3 Hazards identification
?Hazard description: Not applicable.
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Flammable.
?Classification system:
The classification was made according to the latest editions of international substances lists, and
expanded upon from company and literature data.
(Contd. on page 2)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 08/14/2008
Trade name: ADHESION PASTE RCA
(Contd. of page 1)
?NFPA ratings (scale 0 - 4)
Health = 0
2 Fire = 2
0 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 0 Health = 0
Fire = 2
FIRE 2
Reactivity = 0
REACTIVITY 0
4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
(Contd. on page 3)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 08/14/2008
Trade name: ADHESION PASTE RCA
(Contd. of page 2)
?Components with limit values that require monitoring at the workplace:
1330-20-7 xylene (2.5-10%)
PEL 435 mg/m? 100 ppm
REL Short-term value: 655 mg/m? 150 ppm
Long-term value: 435 mg/m? 100 ppm
TLV Short-term value: 651 mg/m? 150 ppm
Long-term value: 434 mg/m? 100 ppm
BEI
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Fluid
Form:
Transparent
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 150癈 (> 302癋)
?Flash point: > 55癈 (> 131癋) (Abel Pensky)
(Contd. on page 4)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 08/14/2008
Trade name: ADHESION PASTE RCA
(Contd. of page 3)
?Ignition temperature: 410癈 (770癋)
?Auto igniting: Product is not selfigniting.
?Danger of explosion: Product does not present an explosion hazard.
?Explosion limits:
0.8 Vol %
Lower:
12.7 Vol %
Upper:
?Vapor pressure at 20癈 (68癋): 3 hPa (2 mm Hg)
?Density at 20癈 (68癋): 1.3 g/cm?br>
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
?Viscosity:
9000 mPas
Dynamic at 20癈 (68癋):
5.0 %
VOC content:
178.6 g/l / 1.49 lb/gl
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
1330-20-7 xylene
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes:
Harmful to aquatic organisms
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
USA
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 08/14/2008
Trade name: ADHESION PASTE RCA
(Contd. of page 4)
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
?Hazard class: 3
?Identification number: UN1210
?Packing group: III
?Proper shipping name (technical name): PRINTING INK
?Label 3
?Land transport ADR/RID (cross-border):
?ADR/RID class: -
?Maritime transport IMDG:
?IMDG Class: -
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
1330-20-7 xylene
?TSCA (Toxic Substances Control Act):
1330-20-7 xylene
96-48-0 gamma-butyrolactone
64742-95-6 Solvent naphtha (petroleum), light arom.
7397-62-8 butyl glycollate
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 08/14/2008 Reviewed on 08/14/2008
Trade name: ADHESION PASTE RCA
(Contd. of page 5)
?Proposition 65
?Chemicals known to cause cancer:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
?Cancerogenity categories
?EPA (Environmental Protection Agency)
1330-20-7 xylene D
?IARC (International Agency for Research on Cancer)
1330-20-7 xylene 3
96-48-0 gamma-butyrolactone 3
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
1330-20-7 xylene A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Risk phrases:
Flammable.
?Safety phrases:
Avoid contact with skin and eyes.
In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water.
This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
?Contact:
Mr. Michael Simon
simon@grulms.de
USA