SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 1/8
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
material No. 1353683
:
DH 100 N
Trade name :
For Spray Application.Meagr
Thinning Oil
Company : Ferro Magmalor GmbH
Furtweg 23
04680 Colditz
Telephone : +49 34381 8370
Telefax : +49 34381 83768
Emergency telephone : +49 (0)69 30 56 418
E-mail address : braeunlingi@ferro.com
Use of the Substance/Preparation : Detergent, thinner or additive in the ceramic industry or printing
trade.
2. HAZARDS IDENTIFICATION
Limited evidence of a carcinogenic effect.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Product contains:
oil/terpene/balsame/wax/resin
organic halogene compound
Information on ingredients/Hazardous components
Concentration 50% - 100%
dichloromethane
CAS-No. 75-09-2 EC-No. 200-838-9
Symbol(s) Xn R-phrase(s) R40
Concentration 1% - 3%
eucalyptus oil
CAS-No. 8000-48-4, 84625-32-1 EC-No. 283-406-2
Symbol(s) Xn R-phrase(s) R10, R36/38, R65
Concentration 0,25% - 0,5%
p-mentha-1,4(8)diene
CAS-No. 586-62-9 EC-No. 209-578-0
Symbol(s) Xn, N R-phrase(s) R10, R65, R51/53
Concentration 0,25% - 0,5%
camphene
CAS-No. 79-92-5 EC-No. 201-234-8
Symbol(s) Xi, N R-phrase(s) R10, R36, R50/53
Concentration 0,25% - 0,5%
pin-2(3)-ene
CAS-No. 80-56-8 EC-No. 201-291-9
Symbol(s) Xn, N R-phrase(s) R10, R36/38, R65, R51/53
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 2/8
Concentration 0,25% - 0,5%
p-mentha-1,3-diene
CAS-No. 99-86-5 EC-No. 202-795-1
Symbol(s) Xn, N R-phrase(s) R10, R22, R51/53, R65
See chapter 16 for text of risk phrases
4. FIRST AID MEASURES
General advice
Bring affected person out of danger area. Place person on side in stable position if unconscious.
Employ mouth-to-mouth resuscitation if breathing ceases.
Remove contaminated or saturated clothing.
Inhalation
Take affected persons out into the fresh air.
Skin contact
Wash off immediately with soap and plenty of water.
Remove contaminated or saturated clothing.
Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at last 10 minutes.
Ingestion
Make affected person vomit but only if he is fully conscious. Have patient rinse out mouth with water.
If symptoms persist, call a physician.
Have patient drink plenty of water in small sips.
Notes to physician
No own experience available.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
The product itself does not burn.
Extinguishing media which shall not be used for safety reasons
none known
Specific hazards during fire fighting
May be released in case of fire: flammable smouldering gases.
In the case of fire, the following hazardous smoke fumes may be produced: chlorine, hydrogen
chloride.
When heated, formation of explosive vapour/air mixtures.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Further information
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure
there are sufficient retaining facilities for water used to extinguish fire. Contaminated fire-
extinguishing water must be disposed of in accordance with the regulations issued by the
appropriate local authorities.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 3/8
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Ensure adequate ventilation.
Wear personal protective equipment; see section 8.
Environmental precautions
Prevent penetration into soil, stretches of water and drainage systems.
Methods for cleaning up
Absorb with liquid-binding material (e.g. inert absorbent kieselguhruniversal binder) pick up.
Additional advice
Dispose of contaminated material as waste in accordance with section 13.
7. HANDLING AND STORAGE
Handling
Safe handling advice
Do not breathe in vapours or aerosols.
Advice on protection against fire and explosion
no data available
Storage
Requirements for storage areas and containers
Fumes may be released in closed storage rooms or during processing. Store in a dry place at room
temperature.
Further information
Product is water-pollutive. Observe the national and local regulations concerning handling and
storage.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Keep away from tobacco products.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
dichloromethane
CAS-No. 75-09-2 EC-No. 200-838-9
Control parameters 75,00 ml/m3 AGW (Germany)
260,00 mg/m3
Engineering measures
If possible, use material transfer/filling, metering and blending plants that are closed.
Eventual aspiration in case of solvent fumes. Technical protection measures have always priority
over personal protection equipment.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 4/8
Occupational exposure controls
Personal protective equipment
Respiratory protection
Ensure suitable suction/aeration at the work place and with operational machinery.
If workplace exposure limit is exceeded apply Respirator with brown AX-type filter.
Hand protection
Wear protective gloves made of the following materials: nitrile rubber.
Eye protection
wear basket-shaped glasses or safety goggles with side-shields.
Skin and body protection
Safety shoes
When handling larger quantities: rubber apron, plastic apron.
Hygiene measures
Wash hands before breaks and immediately after handling the product.
Protective measures
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid
Colour colourless
Odour characteristic
Safety data
physical state liquid
Lower explosion limit 13 %(V)
Upper explosion limit 25 %(V)
Water solubility insoluble
10. STABILITY AND REACTIVITY
Conditions to avoid Avoid temperatures above 120癈.
Materials to avoid Strong oxidizing agents
Hazardous decomposition products Information referring to dichloromethane: If heated, decomposition and
possible development of phosgene, hydrogene chloride gas, carbon
monoxide and chlorine gas.
11. TOXICOLOGICAL INFORMATION
Chronic toxicity / Subacute May cause cancer.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 5/8
toxicity
Skin irritation not known
Eye irritation not known
Sensitisation not known
No results of animal experiments with the product available.
Acute oral toxicity
dichloromethane LD50 rat: 2.136 mg/kg
12. ECOLOGICAL INFORMATION
Persistence and degradability
Biodegradability no data available
Physico-chemical removability no data available
Ecotoxicity effects
Specific information for this product is not available.
Toxicity to fish
dichloromethane LC50 Fish: 237 - 626 mg/l / 48 h
Toxicity to daphnia
dichloromethane EC50 Daphnia: 220 mg/l / 48 h
Further information on ecology
Further Information May cause long-term adverse effects in the aquatic environment.
Harmful to aquatic organisms.
13. DISPOSAL CONSIDERATIONS
Product
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemical or used container.
In agreement with the wast code must be determined regional waste disposal authority or company.
Dispose of as special waste in compliance with local and national regulations.
Uncleaned packaging
If there is product residue in the emptied container, follow directions for handling on the container's
label.
Dispose of as unused product.
14. TRANSPORT INFORMATION
Land transport ADR/RID/GGVSE (Germany)
Class 6.1
Code T1
Packaging group III
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 6/8
orange warning plate 60 / 1593
Description of the goods (Technical name)
1593 DICHLOROMETHANE, SOLUTION
Sea transport IMDG-Code/GGVSee
Class 6.1
UN-Number 1593
Packaging group III
Proper technical name (Proper shipping name)
DICHLOROMETHANE, SOLUTION
Air transport ICAO-TI/IATA-DGR
Class 6.1
UN-Number 1593
Packaging group III
Proper technical name (Proper shipping name)
Dichloromethane, solution
15. REGULATORY INFORMATION
Labelling according to EC Directives
statutory basis/list 1999/45/EC
Hazard-defining component(s)
dichloromethane
Symbol(s) Xn Harmful
R-phrase(s) R40 Limited evidence of a carcinogenic effect.
R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrase(s) S23 Do not breathe vapour.
S24/25 Avoid contact with skin and eyes.
S36/37 Wear suitable protective clothing and gloves.
S60 This material and its container must be disposed of as
hazardous waste.
Exceptional labelling of special Can become flammable in use.
preparations
Major Accident Hazard 96/82/EC Update: 2003
Legislation listing: Directive 96/82/EC does not apply
National legislation (Germany)
Water contaminating class WGK 2 water endangering
(Germany) Update: VWVWS A4
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 7/8
TA Luft List (Germany) Class I II III IV
organic 85,0 % 0,0 % 0,0 %
carcinogenic 0,0 % 0,0 % 0,0 %
inorganic-dust-like 0,0 % 0,0 % 0,0 %
inorganic-gaseous 0,0 % 0,0 % 0,0 % 0,0 %
Other regulations The employment limitations under the regulations to the protection from
hazardous materials of pregnant women and young mothers guideline and
the protection of young persons act are to be observed.
16. OTHER INFORMATION
Risk phrase (R phrase) texts
dichloromethane
R40 Limited evidence of a carcinogenic effect.
eucalyptus oil
R10 Flammable.
R36/38 Irritating to eyes and skin.
R65 Harmful: may cause lung damage if swallowed.
p-mentha-1,4(8)diene
R10 Flammable.
R65 Harmful: may cause lung damage if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
camphene
R10 Flammable.
R36 Irritating to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
pin-2(3)-ene
R10 Flammable.
R36/38 Irritating to eyes and skin.
R65 Harmful: may cause lung damage if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
p-mentha-1,3-diene
R10 Flammable.
R22 Harmful if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
Further information
Data sheet producing department:
Ferro US-PS Telephone: +49 (0)69 27116-605
Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For Spray Application.Meagr DH 100 N
specification 2001687 Revision date 29.04.2008
Version 3.0 Print Date 28.04.2009
material No. 1353683 Page 8/8
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
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