Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Identification of the Substance:
Trade Name: CAMPHENE P&F
Chemical Name: Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-
Use of the Substance:Flavor and fragrance ingredient
Company Identification:
_______________________________________________________________________
European Headquarters
LyondellBasell Flavors & Fragrances, LLC LyondellBasell Flavors & Fragrances, LLC
P.O. Box 389 C/O SCM EUROPE
Jacksonville, FL 32201, USA Place de l'ALBERTINE 2
Telephone: 904-768-5800 B-1000 Brussels - Belgium
Fax:904-768-2200 Telephone: +32.2.289.05.10 Fax:+32.2.289.05.90
_______________________________________________________________________
Emergency Telephone: CHEMTREC: (USA, Canada): 1-800-424-9300 ;(All Others): 703-527-3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Typical
CAS Number EINECS Number Ingredient Weight %
471-84-1 FENCHENE, ALPHA- 2.60
508-32-7 208-083-7 TRICYCLENE 2.80
79-92-5 201-234-8 CAMPHENE 93.30
EU Classifications (refer to Section 16 for descriptions):
Symbol(s) Risk Phrase Code(s) Safety Phrase Code(s)
Xi,N R(10)-36-50/53 S26-61
3. HAZARDS IDENTIFICATION
This substance is classified as dangerous according to EU Directive 1999/45/EC.
Potential Health Effects
Acute Health Effects:
Contact with the undiluted material is irritating to eyes.
Chronic Health Effects:
Not Determined.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 1 of 6
Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
4. FIRST AID MEASURES
Inhalation:
Seek fresh air immediately. If breathing is difficult, seek medical advice.
Eye Contact:
Flush with water for at least 15 minutes. If irritation develops, get
medical attention.
Skin Contact:
Remove contaminated clothing. Wash affected areas with plenty of soap and
water. If irritation develops, seek medical advice.
Ingestion:
Drink lots of water to dilute substance. Get medical attention immediately
or contact a poison control center for advice.
5. FIRE FIGHTING MEASURES
Suitable Fire Extinguishing Media:
Carbon dioxide, dry chemical, foam.
Unsuitable Fire Extinguishing Media:
If water must be used, use as a spray only.
Special Exposure Hazards:
Flammable Solid. Avoid heat, sparks and open flames.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
Special Protective Equipment for Fire Fighters:
Standard turnout gear for combustibe materials.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Standard turnout gear for combustibe materials.
Environmental Precautions:
Do not allow the substance or solutions of the substance to be discharged
into lakes, streams, ponds or public waters.
Cleanup Procedures:
Small spills should be absorbed by dirt, sand, vermiculate, or other
suitable absorbent. Large spills may be pumped (if liquid) or scooped
(if solid) into closed containers for recovery or disposal.
7. HANDLING AND STORAGE
Handling:
Wear safety glasses or goggles, rubber gloves and apron when handling
material. If transferring to or from the container, use proper
grounding procedures.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 2 of 6
Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
Storage:
Do not store in close proximity to excessive heat, open flames, strong
acids or strong bases. To minimize product degradation, avoid prolonged
exposure of the substance to air. Keep container tightly closed when
not in use.
Ventilation:
Mechanical exhaust may be needed in confined and poorly ventilated areas.
Safety Stations:
An eyewash station and a safety shower should be readily available and
clearly marked.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits:
None found.
Exposure Controls:
Respiratory Protection:
A respirator is not normally required. If vapor concentration is suspected
to be high, use a NIOSH approved organic vapor respirator
Eye Protection:
Wear safety glasses or goggles.
Hand Protection:
Wear standard industrial type rubber gloves.
Skin Protection:
A rubber apron is recommended when handling the material for extended
periods of time.
Personal Hygiene:
Wash hands and other exposed areas of skin with soap and water after
handling the material.
Environmental Controls:
No environmental exposure controls required under Community environmental
protection laws.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information:
Property Result
Appearance: White, crystalline solid at room temperature.
Odor: Camphor-type.
Important Health, Safety and Environmental Information:
Property Result
pH: Not determined.
Boiling Point: 320F (160C) (Thermal Analyzer)
Flash Point: 93F (34C) (Tag Closed Cup)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 3 of 6
Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
Melting Point: 111-115癋 (44 - 46癈) (Thermal Analyzer)
Flammability: Not determined.
Explosive Properties: Not an explosive.
Oxidizing Properties: Not Determined.
Vapor Pressure: ca. 3 mmHG @ 20 C
Solubility in Water (Weight%): Not determined
Solubility in Alcohol(Weight%): 100
Fat Solubility: NOT DETERMINED.
Partition Coefficient (n-Octanol/Water): Not determined
Viscosity: Not determined.
Vapor Density (air=1): CA.4.7
Evaporation Rate (Butyl Acetate=1): Not determined.
Autoignition Temperature: Not determined
Specific Gravity: 0.839 @ 60 C
10. STABILITY AND REACTIVITY
Stability:
Substance is stable and unreactive under conditions of normal use.
Conditions to Avoid:
Prolonged or excessive heat and/or exposure to air may cause non-hazardous
decomposition and/or oxidation of the substance.
Materials to Avoid:
Avoid contact with strong acids, bases and materials that react with
unsaturated hydrocarbons.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
11. TOXICOLOGICAL INFORMATION
Primary Target Organs: Eyes
Primary Entry Route(s): Eyes.
Medical Conditions Aggravated by Overexposure No known conditions.
Acute Toxicity:
Parameter Result
Acute Oral Toxicity: LD50 (Rat): > 5000 mg/kg
Acute Inhalation Toxicity: Not determined
Acute Dermal Toxicity: LD50 (rabbit): >2500 mg/kg
Eye Irritancy: Contact with the undiluted material is irritating to eyes.
Dermal Irritancy: Camphene applied full strength to intact or abraded rabbit skin for 24
hours under occlusion was slightly irritating. Closed patch test (48H,
4% in petrolatum): No irritation on human subjects.
1095Irritating to skin.
Skin Sensitization: Maximization test (4% in petrolatum): No sensitization in 25 human
subjects.
Mutagenicity: Not determined
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 4 of 6
Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
Teratogenicity: Not determined.
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not determined.
Mobility: Not Determined.
Persistence and Degradability: Not determined.
Bioaccumulation Potential: Not determined.
Ozone Depleting Substances: None.
13. DISPOSAL CONSIDERATIONS
Disposal Methods: This material, if discarded, is considered a hazardous waste by EPA
regulations 40 CFR 261.
Safe Handling of Wastes: Refer to Section 8 for information pertaining to personal protective
equipment and exposure controls when handling this material for
disposal.
Community Provisions: Dispose of this material at a local, state or federally approved landfill,
incinerator or recovery facility.
14. TRANSPORT INFORMATION
Label Codes: FLAMMABLE SOLID
DOT Proper Shipping Name (Bulk): UN1325, Flammable Solid, Organic, n.o.s.(Camphene),
4.1, PGII
DOT Proper Shipping Name (Non-Bulk): UN1325, Flammable Solid, Organic, n.o.s.(Camphene),
4.1, PGII
ERG: 133
15. REGULATORY INFORMATION
Chemical Inventories Status:
USA (TSCA): Compliant.
European Community (EINECS): Compliant.
Canada (DSL): Compliant.
Australia (AICS): Compliant.
Japan (IEC): Compliant.
Korea (KECI/ECL): Not Compliant
Philippines (PICCS): Compliant.
China (SEPA/CICS): Compliant.
USA: Federal:
SARA Title III Section 302/304: None.
SARA Title III Section 311/312: Yes
SARA Title III Section 313: None.
Hazardous Air Pollutants: None.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 5 of 6
Product Code 01F24AS
Revision Date 05/03/2010
Supersedes 01/12/2010
Material Safety Data Sheet Date Printed 05/11/2010
USA: States:
None.
International:
None.
16. OTHER INFORMATION
EU Classifications:
Symbol Code(s): Symbol Phrase(s):
Xi,N IRRITANT/DANGEROUS FOR THE ENVIRONMENT
Risk Phrase Codes: Risk Phrases:
R(10)-36-50/53 Flammable Irritating to eyes, Very toxic to aquatic organisms, may cuase
long term adverse effects in the aquatic environment.
Safety Phrase Codes: Safety Phrases:
S26-61 If swallowed, do not induce vomiting. Get medical attention
immediately. Avoid releases to the environment. Refer to special
instructions/Safety Data sheet.
U.S. NPCA/HMIS Hazardous Materials Information System
Health Flammability Reactivity Personal Protection*
1 3 1 C
0 - Minimal Hazard: No significant risk to health.
1 - Slight Hazard: Irritation or minor reversible injury possible.
2 - Moderate Hazard: Temporary or minor injury may occur.
3 - Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given.
4 - Severe Hazard: Life-threatening, major or permanent damage mayresult from single or repeated exposures.
* This rating will generally suffice for normal operating conditions.Please note however, that the type of personal
protection utilized may change based on specific use conditions (refer to Section 8).
Reason(s) for (Re)issue:
Legal entity change.
Technical Contact(s):
Environmental and Regulatory Affairs Dept.
References:
RIFM - Research Institute for Fragrance Materials RTECS- Registry of Toxic Effects of Chemical Substances
Acronyms: NTP(National Toxicology Program); IARC (International Agency for
Research on Cancer); OSHA (Occupational Health and Safety
Administration); DOT (U.S. Dept. of Transportation)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 6 of 6
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