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MSDS Material Safety Data Sheet
CAS

112-07-2 96-48-0 1333-86-4

File Name: 112-07-2_96-48-0_1333-86.asp

                                                     MATERIAL SAFETY DATA SHEET



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1. Chemical Product and Company Identification
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CB271A
Material name
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Inkjet printing
Use of the preparation
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01
Version #
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08-Feb-2008
Revision date
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Mixture
CAS #
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Hewlett-Packard Company
Manufacturer information
1000 NE Circle Boulevard
Corvallis, OR 97330-4239 US
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Hewlett-Packard health effects line
1-800-457-4209
(Toll-free within the US)
1-503-494-7199
(Direct)
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General information telephone number
1-800-474-6836
HP Customer Care Line
1-800-474-6836
(Toll-free)
1-208-323-2551
(Direct)
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Feb 08, 2008
Date prepared
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246669
MSDS number
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2. Hazards Identification
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Any potential hazards are presumed to be due to exposure to the components.
Acute health effects
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Skin contact
Ethylene Glycol, Monobutyl Ether Acetate
Contact with skin may result in irritation. Harmful if absorbed through the skin.
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Eye contact
4-butyrolactone
Irritating to eyes.
Ethylene Glycol, Monobutyl Ether Acetate
Contact with eyes may result in irritation.
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Inhalation
4-butyrolactone
Inhalation may result in respiratory irritation.
Ethylene Glycol, Monobutyl Ether Acetate
Inhalation may result in respiratory irritation.
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Ingestion
4-butyrolactone
Harmful if swallowed. May depress the central nervous system.
Ethylene Glycol, Monobutyl Ether Acetate
Swallowing large amounts may cause digestive discomfort. Harmful if swallowed.
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Potential health effects
Potential routes of exposure under normal use conditions are skin, eye contact and inhalation.
Routes of exposure

Complete toxicity data are not available for this specific formulation
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None known.
Chronic health effects

Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 1/ 6
MATERIAL SAFETY DATA SHEET

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Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly
Carcinogenicity
carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not
present this carcinogenic risk.
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3. Composition / Information on Ingredients
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Component/substance CAS number % by weight

Ethylene Glycol, Monobutyl Ether Acetate 112-07-2 75 - 90
4-butyrolactone 96-48-0 5 - 10
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Carbon black 1333-86-4 < 7.5
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This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard
Composition comments
Communication Standard).

Carbon black is present only in a bound form in this preparation.
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4. First Aid Measures
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First aid procedures
Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. If
Eye contact
irritation persists get medical attention.
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Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation
Skin contact
develops or persists.
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Remove to fresh air. If symptoms persist, get medical attention.
Inhalation
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If material is ingested, immediately contact a physician or poison control center.
Ingestion
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5. Fire Fighting Measures
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167 癋 (75 癈); Pensky-Martens Closed Cup
Flash point and method
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Refer to section 10.
Hazardous combustion
products
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Combustible liquid. Many liquids are lighter than water. Vapors may travel to a source of
Flammable properties
ignition and flash back.
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Extinguishing media
Dry chemical, CO2, water spray or regular foam.
Suitable extinguishing
media
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high volume water jet
Unsuitable extinguishing
media
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Combustible liquid. Many liquids are lighter than water. Vapors may travel to a source of
Unusual fire and explosion
ignition and flash back.
hazard
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6. Accidental Release Measures
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Remove all sources of ignition. Wear appropriate personal protective equipment.
Personal precautions
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Do not let product enter drains. Do not flush into surface water or sanitary sewer system.
Environmental precautions
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Use spark-proof tools and explosion-proof equipment. Soak up with inert absorbent material.
Other information
Use personal protective equipment to minimize exposure to skin and eye. Dispose of in
compliance with federal, state, and local regulations.
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7. Handling and Storage
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Use spark-proof tools and explosion-proof equipment. Keep this product from heat, sparks, or
Handling
open flame. Avoid contact with skin, eyes and clothing. Use with adequate ventilation. Keep
away from sources of ignition - No smoking.


Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 2/ 6
MATERIAL SAFETY DATA SHEET

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Keep away from heat, sparks and flame. Keep away from oxidizers. Store at ambient
Storage
temperature and atmospheric pressure. Keep away from excessive heat or cold.
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8. Exposure Controls/Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Ethylene Glycol, Monobutyl 112-07-2 20 ppm Not established Not established
Ether Acetate
Carbon black 1333-86-4 3.5 mg/m3 Not established Not established
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OSHA
Components CAS # TWA STEL Ceiling
Carbon black 1333-86-4 3.5 mg/m3 Not established Not established
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Exposure limits have not been established for this product.
Exposure guidelines
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
Ethylene Glycol, Monobutyl 112-07-2 20 ppm TWA
Ether Acetate
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
Carbon black 1333-86-4 3.5 mg/m3 TWA
U.S. - OSHA - Final PELs - Time Weighted Averages (TWAs)
Carbon black 1333-86-4 3.5 mg/m3 TWA
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Personal protective equipment
Use personal protective equipment to minimize exposure to skin and eye.
General
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Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin,
General hygeine
eyes and clothing.
considerations
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9. Physical & Chemical Properties
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Black
Color
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Not available
Odor threshold
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Liquid.
Physical state
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Not determined
pH
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Not available
Melting point
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Not available
Freezing point
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375.8 癋 (191 癈)
Boiling point
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167 癋 (75 癈); Pensky-Martens Closed Cup
Flash point
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Not determined
Evaporation rate
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Not available.
Flammability
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Not available
Flammability limits in air,
upper, % by volume
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Not available
Flammability limits in air,
lower, % by volume
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0.3
Vapor pressure
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Not available
Vapor density


Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 3/ 6
MATERIAL SAFETY DATA SHEET

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1
Specific gravity
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Not available
Relative density
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1.1 % w/w
Solubility in water
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Not available
Partition coefficient
(n-octanol/water)
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Not available
Auto-ignition temperature
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Not available
Decomposition temperature
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> 90 % w/w
VOC
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10. Chemical Stability & Reactivity Information
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Stable under normal storage conditions.
Chemical stability
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Strong oxidizing agents. This product may react with strong acids. This product may react with
Incompatible materials
strong alkalies.
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Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide,
Hazardous decomposition
carbon dioxide and/or low molecular weight hydrocarbons.
products
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Will not occur.
Possibility of hazardous
reactions
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11. Toxicological Information
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Carcinogenicity
U.S. - OSHA - Hazard Communication Carcinogens
Carbon black 1333-86-4 Present
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Symptoms and target organs
NIOSH - Pocket Guide - Target Organs
Carbon black 1333-86-4 respiratory system, eyes (lymphatic cancer in presence of PAHs)
NIOSH - Pocket Guide - Target Organs
Ethylene Glycol, Monobutyl 112-07-2 respiratory system, eyes, skin, CNS, hematopoietic system, blood,
Ether Acetate kidneys, liver, lymphoid system
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12. Ecological Information
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This product has not been tested for ecological effects.
Aquatic toxicity
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Not available
Persistence and degradability
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13. Disposal Considerations
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Dispose of in compliance with federal, state, and local regulations. Do not allow this material to
Disposal instructions
drain into sewers/water supplies.
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14. Transportation Information
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Department of Transportation (DOT) Requirements
Not regulated as dangerous goods.
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IATA
Not regulated as dangerous goods.




Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 4/ 6
MATERIAL SAFETY DATA SHEET

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15. Regulatory Information
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All ingredients are listed or exempt
US federal regulations
US TSCA 12(b): Does not contain listed chemicals.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Ethylene Glycol, Monobutyl 112-07-2 (Includes mono- and di- ethers of ethylene glycol; diethylene glycol and
Ether Acetate triethylene glycol R-(OCH2CH2)n-OR'' where n = 1 2 or 3; R = alkyl or
aryl groups; R'' = R h or groups which when removed yield glycol ethers
with the structure R-(OCH2CH2)n-OH. Polymers are excluded from
glycol category); Statutory RQ = 1 pound (.454 kg); no final RQ is being
assigned to the generic or broad
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Ethylene Glycol, Monobutyl 112-07-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where
Ether Acetate n = 1,2, or 3, R=alkyl C7 or less, or R = phenyl or alkyl substituted
phenyl, R' = H or alkyl C7 or less, or OR' consisting of carboxylic acid
ester, sulfate, phosphate, nitrate, or sulfonate, Chemical Category
N230)
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Hazard categories
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Yes
Section 311 hazardous
chemical
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State regulations
U.S. - California - Proposition 65 - Carcinogens List
Carbon black 1333-86-4 carcinogen, initial date 2/21/03 (airborne, unbound particles of
respirable size)
U.S. - Pennsylvania - RTK (Right to Know) List
Ethylene Glycol, Monobutyl 112-07-2 Environmental hazard
Ether Acetate
U.S. - Pennsylvania - RTK (Right to Know) List
Carbon black 1333-86-4 Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Carbon black 1333-86-4 sn 0342
U.S. - New Jersey - Right to Know Hazardous Substance List
Ethylene Glycol, Monobutyl 112-07-2 sn 2265
Ether Acetate
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16. Other Information
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Health: 1
HMIS?ratings
Flammability: 2
Physical hazard: 0
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Health: 1
NFPA ratings
Flammability: 2
Instability: 0
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Feb 8 2008 1:58PM
Issue date

Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 5/ 6
MATERIAL SAFETY DATA SHEET

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1
Revision
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Nov 7 2007 11:09AM
Replaces sheet dated
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This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard
Disclaimer
Company. Data is the most current known to Hewlett-Packard Company at the time of
preparation of this document and is believed to be accurate. It should not be construed as
guaranteeing specific properties of the products as described or suitability for a particular
application. This document was prepared to the requirements of the jurisdiction specified in
Section 1 above and may not meet regulatory requirements in other countries.
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Explanation of abbreviations
American Conference of Governmental Industrial Hygienists
ACGIH
Chemical Abstracts Service
CAS
Comprehensive Environmental Response Compensation and Liability Act
CERCLA
Code of Federal Regulations
CFR
Cleveland Open Cup
COC
Department of Transportation
DOT
Emergency Planning and Community Right-to-Know Act (aka SARA)
EPCRA
International Agency for Research on Cancer
IARC
National Institute for Occupational Safety and Health
NIOSH
National Toxicology Program
NTP
Occupational Safety and Health Administration
OSHA
Permissible Exposure Limit
PEL
Resource Conservation and Recovery Act
RCRA
Recommended
REC
Recommended Exposure Limit
REL
Superfund Amendments and Reauthorization Act of 1986
SARA
Short-Term Exposure Limit
STEL
Toxicity Characteristics Leaching Procedure
TCLP
Threshold Limit Value
TLV
Toxic Substances Control Act
TSCA
Volatile Organic Compounds
VOC




Material name CB271A MSDS US
Creation date Sep 11, 2007 Version number 1 6/ 6

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