Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 1/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name FANDANGO
Product code (UVP) 05988683
Usage fungicide
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC)
Fluoxastrobin 100g/l, Prothioconazole 100g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Fluoxastrobin 361377-29-9 N R50/53 8.80
Prothioconazole 178928-70-6 N R51/53 8.80
gamma-Butyrolactone 96-48-0 Xn R22, R36 36.30
202-509-5
2-Ethylhexanol propylene 64366-70-7 Xn R20, R52/53 15.00
ethyleneglycol ether
Alkylarylpolyglycol ether 104376-75-2 R52/53 5.00
Citric acid 77-92-9 Xi R36 1.00
201-069-1
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways).
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 2/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center
immediately.
Skin contact
Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400,
subsequently rinse with water.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical
attention if irritation develops and persists.
Ingestion
Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth.
Notes to Physician
Treatment
Treat symptomatically.
Gastric lavage is not normally required. If a significant amount (more than a mouthful) has been
ingested, administer activated charcoal and sodium sulphate.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray
carbon dioxide (CO2)
foam
sand
Specific hazards during fire fighting
nitrogen oxides (NOx)
sulphur dioxide (SO2)
carbon monoxide (CO)
hydrogen chloride (HCl)
hydrogen cyanide (hydrocyanic acid)
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid contact with spilled product or contaminated surfaces.
Wear personal protective equipment. Unprotected persons must be kept away.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 3/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Storage
Requirements for storage areas and containers
Keep container tightly closed in a dry and well-ventilated place.
Store in a place accessible by authorized persons only.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage temperature -10 - 40 癈
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Personal protective equipment
Respiratory Protection Wear respirator conforming to EN140 type A filter.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 4/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands before breaks and at the end of workday.
Remove soiled and/or soaked clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form clear to slightly turbid, liquid
Colour yellow to brown
Odour aromatic
Safety data
pH 4 - 5 at 10 g/l (20 癈)
emulsion in water
Flash Point 105 癈
Ignition temperature 415 癈
Density 1.14 g/cm?at 20 癈
Viscosity, dynamic 91.0 mPa.s at 20 癈
Surface tension 34.1 mN/m at 20 癈
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid None.
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 5/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 2,500 mg/kg
Acute Inhalation Toxicity LC50 (rat) >= 5.077 mg/l
Exposure time: 4 h
Acute Dermal Toxicity LD50 (rat) > 4,000 mg/kg
Skin Irritation Non-irritant. (rabbit)
Eye Irritation Non-irritant. (rabbit)
Sensitization Non-sensitizing. (guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 3.29 mg/l
Exposure time: 96 h
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 6.9 mg/l
Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 13 mg/l
Growth rate Exposure time: 72 h
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3082
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 6/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION)
IMDG
UN-No 3082
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION )
IATA
UN-No 3082
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION )
UK 'Carriage' Regulations
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Emergency action code 3Z
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(FLUOXASTROBIN, PROTHIOCONAZOLE SOLUTION)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Labelling according to EC Directives
Hazardous components which must be listed on the label:
?Prothioconazole
?Fluoxastrobin
?gamma-Butyrolactone
?2-Ethylhexanol propylene ethyleneglycol ether
Symbol(s)
N Dangerous for the environment
R-phrase(s)
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
FANDANGO 7/7
Version 1 / GB Revision Date: 14.06.2006
102000008127 Print Date: 14.07.2008
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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