaminated clothing thoroughly before reuse.
Wash skin thoroughly with soap and water after handling. Solvents should not be used to clean skin because of
increased penetration potential. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks, or open flames. Material is extremely light sensitive. Use extreme care and do not
expose to natural or UV light, unless using material for its intended use. Since the material is very
photosensitive any type of light may initiate the curing process.
Storage Keep away from heat, sparks, and flame. Store in tightly closed container. Store in cool, dry, well-ventilated
place, keep it away from any type of light. Store at temperature below 100癋/38癈.
Explosion Hazard High temperature and fire conditions may cause rapid and uncontrolled polymerization which can result in
explosions and the violent rupture of storage vessel or containers.
Section VII: Exposure Controls/Personal Protective Equipment
Engineering Control Local exhaust recommended to control exposure which may result from operations generating aerosols and hot
operations generating vapors.
Personal Protective Equipment
General To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that a hazard
assessment in accordance with the OSHA PPE Standard (29CFR1910.132), or European Standard EN166 be
conducted before using this product. Provide eye wash stations and safety showers. Wear impervious clothing
to prevent ANY contact with this product, such as gloves, apron, boots, or whole body suit. Nitrile rubber is
better than PVC.
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Eye/Face Protection Wear safety glasses. Wear coverall chemical splash goggles and face shield when possibility exists for eye and
face contact due to splashing or spraying material.
Skin Protection Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron, boots, or whole
body suit. Nitrile rubber is better than PVC.
Respirator Protection A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be
permissible under certain limited circumstances where airborne concentrations are expected to exceed exposure
limits. Protection provided by nuisance level organic vapor dust masks can be used, however the use of the
respirator is limited. Follow OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN
149.
Section XI: Physical and Chemical Properties
Appearance Odor & Odor Threshold pH Special Gravity Viscosity % Volatile
Clear/semi Sweet ester oil N/A (H2O = 1): 1.15 N/DA By Volume:<0.5
Viscous liquid
BOILING RANGE: 171oF- 228oF SPECIFIC GRAVITY (h20=1): 7.502 lb/gl
VAPOR DENSITY: Heavier than air EVAPORATION RATE (m-Butyl Acetate=1): > 1.0
COATING V.O.C.: 3.36 lb/gl MATERIAL V.O.C.: 3.34 lb/gl
SOLUBILITY IN WATER: moderate
Section X: Stability and Reactivity
Stability: Incompatibility (Materials to Avoid):
Normally Stable Polymerization initiators including peroxides, strong oxidizing agents, copper,
copper alloys, carbon steel, iron, rust and string bases.
Hazardous Decomposition Products: Hazardous Polymerization:
Fumes produced when heated to decomposition May occur--Uncontrolled polymerization may cause
may include: carbon monoxide, carbon dioxide. cause rapid evolution of heat and increased pressure that could result in violent rupture of sealed storage
vessels or containers.
Condition to Avoid:
Storage <100癋/38癈, exposure to light, loss of dissolved air, loss of polymerization inhibitor, contamination with incompatible materials.
Section XI: Toxicological Information
Acute Oral Acute Dermal Acute Inhalation Irritation-Skin Irritation-Eye
Toxicity Toxicity Toxicity
N/DA N/DA N/DA N/DA N/DA
Sensitization Mutagenicity Sub-chronic Toxicity
N/DA N/DA N/DA
Section XII: Ecological Information
Ecological Information
Acute Toxicity Acute Toxicity Acute Toxicity Bioconcentration Toxicity to
To Fish to Invertebrate to Algae Sewage Bacteria
N/DA N/DA N/DA N/DA N/DA
Chemical Fate Information
Biodegrapdability N/DA
Chemical Oxygen Demand N/DA
Section XIII: Disposable Considerations
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors may explode on ignition; do not cut,
drill, or weld on or near container. Mix with compatible chemical which is less flammable and incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or
contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.
Section XIV: Transport Information
Proper shipping name: Paint
DOT Haz Class: 3 (Flammable Liquid)
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UN#: 1263,
Packing Group: PG II
Section XV: Regulatory Information
US Federal Regulations:
Clean Air Act: HAP/ODS This product contains hazardous air pollutants (HAP's), as defined by U.S. C lean Air Act. They are
as follows:
Benzophenone, CAS# 119-61-9 ODS
This product does not contain any Class 1 or Class 2 (ODS's). (Ozone Depleting Substances).
Clean Water Act: Priority Pollutant This product contains the following Hazardous Substances as defined by the CWA: NONE
This product does not contain any substances that are a Priority Pollutant or Toxic Pollutant under
the CWA.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/or other applications as
an indirect food additive.
Occupational Safety and Health This product is considered to be hazardous under the OSHA
Act Hazard Communication Standard. Its hazards are:
Immediate (acute) health hazard
Delayed (chronic) health hazard
Reactive hazard
RCRA This product is considered to be hazardous waste under RCRA (40 CFR 261) RCRA Code:
?Ethyl Methacrylate, CAS # 97-63-2, RCRA Code: U118
?Characteristic of Ignitability, RCRA Code: D001
SARA Title III: Section 302(TPQ) This product contains no chemicals regulated under Sec. 302 as extremely hazardous substances that
carry a TPQ.
SARA Title III: Section 302 (RQ) This product contains chemicals regulated under Section 304 as extremely hazardous chemicals for
emergency release notification ("CERCLA" List).
Ethyl Methacrylate, CAS #97-63-2, RQ (Lbs): 1000
SARA Title III: Section 311-312 This product is considered hazardous under OSHA Hazard Communication Standard and is
regulated under Section 311-312 (40 CFR 370). Is hazard are:
Immediate (acute) health hazard
Delayed (chronic) health hazard
Reactive hazard
SARA Title III: Section 313 This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
None
TSCA Section 8 (b): Inventory This product contains chemical listed on the TSCA inventory or otherwise complies with TSCA
premanufacture notification requirements.
State Regulations:
CA Right-to-know Law: None
California No Significant
Risk Rule: None
MA Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
NJ Right-to-Know Law: Ethyl Methacrylate, CAS # 97-63-2
PA Right-to-Know Law: Ehtyl Methacrylate, CAS # 97-63-2
FL Right-to-Know Law: Ehtyl Methacrylate, CAS # 97-63-2
MN Right-to-Know Law: Benzophenone, CAS # 119-61-9
International Regulations:
CDSL: Canadian Inventory Ethy Methacrylate, CAS # 97-63-2 is on the DSL list. WHMIS= B2, D2B.
Tetraethylene glycol dimethacrylate, CAS# 109-17-1 is not on the DSL List. WHMIS=n/da.
Benzophenone CAS # 119-61-9 is on the DSL list. WHMIS= n/da
D&C Violet #2, CAS # 81-48-1 is not on the DSL List. WHMIS=n/na.
EINECS: European Inventory: Permatop:
Hazard Symbol: Xi: Irritant, F: Flammable
Risk Phrases: R22: Harmful if swallowed, R36/37/38; Irritating to eyes, respiratory system and
skin, R43: may cause sensitization by skin contact.
Safety Phrases: S18: Handle and open container with care, S24/25: Avoid contact with skin and
eyes, S36/37: Wear suitable protective clothing and gloves, S38: In case of insufficient
ventilation, wear suitable respiratory equipment. S46: If swallowed seek medical advice
immediately and show this container or label
Section XVI: Other Information
Hazard Rating System NFPA: Health 2/ Flammability 2/ Reactivity 1
HMIS: Health 2/ Flammability 2/ Reactivity 1
Revised: July 3rd, 2009
Supersedes Date: 02/01/07
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OSHA PEL for misance dust: 15 mg/m?(total dust)
5 mg/m?(respirable dust)
ACGIH PEL for misance dust: 10 mg/m?br>
Product Number: 4020069
Revised Sections since Last Version: Change sections, I, II, VII, XV, XVI
The information presented herein was obtained from sources considered to be liable. However, this information is provided without any warranty, expressed
or implied, regarding its correctness or suitability for consumers intended to use and/or application. For this and other reasons, we assume no responsibility
and expressly disclaim liability for loss, damage or expense arising out of any way connected with handling, storage, use or disposal of the product. This
MSDS was prepared expressly for this product. Use the materials only directed. If the product is used as a component of other product, the information
contained within the MSDS may not be applicable. If one could have any concerns with or problems understanding this MSDS form, please direct all
questions to INFOTRAC, Chemical Emergency Resources System at (800) 535-5053.
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