WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 1 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
DR
1. Identification of substance:
Product details:
?Trade name: PermaGrip Adhesive, Part A
?Article number: 83674, AA0484
?Application of the substance / the preparation
Adhesives
Acrylic resin
Manufacturer/Supplier:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603
Tel: (903) 643-8080
Fax: (903) 643-8181
Emergency Contact: Chemtel International Call Collect (813) 248-0585
Other Calls: Chemtel (877) 486-1122
2. Composition/Data on components:
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 80-62-6 methyl methacrylate 40-70%
EINECS: 201-297-1 Xi, F; R 11-37/38-43
CAS: 868-77-9 2-hydroxyethyl methacrylate 5-20%
EINECS: 212-782-2 Xi; R 36/38-43
CAS: 79-41-4 methacrylic acid 1.0-5.0%
EINECS: 201-204-4 C; R 21/22-35
CAS: 128-37-0 2,6-di-tert-butyl-p-cresol 1.0-5.0%
EINECS: 204-881-4 Xi; R 36/38
?Additional information For the wording of the listed risk phrases refer to section 16.
3. Hazards identification
Hazard designation:
Xi Irritant
F Highly flammable
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitisation by skin contact.
Contains epoxy constituents. See information supplied by the manufacturer.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by supplier companies.
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 2 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
4. First aid measures
?General information
Take affected persons out of danger area and instruct to lie down.
Personal protection for the First Aider.
DR
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
?After swallowing
A person vomiting while lying on their back should be turned onto their side.
Call a doctor immediately.
?Information for doctor
?The following symptoms may occur:
Dermatitis
Allergic reactions see section 3.
5. Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fire with alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
Can form explosive gas-air mixtures.
see section 10
?Protective equipment:
Wear full protective suit.
Wear self-contained breathing apparatus.
6. Accidental release measures
?Person-related safety precautions:
Keep away from ignition sources
Wear protective equipment. Keep unprotected persons away.
Particular danger of slipping on leaked/spilled product.
Keep people at a distance and stay on the windward side.
Ensure adequate ventilation
Use breathing protection against the effects of fumes/dust/aerosol.
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
Inform respective authorities in case product reaches water or sewage system.
?Measures for cleaning/collecting:
Collect mechanically.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
organic solvent
Ensure adequate ventilation.
?Additional information: See Section 7 for information on safe handling
7. Handling and storage
?Handling
?Information for safe handling:
Avoid splashes or spray in enclosed areas.
Extractors are required on all machines used for thermal processing or metal removal processes.
Restrict the quantity stored in the work place.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Wear breathing protection when decanting larger quantities without extractor facilities.
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 3 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Do not spray on flames or red-hot objects.
Use explosion-proof apparatus / fittings and spark-proof tools.
Protect against electrostatic charges.
DR
Fumes can combine with air to form an explosive mixture.
Flammable mixtures may be formed in empty containers.
Substance/product can reduce the ignition temperature of flammable substances.
Danger of explosion if fluid enters the drainage system
?Storage
?Requirements to be met by storerooms and containers: Prevent any penetration into the ground.
?Information about storage in one common storage facility: see section 10
?Further information about storage conditions:
Store in a cool place.
Store under dry conditions.
Protect from heat and direct sunlight.
Protect from the effects of light.
Store only outside or in explosion proof rooms.
Must be stored in a collecting room.
?Maximum storage temperature: 32 癈
8. Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate (40-70%)
OES Short-term value: 416 mg/m? 100 ppm
Long-term value: 208 mg/m? 50 ppm
79-41-4 methacrylic acid (1.0-5.0%)
OES Short-term value: 143 mg/m? 40 ppm
Long-term value: 72 mg/m? 20 ppm
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Wash hands during breaks and at the end of the work.
Apply solvent resistant skin protective compounds before beginning work.
Do not eat, drink or smoke while working.
?Breathing equipment:
Use breathing protection in case of insufficient ventilation (acc. to EN 141, EN 143 ...).
Filter A/P2.
?Protection of hands (EN420,EN388,EN374 etc.): Impervious gloves
?Material of gloves
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection:
Tightly sealed safety glasses.
Face protection
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 4 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?Body protection:
Impervious protective clothing
Solvent resistant protective clothing
Apron
9. Physical and chemical properties:
?General Information
Form: Pasty
Colour: Blue Opaque
Odour: Acrid
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: > 100癈
?Flash point: 14癈 (SetaFlash CC)
?Danger of explosion: Product is not explosive. However, formation of explosive air/steam
mixtures is possible.see section 7. & 10.
?Critical values for explosion:
Lower: 1.7 Vol %
Upper: 12.5 Vol %
?Density at 20癈 1.03 g/cm?br>
?Solubility in / Miscibility with Water: Not miscible or difficult to mix
?Additional information Mix carefully !
When mixing base and activator, carefully observe the mass and
temperature limits given in the Technical Data Sheet or in the
manufacturing instruction in order to avoid formation of considerable
heat and the possibility of a fire with the release of toxic fumes.
10. Stability and reactivity
?Thermal decomposition / conditions to be avoided:
Stable at ambient temperature
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
Exothermic thermal decomposition
?Stable approx. until: > 37 癈
?Dangerous reactions
Develops readily flammable gases / fumes
Used empty containers may contain product gases which form explosive mixtures with air
Reacts with catalysts
Exothermic polymerisation
Photoreactive
Reacts with acids, alkalis and oxidizing agents
Reacts with reducing agents
?Dangerous products of decomposition:
Inflammable gases/vapours
Hydrocarbons
Carbon monoxide and carbon dioxide
Sulphur oxides (SOx)
DR
11. Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 5 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
12. Ecological information:
?General notes: Do not allow product to reach ground water, water bodies or sewage system.
13. Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
?Uncleaned packagings:
?Recommendation:
Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
?Recommended cleaning agent:
Dibasic carboxylic esters (DBE): mixture of dimethyl esters of adipic, glutaric and succinic acids
14. Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: 3 Flammable liquids.
?Kemler Number: 33
?UN-Number: 1133
?Packaging group: II
?Label 3
?Designation of goods: 1133 ADHESIVES (vapor pressure at 50癈 at most 110 kPa)
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 1133
?Label 3
?Packaging group: II
?EMS Number: F-E,S-D
?Marine pollutant: Not a marine pollutant
DR
?Correct technical name: ADHESIVES
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 3
?UN/ID Number: 1133
?Label 3
?Packaging group: II
?Correct technical name: ADHESIVES
WM2000A-A Acrylic Adhesive Material Safety Data Sheet
Part Nos.: WM2000A-A400 thru WM2000A-A3900 According to 91/155 EC
Page 6 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
15. Regulatory information
?Designation according to EC guidelines:
The product has been labelled in accordance with EC Directives / relevant national laws.
?Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
?Hazard-determining components of labelling:
methyl methacrylate
2-hydroxyethyl methacrylate
?Risk phrases:
11 Highly flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitisation by skin contact.
?Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
?Special designation of certain preparations:
Contains epoxy constituents. See information supplied by the manufacturer.
?National regulations
?Technical instructions on air emissions in Germany ("TA Luft"):
?Class Share in %
?II 40-70
?Water hazard class (as established in Germany):
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16. Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
11 Highly flammable.
21/22 Harmful in contact with skin and if swallowed.
35 Causes severe burns.
36/38 Irritating to eyes and skin.
37/38 Irritating to respiratory system and skin.
43 May cause sensitisation by skin contact.
Organization that prepared MSDS:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Person who prepared MSDS:
Name: Elvin C. Loyd Job Title: Vice President
Printing date 01.10.2007/Reviewed on 01.10.2007
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 1 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
1. Identification of substance:
?Product details:
?Trade name: PermaGrip Adhesive, Part B
?Article number: 83046
?Application of the substance / the preparation
Adhesives
Activator
Manufacturer/Supplier:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603
Tel: (903) 643-8080
Fax: (903) 643-8181
Emergency Contact: Chemtel International Call Collect (813) 248-0585
Other Calls: Chemtel (877) 486-1122
2. Composition/Data on components:
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 80-62-6 methyl methacrylate 40-70%
EINECS: 201-297-1 Xi, F; R 11-37/38-43
CAS: 34562-31-7 3,5-Diethyl-1,2-dihydro-1-phenyl-2-propylpyridine (PDHP) 5-20%
EINECS: 252-091-3 Xi; R 36/38
?Additional information For the wording of the listed risk phrases refer to section 16.
* 3. Hazards identification
?Hazard designation:
Xi Irritant
F Highly flammable
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 37/38 Irritating to respiratory system and skin.
R 43 May cause sensitisation by skin contact.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by supplier companies.
4. First aid measures
?General information
Take affected persons out of danger area and instruct to lie down.
Personal protection for the First Aider.
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact
Instantly wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor.
?After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 2 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?After swallowing
A person vomiting while lying on their back should be turned onto their side.
Call a doctor immediately.
?Information for doctor
?The following symptoms may occur:
Dermatitis
Allergic reactions
see section 3.
5. Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fire with alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
Can form explosive gas-air mixtures.
see section 10
?Protective equipment:
Wear full protective suit.
Wear self-contained breathing apparatus.
6. Accidental release measures
?Person-related safety precautions:
Keep away from ignition sources
Wear protective equipment. Keep unprotected persons away.
Particular danger of slipping on leaked/spilled product.
Keep people at a distance and stay on the windward side.
Ensure adequate ventilation
Use breathing protection against the effects of fumes/dust/aerosol.
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
Inform respective authorities in case product reaches water or sewage system.
?Measures for cleaning/collecting:
Collect mechanically.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
organic solvent
Ensure adequate ventilation.
?Additional information: See Section 7 for information on safe handling
7. Handling and storage
?Handling
?Information for safe handling:
Avoid splashes or spray in enclosed areas.
Extractors are required on all machines used for thermal processing or metal removal processes.
Restrict the quantity stored in the work place.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Wear breathing protection when decanting larger quantities without extractor facilities.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Do not spray on flames or red-hot objects.
Use explosion-proof apparatus / fittings and spark-proof tools.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 3 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
Flammable mixtures may be formed in empty containers.
Substance/product can reduce the ignition temperature of flammable substances.
Danger of explosion if fluid enters the drainage system
DR
?Storage
?Requirements to be met by storerooms and containers: Prevent any penetration into the ground.
?Information about storage in one common storage facility: see section 10
?Further information about storage conditions:
Store in a cool place.
Store under dry conditions.
Protect from heat and direct sunlight.
Protect from the effects of light.
Store only outside or in explosion proof rooms.
Must be stored in a collecting room.
?Maximum storage temperature: 32 癈
8. Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate (40-70%)
OES Short-term value: 416 mg/m? 100 ppm
Long-term value: 208 mg/m? 50 ppm
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Wash hands during breaks and at the end of the work.
Apply solvent resistant skin protective compounds before beginning work.
Do not eat, drink or smoke while working.
?Breathing equipment:
Use breathing protection in case of insufficient ventilation (acc. to EN 141, EN 143 ...).
Filter A/P2.
?Protection of hands (EN420,EN388,EN374 etc.): Impervious gloves
?Material of gloves
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection:
Tightly sealed safety glasses.
Face protection
?Body protection:
Impervious protective clothing
Solvent resistant protective clothing
Apron
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 4 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
9. Physical and chemical properties:
?General Information
Form: Pasty
Colour: Yellow Opaque
Odour: Acrid/Fruit-like
?Change in condition
Melting point/Melting range: Not determined
DR
Boiling point/Boiling range: > 100癈
?Flash point: 14癈 (SetaFlash CC)
?Danger of explosion: Product is not explosive.However, formation of explosive air/steam
mixtures is possible.
see section 7. & 10.
?Critical values for explosion:
Lower: 2.1 Vol %
Upper: 12.5 Vol %
?Vapour pressure at 20癈: 38 hPa
?Density at 20癈 0.96 g/cm?br>
?Solubility in / Miscibility with
Water: Not miscible or difficult to mix
?Solvent content:
Organic solvents: Parts A & B combined (EPA Method 24):
30,73 % = 312 g/l
?Additional information Mix carefully !
When mixing base and activator, carefully observe the mass and
temperature limits given in the Technical Data Sheet or in the
manufacturing instruction in order to avoid formation of
considerable heat and the possibility of a fire with the release of
toxic fumes.
10. Stability and reactivity
?Thermal decomposition / conditions to be avoided:
Stable at ambient temperature
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
Exothermic thermal decomposition
To maintain inhibitor activity, oxygen must not be eliminated from the atmosphere above the product.
?Dangerous reactions
Develops readily flammable gases / fumes
Used empty containers may contain product gases which form explosive mixtures with air
Reacts with catalysts
Exothermic polymerisation
Photoreactive
Reacts with acids, alkalis and oxidizing agents
Reacts with reducing agents
Exothermic reaction
?Dangerous products of decomposition:
Inflammable gases/vapours
Hydrocarbons
Carbon monoxide and carbon dioxide
Poisonous gases/vapours
11. Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 5 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
12. Ecological information:
?General notes: Do not allow product to reach ground water, water bodies or sewage system.
13. Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
?Uncleaned packagings:
?Recommendation:
Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
?Recommended cleaning agent:
Dibasic carboxylic esters (DBE): mixture of dimethyl esters of adipic, glutaric and succinic acids
?14. Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: 3 Flammable liquids.
?Kemler Number: 33
?UN-Number: 1133
?Packaging group: II
?Label 3
?Designation of goods: 1133 ADHESIVES (vapor pressure at 50癈 at most 110 kPa)
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 1133
?Label 3
?Packaging group: II
?EMS Number: F-E,S-D
?Marine pollutant: Not a marine pollutant
?Correct technical name: ADHESIVES
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 3
?UN/ID Number: 1133
?Label 3
?Packaging group: II
?Correct technical name: ADHESIVES
WM2000A-B Adhesive Activator EU Material Safety Data Sheet
Part No.: WM2000A-B According to 91/155 EC
(Subcomponents of AKD-400 thru AKC3900)
Page 6 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
DR
* 15. Regulatory information
?Designation according to EC guidelines:
The product has been labelled in accordance with EC Directives / relevant national laws.
?Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
?Hazard-determining components of labelling:
methyl methacrylate
?Risk phrases:
11 Highly flammable.
37/38 Irritating to respiratory system and skin.
43 May cause sensitisation by skin contact.
?Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
?National regulations
?Technical instructions on air emissions in Germany ("TA Luft"):
?Class Share in %
?II 40-70
?Water hazard class (as established in Germany):
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16. Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
11 Highly flammable.
36/38 Irritating to eyes and skin.
37/38 Irritating to respiratory system and skin.
43 May cause sensitisation by skin contact.
Organization that prepared MSDS:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Person who prepared MSDS:
Name: Elvin C. Loyd Job Title: Vice President
* Data compared to the previous version altered.
Printing date 01.10.2007/Reviewed on 01.10.2007
WM2000F-A Epoxy Adhesive EU Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500) According to 91/155 EC
Page 1 of 5 Printing date 01.10.2007 Reviewed on 01.10.2007
DR
1. Identification of substance:
Product details:
?Trade name: Perma-Putty Part A
?Article number: 83206
?Application of the substance / the preparation
Epoxy resin adhesive
Resin
Manufacturer/Supplier:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603
Tel: (903) 643-8080
Fax: (903) 643-8181
Emergency Contact: Chemtel International Call Collect (813) 248-0585
Other Calls: Chemtel (877) 486-1122
2. Composition/Data on components:
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
epoxy resin (M < 700), bisphenol A - epichlorohydrin
Xi, N; R 36/38-43-51/53
40-70%
?Additional information For the wording of the listed risk phrases refer to section 16.
3. Hazards identification
?Hazard designation:
Xi Irritant
N Dangerous for the environment
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitisation by skin contact.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Contains epoxy constituents. See information supplied by the manufacturer.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by supplier companies.
4. First aid measures
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
WM2000F-A Epoxy Adhesive EU Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500) According to 91/155 EC
Page 2 of 5 Printing date 01.10.2007 Reviewed on 01.10.2007
?After swallowing
A person vomiting while lying on their back should be turned onto their side.
Call a doctor immediately.
DR
?Information for doctor
?The following symptoms may occur:
Dermatitis
Allergic reactions
see section 3.
5. Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
see section 10
?Protective equipment: Wear self-contained breathing apparatus.
6. Accidental release measures
?Person-related safety precautions:
Particular danger of slipping on leaked/spilled product.
Wear protective clothing.
Ensure adequate ventilation
Use breathing protection against the effects of fumes/dust/aerosol.
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Collect mechanically.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
organic solvent
Ensure adequate ventilation.
?Additional information: See Section 7 for information on safe handling
7. Handling and storage
?Handling
?Information for safe handling:
Avoid splashes or spray in enclosed areas.
Ensure good ventilation/exhaustion at the workplace.
Extractors are required on all machines used for thermal processing or metal removal processes.
?Information about protection against explosions and fires: Do not spray on flames or red-hot objects.
?Storage
?Requirements to be met by storerooms and containers: Prevent any penetration into the ground.
?Information about storage in one common storage facility: see section 10
?Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
Store under dry conditions.
?Recommended storage temperature: < 25 癈
8. Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
14807-96-6 Talc (20-40%)
OES Long-term value: 1 mg/m?respirable dust
DR
WM2000F-A Epoxy Adhesive EU Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500) According to 91/155 EC
Page 3 of 5 Printing date 01.10.2007 Reviewed on 01.10.2007
13463-67-7 titanium dioxide (1.0-5.0%)
OES Long-term value: 10* 4** mg/m?br>
*total inhalable dust **respirable dust
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Use skin protection cream for preventive skin protection.
Wash hands during breaks and at the end of the work.
Do not eat, drink or smoke while working.
?Breathing equipment:
Use breathing protection in case of insufficient ventilation (acc. to EN 141, EN 143 ...).
Filter A/P2.
?Protection of hands (EN420,EN388,EN374 etc.): Impervious gloves
?Material of gloves
Fluorocarbon rubber (Viton)
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection: Tightly sealed safety glasses.
?Body protection: Impervious protective clothing
9. Physical and chemical properties:
?General Information
Form: Viscous
Colour: White
Odour: Mild
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: > 249癈
?Flash point: 249癈 (PMCC)
?Ignition temperature: > 300癈
?Danger of explosion: Product is not explosive.
see section 7. & 10.
?Density at 20癈 1.57 g/cm3
?Solubility in / Miscibility with
Water: Not miscible or difficult to mix
?Ketones: Readily soluble
?Solvent content:
Organic solvents: 0%
10. Stability and reactivity
?Thermal decomposition / conditions to be avoided:
Stable at ambient temperature
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
DR
WM2000F-A Epoxy Adhesive EU Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500) According to 91/155 EC
Page 4 of 5 Printing date 01.10.2007 Reviewed on 01.10.2007
?Dangerous reactions
Reacts with strong oxidizing agents
Reacts with amines
Exothermic reaction
?Dangerous products of decomposition:
Hydrocarbons
Carbon monoxide and carbon dioxide
11. Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
12. Ecological information:
?Information about elimination (persistence and degradability):
?Other information: The product is slightly biodegradable.
?General notes:
The product contains materials that are harmful to the environment.
Also poisonous for fish and plankton in water bodies.
Do not allow product to reach ground water, water bodies or sewage system.
13. Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
?Uncleaned packagings:
?Recommendation:
Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
?Recommended cleaning agent: 2-Butanone, MEK (Caution: flammable !)
14. Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: -
?Maritime transport IMDG:
?IMDG Class: non regulated
?Marine pollutant: Not a marine pollutant
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: non regulated
?Transport/Additional information: Not dangerous according to the above specifications.
15. Regulatory information
?Designation according to EC guidelines:
The product has been labelled in accordance with EC Directives / relevant national laws.
?Code letter and hazard designation of product:
Xi Irritant
N Dangerous for the environment
DR
?Hazard-determining components of labelling:
epoxy resin (M < 700), bisphenol A - epichlorohydrin
WM2000F-A Epoxy Adhesive EU Material Safety Data Sheet
Part No.: WM2000F-A (Subcomponent of FKC-500) According to 91/155 EC
Page 5 of 5 Printing date 01.10.2007 Reviewed on 01.10.2007
?Risk phrases:
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
28 After contact with skin, wash immediately with plenty of soap and water.
37/39 Wear suitable gloves and eye/face protection.
57 Use appropriate container to avoid environmental contamination.
?Special designation of certain preparations:
Contains epoxy constituents. See information supplied by the manufacturer.
?National regulations
?Technical instructions on air emissions in Germany ("TA Luft"):
?Class Share in % total emissions on volatile organic compounds
?Water hazard class (as established in Germany):
Water hazard class 2 (Self-assessment): hazardous for water.
16. Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Organization that prepared MSDS:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Person who prepared MSDS:
Name: Elvin C. Loyd Job Title: Vice President
Printing date 01.10.2007/Reviewed on 01.10.2007
This page intentionally left blank.
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 1 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
1. Identification of substance:
Product details:
?Trade name: Perma-Putty Part B
?Article number: 36765, AB0002
?Application of the substance / the preparation
Epoxy resin adhesive
Hardening agent/ Curing agent
Manufacturer/Supplier:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603
Tel: (903) 643-8080
Fax: (903) 643-8181
Emergency Contact: Chemtel International Call Collect (813) 248-0585
Other Calls: Chemtel (877) 486-1122
2. Composition/Data on components:
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 111-40-0 diethylenetriamine
EINECS: 203-865-4 C; R 21/22-34-43 5-20%
Bisphenol A
Xi; R 36/37/38-43 1.0-5.0%
CAS: 25085-99-8 Propane, 2,2-bis(P-(2,3-epoxypropoxy)phenyl)-, Polymers
Polymer Xi, N; R 36/38-43-51/53 < 1.0%
?Additional information For the wording of the listed risk phrases refer to section 16.
3. Hazards identification
?Hazard designation:
C Corrosive
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
R 34 Causes burns.
R 43 May cause sensitisation by skin contact.
Contains epoxy constituents. See information supplied by the manufacturer.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by supplier companies.
4. First aid measures
?General information Instantly remove any clothing soiled by the product.
?After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 2 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
Call a doctor immediately.
?After swallowing
A person vomiting while lying on their back should be turned onto their side.
Drink copious amounts of water and provide fresh air. Instantly call for doctor.
?Information for doctor
?The following symptoms may occur:
Skin burns
Dermatitis
Allergic reactions
see section 3.
5. Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
see section 10
?Protective equipment: Wear self-contained breathing apparatus.
6. Accidental release measures
?Person-related safety precautions:
Wear protective clothing.
Particular danger of slipping on leaked/spilled product.
Use breathing protection against the effects of fumes/dust/aerosol.
Ensure adequate ventilation
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Collect mechanically.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
organic solvent
Ensure adequate ventilation.
?Additional information: See Section 7 for information on safe handling
7. Handling and storage
?Handling
?Information for safe handling:
Avoid splashes or spray in enclosed areas.
Ensure good ventilation/exhaustion at the workplace.
Extractors are required on all machines used for thermal processing or metal removal processes.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Do not spray on flames or red-hot objects.
The product forms flammable fumes when heated.
?Storage
?Requirements to be met by storerooms and containers: Prevent any penetration into the ground.
?Information about storage in one common storage facility: see section 10
?Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 3 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
DR
8. Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
14807-96-6 Talc (20-40%)
OES Long-term value: 1 mg/m?br>
respirable dust
111-40-0 diethylenetriamine (5-20%)
OES Long-term value: 4.3 mg/m? 1 ppm
Sk
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Wash hands during breaks and at the end of the work.
Do not eat, drink or smoke while working.
?Breathing equipment:
Use breathing protection in case of insufficient ventilation (acc. to EN 141, EN 143 ...).
Filter A/P2.
?Protection of hands (EN420,EN388,EN374 etc.): Impervious gloves
?Material of gloves
Fluorocarbon rubber (Viton)
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
?Eye protection:
Tightly sealed safety glasses.
Face protection
?Body protection: Alkaline resistant protective clothing
9. Physical and chemical properties:
?General Information
Form: Viscous
Colour: Black
Odour: Ammonia-like
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: > 200癈
?Flash point: 102癈 (Open Cup)
?Ignition temperature: > 300癈
?Danger of explosion: see section 7. & 10.
?Density at 20癈 1.65 g/cm3
?Solubility in / Miscibility with
Water: Partly soluble
?Ketones: Readily soluble
?pH-value: Alkaline
DR
?Solvent content:
Organic solvents: 0%
?Solids content: > 50 %
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 4 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
?Additional information Mix carefully !
When mixing base and activator, carefully observe the mass and
temperature limits given in the Technical Data Sheet or in the manufacturing
instruction in order to avoid formation of considerable heat and the possibility
of a fire with the release of toxic fumes. Strictly observe manufacturing
instructions !
Upper mass limit / Maximum temperature to be observed: approx.
0,9 kg (PART A + PART B) / -
10. Stability and reactivity
?Thermal decomposition / conditions to be avoided:
Stable at ambient temperature
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
?Dangerous reactions
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised
Reacts with water
Reacts with strong oxidizing agents
Reacts with acids
Reacts with various metals
Exothermic reaction
?Dangerous products of decomposition:
Ammonia
Hydrocarbons
Nitrogen oxides (NOx)
Carbon monoxide and carbon dioxide
11. Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
111-40-0 diethylenetriamine
Oral LD50 1080 mg/kg (rat)
Dermal LD50 1000 mg/kg (rbt)
?Primary irritant effect:
?on the skin: Caustic effect on skin and mucous membranes.
?on the eye: Strong caustic effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
12. Ecological information:
?General notes: Do not allow product to reach ground water, water bodies or sewage system.
13. Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
DR
?Uncleaned packagings:
?Recommendation:
Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
?Recommended cleaning agent: 2-Butanone, MEK (Caution: flammable !)
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 5 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
14. Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: 8 Corrosive substances.
?Kemler Number: 80
?UN-Number: 3259
?Packaging group: III
?Label 8
?Designation of goods: 2735 AMINES, SOLID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
?Maritime transport IMDG:
?IMDG Class: 8
?UN Number: 3259
?Label 8
?Packaging group: III
?EMS Number: F-A,S-B
?Marine pollutant: Not a marine pollutant
?Correct technical name: AMINES, SOLID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 8
?UN/ID Number: 3259
?Label 8
?Packaging group: III
?Correct technical name: AMINES, SOLID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
DR
15. Regulatory information
?Designation according to EC guidelines:
The product has been labelled in accordance with EC Directives / relevant national laws.
?Code letter and hazard designation of product:
C Corrosive
?Hazard-determining components of labelling:
diethylenetriamine
Bisphenol A
?Risk phrases:
34 Causes burns.
43 May cause sensitisation by skin contact.
?Safety phrases:
20 When using do not eat or drink.
23 Do not breathe fumes/aerosol.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
WM2000F-B Epoxy Activator EU Material Safety Data Sheet
Part No.: WM2000F-B (Subcomponent of FKC-500) According to 91/155 EC
Page 6 of 6 Printing date 01.10.2007 Reviewed on 01.10.2007
60 This material and its container must be disposed of as hazardous waste.
?Special designation of certain preparations:
Contains epoxy constituents. See information supplied by the manufacturer.
?National regulations
?Technical instructions on air emissions in Germany ("TA Luft"):
?Class Share in % total emissions on volatile organic compounds
?Water hazard class (as established in Germany):
Water hazard class 2 (Self-assessment): hazardous for water.
16. Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
21/22 Harmful in contact with skin and if swallowed.
34 Causes burns.
36/37/38 Irritating to eyes, respiratory system and skin.
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Organization that prepared MSDS:
WrapMaster, Inc.
2701 State Highway 322
Longview, Texas 75603 (903) 643-8080
Person who prepared MSDS:
Name: Elvin C. Loyd Job Title: Vice President
Printing date 01.10.2007/Reviewed on 01.10.2007
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