SAFETY DATA SHEET - REGULATIONS 1994 (CHIP 2)
WE urge the customer receiving this Material Safety Data Sheet to study it carefully to become aware of
hazards, if any, of the product involved. In the interests of safety you should:
1) notify your employees, agents and contractors of the information on this sheet,
2) furnish a copy to each of your customers for the product, and
request your customers to inform their employees and customers as well.
3)
1) Identification and Company
Date revised: 11 02 03 Revision No:06 Compiler: Mr F M Jachim
Manufacturer or Supplier: Parasol Inc.
Product Name: Rubberbond
Chemical Characterisation: Solvent based paint for rubberised materials.
Form Liquid - 1 litre, 5 litre cans and 20 litre. containers.
Colour Various
Odour Characteristic odour
2) Composition
Material CAS No: % Content Risk Symbol Risk Phrases
Methyl Ethyl Ketone 78-93-3 37.00 11,36,66,67
Xi
Methyl Isobutyl Ketone 108-10-1 19.40 Xn 11,20,36,37,66
Ethyl Acetate 141-78-6 19.40 Xi 11,36,66,67
Xylene 1330-20-7 7.43 10,20,21,38
Xn
Ethylbenzene 100-41-4 1.67 11,20
Xn
Chlorobenzene 108-90-7 0.14 10,20,51,53
Xn
Toluene 108-88-3 0.01 MAX. 11,20
Xn
Isobutanol 78-83-1 1.22 Xi 10,37,38,41,67
Butyl Benzyl Phthalate 85-68-7 2.00 20, 36,38
Xi
Cellolose Acetate Butyrate 9004-36-8 0.30 36,37,38
Xi
Chlorinated Polyolefin 68609-36-9 2.50 None
None
Epoxidized Oil 61789-01-3 0.14 None
None
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Micronized Polyethylene Wax 9002-88-4 1.00 None
Non-Haz
Amorphous Silica 7631-86-9 0.20 None
Non-Haz
Acrylic Polymer Not Required 1.99 None
Non-Haz
Polyurethane Polymer Not Required 5.40 None
Non-Haz
Surface Active Agent 95-63-3 10,20,36,37,38
Xn
Surface Active Agent 64742-47-8 65
Xn
Surface Active Agent 647421-82-1 65
Xn
0.20
Surface Active Agent 64742-94-5 65
Xn
Surface Active Agent 64747-49-0 11,51,53,65
Xn
Pigments Not Required 0.01< 20.00 None
Non-Haz
3) Hazards Identification
Physical Highly Flammable. R-11
Adverse Human Effects Can enter the body by inhalation, ingestion, or through the skin. Irritates the
eyes, skin and respiratory tract.
Liquid removes the skin's natural oils.
Repeated exposure may cause skin dryness or cracking. Vapours may
cause drowsiness and dizziness.
4) First Aid Measures
Inhalation Move the exposed person to fresh air at once.
Get medical attention immediately.
For breathing difficulties oxygen may be necessary.
If rapid recovery does not follow, apply artificial respiration.
Ingestion Do not induce vomiting.
Obtain medical attention immediately.
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Skin Wash the skin immediately with soap and water.
Use a moisturiser.
Get medical attention if any discomfort continues.
Eye Flush with plenty of water for several minutes.
Make sure to remove any contact lenses before rinsing.
Continue to rinse for at least 15 minutes.
If irritation persists, refer for medical attention.
5) Fire Fighting Measures
Extinguishing Media Use a dry chemical powder, foam or carbon dioxide extinguisher, sand or
earth.
Do not use water in a jet.
Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water.
Use water to keep fire-exposed containers cool.
Unusual Fire & Explosion Hazards Risk of explosion if heated.
Vapours may cause a flash fire or ignite explosively.
Vapours may travel considerable distance to a source of ignition
and flash back.
Static electricity can build-up during the handling or mixing of the
non-polar hydrocarbon solvents such as xylene or toluene.
6) Accidental Release Measures
Spillage/Leakage/Gas Leakage Extinguish all ignition sources.
Avoid sparks, flames, heat and smoking.
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Ventilate.
Wear the necessary protective equipment.
Prevent the liquid from spreading with sand or sawdust.
Shovel up and remove to a safe place.
Flush contaminated area with water.
If leakage cannot be stopped evacuate area.
Ventilate well.
Do not contaminate water sources or sewer.
Shovel up and remove to a safe place.
Extinguish naked flames.
Ensure adequate ventilation.
Wear protective clothing and breathing apparatus as outlined below.
7) Handling and Storage
Handling Precautions Ensure adequate positive ventilation to keep concentrations well below
hazard levels.
Keep away from heat, sparks and open flames.
Static electricity may result in build-up, which may cause a flash fire or
an explosion.
Storage Precautions Containers must not be exposed to direct sunlight or temperatures above
50癈.
Store away from oxidising agents.
Avoid exposure to sources of heat or ignition.
Keep containers tightly closed.
8) Exposure Controls and Personal Protection
Name CAS No. STD LT EXP (8 hrs) ST EXP (15
min)
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Methyl Ethyl Ketone 78-93-3 OES 200 ppm (SK) 300 ppm (SK)
Methyl Isobutyl Ketone 108-10-1 OES 50 ppm (SK) 75 ppm (SK)
Ethyl Acetate 141-78-6 OES 400 ppm (SK) No Data
Isobutanol 78-83-1 OES 50 ppm (SK) 75 ppm (SK)
Xylene 1330-20-7 OES 100 ppm (SK) 150 ppm (SK)
Toluene 108-88-3 OES 50 ppm (SK) 75 ppm (SK)
Chlorobenzene 108-90-7 OES 10 ppm (SK) No Data
Comments OES = Occupational Exposure Standard
SUP = Supplier's Recommendation
SK = Can be absorbed through skin
Protective Equipment Wear safety goggles/glasses to give protection to eyes.
Wear suitable protective gloves.
Wear overalls.
Avoid contact with liquid.
Wear an approved breathing apparatus when concentrations above 100
ppm are present.
Ventilation Provide adequate general and local exhaust ventilation.
Respirators No specific recommendation made, but respiratory protection must be used
if the general level exceeds the Occupational Exposure Level (OEL).
In case of insufficient ventilation, wear suitable respiratory equipment.
Protective Gloves Use protective nitrile rubber gloves.
Eye Protection Use approved safety goggles/glasses or face shield.
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Protective Clothing Wear appropriate clothing to prevent any possibility of liquid contact and
repeated or prolonged vapour contact.
Wear antistatic clothing made of natural fibre of high temperature
resistant synthetic fibre.
Wear chemical resistant gloves, boots, and protective clothing
appropriate for the risk of exposure.
Industrial Hygiene Work Routine DO NOT SMOKE IN WORK AREA.
Wash at the end of each work shift and before eating, smoking and
using the toilet.
Promptly remove any clothing that becomes contaminated.
No eating or drinking while working with this material.
9) Physical and Chemical Properties
Appearance Liquid
Odour Characteristic odour
Melting point - 84 癈
Boiling point >80 癈
(20 癈) 0.862 - 1.100 gm/ml
Density
Vapour Pressure (20癈) 95 mbar
Viscosity (20癈) 11-16 sec's. Ford Cup No. 4
Solubility in water (20癈) less than 100 gm/l
-3 癈 Closed Cup
Flash Point
Autoignition Temperature >460癈
Flammability Limit (upper %) 10.5
Flammability Limit (lower %) 1.8
10) Stability and Reactivity
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Thermal Decomposition Thermal decomposition may occur.
Decomposition may yield acrylic monomers.
Hazardous Decomposition
Products Fire creates Vapours/ Gases/ Carbon monoxide (CO) & Carbon dioxide
(CO2) Fumes, Oxides of carbon and nitrogen.
Hazardous Reactions No hazardous decomposition products when stored and used correctly.
Conditions to Avoid Avoid heat, flames and other sources of ignition.
Avoid contact with strong oxidising agents, strong alkali, and strong
mineral acids.
11) Toxicological Information
Health Hazards, General Prolonged and repeated contact with solvents over a long period may lead to
permanent health problems.
Inhalation Gas or vapour at high concentrations may irritate respiratory system.
Gas or vapour displaces oxygen available for breathing (asphyndent).
Vapours may cause systematic effects like narcosis, headaches, dizziness,
fatigue, muscular weakness, or drowsiness.
In extreme cases, loss of consciousness may occur.
Skin Product has a de-fatting effect on the skin.
Prolonged or repeated exposure may cause severe irritation.
Eyes Irritating to the eyes.
Spray and vapour in the eyes may cause irritation and smarting. May
cause severe irritation to eyes.
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Ingestion Ingestion may cause sore throat, nausea, diarrhoea, and abdominal pain.
Route of entry Inhalation, skin, eyes, or ingestion.
12) Ecological Information
Mobility Very low water solubility.
Degradability Biologically degradable.
Bioaccumulative Potential Practically no potential to bioaccumulate.
Aquatic Toxicity Low biochemical oxygen demand and essentially no oxygen depletion in
aquatic systems.
Do not allow to escape into water, wastewater drains or soil.
13) Disposal Considerations
Disposal via an authorised waste disposal contractor to an approved
waste disposal site, observing all local and national regulations.
The relevant EC Directives and local, regional and national regulations
must be in compliance. Used
containers must not be cut up or punctured until completely purged of
product residues.
Empty containers must not be burned because of explosion hazard.
Containers must be recycled in compliance with national legislation and
environmental regulations.
Disposal subject to the Local Authority laws and requirements, national
and environmental regulations.
Disposal via licensed waste disposal contractor.
14) Transport Information
LITRES:
ADR:
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
ADR: UN Number 1263
ADR: Proper Shipping Name Paint
ADR: Class 3
ADR: Packing Group II
ADR: Classification Code F1
ADR: Transport Category 2
ADR: Hazard Identification Number 33
IMDG:
IMDG: UN Number 1263
IMDG: Proper Shipping Name Paint
IMDG: Class 3
IMDG: Packing Group II
IMDG: EmS F-E, S-E
IATA:
IATA: UN Number 1263
IATA: Proper Shipping Name Paint
IATA: Class 3
IATA: Packing Group II
IATA: Packing Instruction 305
15) Regulatory Information
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Risk Phrases R-11 Highly Flammable.
R-20 Harmful by inhalation.
R-21 Harmful in contact with skin.
R-36 Irritating to eyes.
R-37 Irritating to respiratory system.
R-38 Irritating to skin.
R-41 Risk of serious damage to eyes.
R-51 Toxic to aquatic organisms.
R-53 May cause long-term adverse effects in the aquatic
environment.
R-65 Harmful. May cause lung damage if swallowed.
R-66 Repeated exposure may can skin dryness or cracking.
R-67 Vapours may cause drowsiness and dizziness.
(reference section 2 composition) R-10 Flammable
Safety Phrases S-9 Keep container in a well-ventilated place.
S-16 Keep away from heat and sources of ignition.
No Smoking.
S-21 When using do not smoke.
S-23 Do not breathe vapour/spray.
S-24 Avoid contact with skin.
S-25 Avoid contact with eyes.
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
S-26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
S-29 Do not empty into drains.
S-33 Take precautionary measures against static
discharges.
S-38 In case of insufficient ventilation wear suitable respiratory
equipment.
S-51 Use only in well-ventilated areas.
UK Regulatory References: Chemicals (Hazard Information and Packaging for Supply)
Regulations 1994 (CHIP 2)
Chemicals (Hazard Information and Packaging for Supply)
Regulations 1994 (CHIP 2) Regulation 6
Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regulations 1996 (CHIP 96)
Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regulations 1997 (CHIP 97)
Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regulations 1998 (CHIP 98)
Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regulations 1999 (CHIP 99)
Chemicals (Hazard Information and Packaging for Supply)
(Amendment) (No. 2) Regulations 1999 (CHIP 99(2))
IATA - Dangerous Goods Regulations
IMDG - International Maritime Dangerous Goods Code
ADR - Dangerous Goods Code
UK Publication References: Approved Guide to the Classification and Labelling of
Substances and Preparations Dangerous for Supply.
(Guidance on Regulations) (Fourth Edition)
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
Safety Data Sheets for Substances and Preparations Dangerous
for Supply. (Approved Code of Practice) (Second Edition)
Approved Supply List - Information Approved for the
Classification and Labelling of Substances and Preparations Dangerous
for Supply. (Fifth Edition)
Carriage of Dangerous Goods - Guidance for Consignors of Dangerous
Goods.
Occupational Exposure Limits.
UK Environmental References: Control of Pollution (Special Waste Regulations) Act
Rivers (Prevention of Pollution) Act
UK Statutory References: Chemicals (Hazard Information and Packaging for Supply)
Regulations 1994 (CHIP 2)
16) Other Information
Emergency Action Notify Police and Fire Brigade immediately.
17) Disclaimer
Disclaimer The information accumulated herein is believed to be accurate and reliable as
of the date above, however Parasol Inc. makes no representation, warranty
or guarantee nor assumes any legal responsibility as to its accuracy, reliability
or completeness. Ultimate determination of suitability for intended use is the
responsibility of the user.
11 02 03 Rev. 06
in accordance with EU Directives
252A Broadway Ave, Toronto, ON-M4P 1V9, Canada. Tel: 888 702-0778, (416) 486-4947 Fax: (416) 486-3552. info@parasolinc.com
|