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TOKYO OHKA KOGYO CO., LTD. Page 1 of 1
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MSDS: TARF-P6071F PM (B)
MATERIAL SAFETY DATA SHEET
TARF-P6071F PM
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TARF-P6071F PM
CREATION DATE: May 29, 2003
REVISION DATE: April 1, 2005
MSDS PREPARED BY: Manufacturing Technology Division, Safety Control Section, TOK
JAPAN
SUPPLIER: TOKYO OHKA KOGYO CO., LTD.
SECTION: Manufacturing Technology Division, Safety Control Section
ADDRESS: 150 Nakamaruko, Nakahara-ku, Kawasaki City, Kanagawa Prefecture 211-0012,
JAPAN
TELEPHONE NUMBER: +81-44-435-3000
FAX NUMBER: +81-44-435-3020
EMERGENCY RESPONSE: +81-44-435-3001
+81-44-435-3002
USA
SUPPLIER: OHKA AMERICA, INC.
ADDRESS: 190 Topaz Street, Milpitas, California 95035, U.S.A.
TELEPHONE NUMBER: +1-408-956-9901
FAX NUMBER: +1-408-956-9995
EMERGENCY RESPONSE: +1-800-424-9300 (CHEMTREC for U.S.A.)
+1-703-527-3887 (CHEMTREC for international)
2. COMPOSITION / INFORMATION ON INGREDIENTS
SIMPLE/MIXTURE: Mixture
CHEMICAL NAME (GENERIC NAME): None
SYNONYM (S): None
INGREDIENT AND COMPOSITION:
INGREDIENTS wt% CHEMICAL FORMULA CAS NO.
Propylene glycol monomethyl
99~75 CH3CH(OCOCH3)CH2OCH3 108-65-6
ether acetate
Gamma-Butyrolactone <5 C4H6O2 96-48-0
Acrylic type resin 20~1 Trade Secret Trade Secret
Photoacid generator <1 Trade Secret Trade Secret
OSHA REGULATORY STATUS:
This material is classified as hazardous under OSHA regulations.
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MSDS: TARF-P6071F PM (B)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Light yellow, flammable liquid with a characteristic odor.
Irritating to eyes.
POTENTIAL HEALTH EFFECTS:
SKIN CONTACT:
Contact causes skin irritation. Prolonged skin contact may cause cracking or other damages on
skin (such as dermatitis).
EYE CONTACT:
Contact causes eye irritation.
INHALATION:
Causes irritation of the nose or the respiratory tract, and may cause headache, nausea, vomit,
dizziness, or unconsciousness. It may also decrease the central nervous system function.
INGESTION:
May nauseate and causes pain in esophagus and stomach if swallowed.
4. FIRST AID MEASURES
SKIN CONTACT:
Wash the affected part with plenty of running water and mild soap.
If irritation continues, immediately take the patient to a physician for examination and treatment.
EYE CONTACT:
Immediately rinse the eyes with running water to wash off the chemical completely.
Immediately take the patient to a physician for examination and treatment.
INHALATION:
Move the patient at once to fresh air.
Immediately take the patient to a physician for examination and treatment.
INGESTION:
Rinse the mouth with water.
Immediately take the patient to a physician for examination and treatment.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
MATERIAL FLASH POINT IGNITON POINT EXPLOSION LIMIT
Product 48 oC Not available Not available
Propylene glycol monomethyl
47 oC 344 oC 1.5~7.0 vol%
ether acetate
Gamma-Butyrolactone 98 oC 455 oC 2.2~15.0 vol%
EXTINGUISHING MEDIA:
Dry sand, foam, carbon dioxide, or dry chemical powder extinguisher.
FIRE FIGHTING INSTRUCTIONS:
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Shut off fuel as much as possible.
Dry chemical or carbon dioxide should be used for small fires.
Evacuate unnecessary personnel to safe area.
Fire fighters should wear proper protective clothing.
Foam should be effective for large fires.
When sprayed, water should be effective for cooling and protection of the fire fighters. However,
use of water may expand the fire.
6. ACCIDENTAL RELEASE MEASURES
Evacuate the leeward personnel.
Ventilate the area.
Quickly shut off all ignition sources.
Equip extinguishers in case of ignition.
Wear proper protective clothings.
When the leak is small, wipe it with cloths. Leave the cloth in the draft, and burn it off after solvent
has evaporated.
When the leak is large, try to stop the flow with cloths, and collect the spilt solution in an empty
container as much as possible.
Prevent spilt solution from entering sewers, watercourses, rivers, or fields.
7. HANDLING AND STORAGE
HANDLING:
Be careful in handling the container, and protect it from damages.
Wear proper protective clothings.
Use only in the well-ventilated area.
Seal the container after handling.
Avoid contact with oxidizing agents or reductants.
Shut off all sources of ignition.
The electric facility should be explosion proof.
Ground.
When moving the solution through pipings, ground the metallic part of the apparatuses, pipings
and containers to prevent generation of electrostatic charges.
Pay attention to ventilation. This vapor is heavier than air, and easily stays at low position.
Do not expose to UV light. Use under tungsten or yellow light.
Solution should not remain in pipings when it is not used.
Water facility should be installed at every place where the solution is used. It should facilitate
measures in case of adhesion or contact with eyes.
Do not bring contaminated protective tools, such as gloves, to the lounge.
Be careful of personal health after handling.
STORAGE:
Keep the container sealed, and store in a cool and dark place. (See the original label on the
container for our storage recommendation.)
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MSDS: TARF-P6071F PM (B)
Keep away all sources of ignition.
Do not heat.
Do not let it evaporate without a reason.
Store in well-ventilated area.
OTHERS:
Follow all national and local regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
When handling, try to use closed apparatuses, equipment or partial ventilator.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTOR: Chemical cartridge respirator with cartridge to protect against the
organic vapor.
Airline respirator.
EYE PROTECTOR: Chemical goggles.
HAND, SKIN AND BODY PROTECTOR: Gloves and clothing to cover the whole body.
EXPOSURE GUIDELINES:
INGREDIENTS ACGIH TLV OSHA PEL
Propylene glycol monomethyl
None established None established
ether acetate
Gamma-Butyrolactone None established None established
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Light yellow liquid
ODOR: Characteristic odor
SPECIFIC GRAVITY: 0.98~1.04 (d25@4)
BOILING POINT: Not available
SOLIDIFYING POINT: <-10 oC
RELATIVE VAPOR DENSITY: Not available
SOLUBILITY IN WATER: Insoluble
VAPOR PRESSURE: Not available
pH: Not available
10. STABILITY AND REACTIVITY
STABILITY: Reactive to UV light. Use under tungsten or yellow light.
CONDITION TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
MATERIALS TO AVOID: Oxidizing agents and reductants.
HAZARDOUS DECOPOSITION PRODUCTS: Emit carbon monoxide when burned with
insufficient oxygen.
HAZARDOUS POLYMERIZATION: Will not polymerize.
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11. TOXICOLOGICAL INFORMATION (Only data for each component is available.)
Propylene glycol monomethyl ether acetate
ACUTE TOXICITY:
Oral LD50 (rat): 8532 mg/kg
Inhalation LC50 (rat): >4350 ppm
Intraperitoneal LD50 (mouse): 750 mg/kg
Skin LD50 (rabbit): >5000 mg/kg
SUBCHRONIC TOXICITY AND CHRONIC TOXICITY:
Inhalation of 300 ppm/6 hours/day caused no effects on rats. Exposure to 1000 ppm effected
kidney, and male rat exposed to 3000 ppm showed increase of the liver weight and effected
kidney.
Inhalation of concentrated mist or vapor caused headache, vomiting, and coma.
MUTAGENIC EFFECT:
Chromosome aberration test (mammalia) is negative.
CARCINOGENIC EFFECT:
No carcinogenic effects were noted in OSHA, EPA, EU, NTP, IARC, and ACGIH.
TERATOGENIC EFFECT:
Inhalation of 500 or 1500 ppm on rats on days 6-15 of gestation caused no effects.
Exposure to 3000 ppm showed fetotoxicity.
Inhalation of 110 ppm on rats on days 6-15 of gestation caused no effects. Exposure to 560 ppm
showed maternal toxicity, and to 2800 ppm showed maternal toxicity, increase of slight spinal
malformation, and fetotoxicity.
Gamma-Butyrolactone
ACUTE TOXICITY:
Oral LD50 (rat): 1540 mg/kg
Oral LD50 (mouse): 1720 mg/kg
Intraperitoneal LD50 (rat): 1000 mg/kg
Intraperitoneal LD50 (mouse): 1100 mg/kg
Skin LD50 (guinea pig): >5000 mg/kg
Intravenous LDLo (rabbit): 500 mg/kg
SUBCHRONIC TOXICITY AND CHRONIC TOXICITYY:
No relevant information found.
MUTAGENIC EFFECT:
Bacillus subtilis H17, M45 with metabolic activation positive.
No chromosome damage in rat liver RL1 cell line.
CARCINOGENIC EFFECT:
IARC - Group 3; Unclassifiable as to carcinogenicity in humans.
No carcinogenic effects were noted in OSHA, EPA, EU, NTP, and ACGIH.
TERATOGENIC EFFECT:
Gavage Sprague-Dawley rats (days 6-15 gestation) 0, 10, 50, 125, 250 or 500 mg/kg. Necropsy
showed lung oedema, hyperaemia and emphysema. Foetal weights significantly increased in high
dosage groups.
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12. ECOLOGICAL INFORMATION (Only data for each component is available.)
Propylene glycol monomethyl ether acetate
BIODEGRADABILITY: Biodegradable.
FISH TOXICITY:
Fatal to brown trout after 21 hours and to yellow perch after 24 hours at 5 ppm. Not toxic to
bluegill sunfish or goldfish after 24 hours at 5 ppm. Test condition; pH 7, dissolved oxygen content
7.5 ppm, total hardness (soap method) 300 ppm, methyl orange alkalinity 310 ppm, free carbon
dioxide 5 ppm and temperature 12.8 oC.
OTHER INFORMATION ON ECOTOXICITY
Octanol/Water Partition Coefficient: No relevant information found.
BOD: No relevant information found.
COD: No relevant information found.
Gamma-Butyrolactone
BIODEGRADABILITY:
Biodegradable.
FISH TOXICITY:
Listed as negative in tests on trout, bluegill sunfish and goldfish. However the authors state that
the high mineral content of the water used in the studies adds an additional source of error.
Therefore the compound listed as negative might be toxic in softer water supplies.
OTHER INFORMATION ON ECOTOXICITY
Octanol/Water Partition Coefficient: 0.64
BOD: No relevant information found.
COD: No relevant information found.
13. DISPOSAL CONSIDERATIONS
RCRA Hazardous waste ID: #D001
All excess material must be collected and transferred to a professional waste disposal company
for incineration.
Carefully review information in - 7.HANDLING & STORAGE.
Comply with all national and local regulations.
14. TRANSPORT INFORMATION
U.S. Department of Transportation (DOT):
PROPER SHIPPING NAME: Resin solution
HAZARD CLASS: 3 (Flammable Liquids)
IDENTIFICATION NUMBER: UN1866
PACKING GROUP: III
Keep away from incompatibilities and all sources of ignition.
Follow all national and local regulations.
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15. REGULATORY INFORMATION
U.S. REGULATION:
TSCA (Toxic Substances Control Act):
One or more components under Low Volume Exemption (LVE), all others TSCA registered.
CERCLA (Comprehensive Emergency Response, Compensation, and Liability Act):
HAZARDOUS SUBSTANCES: Not regulated
SARA TITLE III (Superfund Amendments and Reauthorization Act):
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: Not regulated
SECTION 311/312 HAZARD CATEGORIES:
Acute: No
Chronic: No
Fire: Yes
Reactive: No
Sudden release: No
SECTION 313 TOXIC CHEMICALS: Not regulated
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: Not regulated
16. OTHER INFORMATION
NFPA RATINGS:
HEALTH=1, FIRE=2, REACTIVITY=1 (SCALE 0-4)
MSDS STATUS:
Revised all Sections.
REFERENCE:
1. HSDB
2. RTECS
3. The Dictionary of Substance and Their Effects (The Royal Society of Chemistry)
4. Material Safety Data Sheet (of the raw material manufacturer)
The information contained herein is based on current knowledge and experience; no responsibility
is accepted that the information is sufficient or correct in all cases. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper
use and disposal of these materials and the safety and health of employees and customers and
the protection of the environment.
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