Material Safety Data Sheet
431-9135 OPTICLEAR SATIN
1. Product and company identification
: 431-9135
Code
Synonym : OPTICLEAR SATIN
Material uses : Coatings: Surface coatings and finishes.
Manufacturer : Chemcraft International, Inc.
3950 New Walkertown Road
Winston-Salem, NC 27105
Ph:336-723-1846 Fax:336-724-7138
In case of emergency : 1-800-424-5571
Validation date : 5/17/2006.
Print date : 11/28/2006.
: K. William
Validator
2. Composition/information on ingredients
Name CAS number %
n-Butyl acetate 123-86-4 30 - 50
Isobutyl alcohol 78-83-1 5 - 15
Isopropanol 67-63-0 5 - 15
Ethyl alcohol 64-17-5 5 - 15
Ethyl Acetate 141-78-6 1-5
Propylene glycol monomethyl ether 107-98-2 1-5
Potential additional emission of formaldehyde 50-00-0* 0.1 - 1
Xylenes 1330-20-7 0.1 - 1
Trace impurities and additional material names not listed above may appear in other sections of this MSDS. These materials
may be listed for toxicological concerns, local compliance, or other reasons.
* Toxicological information, if available, is listed in section 11
3. Hazards identification
Physical state : Liquid.
: This material is considered hazardous by the OSHA Hazard Communication Standard
OSHA/HCS status
(29 CFR 1910.1200).
OSHA: Standard for Occupational Exposure to Formaldehyde 29CFR 1910.1048 must be consulted
before initial use of product.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
: Do not get in eyes or on skin or clothing. Wash thoroughl y after handl ing. Risk of
Effects of Acute
cancer depends on duration and level of exposure.
Exposure
Potential chronic health : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by
effects ACGIH [Ethanol]. Classified A5 (Not suspected for humans.) by ACGIH, 4 (Probably not
for humans.) by IARC [Acetic Acid, Ethyl Ester]. Classified 4 (Probably not for humans.)
by IARC, None. by OSHA [2-Propanol, 1-methoxy-]. Classified 4 (Probably not for
humans.) by IARC [Silica gel, pptd., cryst.-free]. Classified A5 (Not suspected for
humans.) by ACGIH, 4 (Probably not for humans.) by IARC [Phosphoric acid, monobutyl
ester]. Classified A2 (Suspected for humans.) by ACGIH, 2A (Probable for human.) by
IARC [Potential additional emission of formaldehyde].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
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3. Hazards identification
Medical conditions : Repeated or prolonged exposure to the substance can produce target organs damage.
aggravated by over-
exposure
See toxicological information (section 11)
4. First aid measures
Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove
any contact lenses.
Skin contact : Get medical attention immediately. Flush contaminated skin with plenty of water.
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing or wear gloves.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Inhalation : Get medical attention immediately. Move exposed person to fresh air. If it is suspected
that fumes are still present, the rescuer should wear an appropriate mask or self-
contained breathing apparatus. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen
by trained personnel. It may be dangerous to the person providing aid to give mouth-
to-mouth resuscitation. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Ingestion : Get medical attention immediately. Wash out mouth with water. Remove dentures if
any. Move exposed person to fresh air. Keep person warm and at rest. If material has
been swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such as
a collar, tie, belt or waistband.
: No action shall be taken involving any personal risk or without suitable training.
Protection of first-aiders
5. Fire-fighting measures
Flammability of the product : Flammable.
Products of combustion : These products are carbon oxides (CO, CO2).
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : No specific hazard.
Vapor may travel considerable distance to source of ignition and flash back. (Acetic Acid,
Special Remarks on :
Butyl Ester)
Fire Hazards
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
: Extremely flammable in the presence of the following materials or conditions: open flames,
Fire Hazards in Presence
sparks and static discharge.
of Various Substances
Highly flammable in the presence of the following materials or conditions: heat.
Slightly fl ammable in the presence of the following materi als or conditions: ox idizing
materials.
: Highly explosive in the presence of the following materials or conditions: open flames,
Explosion Hazards in
sparks and static discharge, heat and shocks and mechanical impacts.
Presence of Various
Substances
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6. Accidental release measures
Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway. Place spilled material in an appropriate container for disposal.
7. Handling and storage
: Do not get in eyes or on skin or clothing. Wash thoroughly after handling.
Handling
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
8. Exposure controls/personal protection
Product name Exposure limits
Acetic Acid, Ethyl Ester ACGIH TLV (United States).
TWA: 400 ppm 8 hour/hours.
TWA: 400 ppm
Consult local authorities for acceptable exposure limits.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor or
mist, use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Personal protection
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before handling
this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
9. Physical and chemical properties
Physical state : Liquid.
Flash point : The lowest known value is Closed cup: -1癈 (30.2癋). (Tagliabue). Open cup: -0.5癈
(31.1癋). (Tagliabue). (Acetic Acid, Ethyl Ester)
Auto-ignition temperature : The lowest known value is 287癈 (548.6癋) (2-Propanol, 1-methoxy-).
Flammable limits : The greatest known range is Lower: 3.3% Upper: 19% (Ethanol)
pH : Neutral.
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9. Physical and chemical properties
Boiling/condensation point : The lowest known value is 77癈 (170.6癋) (Acetic Acid, Ethyl Ester). Weighted average:
115.24癈 (239.4癋)
Melting/freezing point : May start to solidify at -48癈 (-54.4癋) based on data for: 1,2-Benzenedicarboxylic acid,
di-C(8-10)-branched alkyl esters, C9-rich. Weighted average: -87.74癈 (-125.9癋)
: 0.929 (Water = 1)
Relative density
Vapor pressure : The highest known value is 9.7 kPa (73 mm Hg) (at 20癈) (Acetic Acid, Ethyl Ester).
Weighted average: 3.62 kPa (27.15 mm Hg) (at 20癈)
Vapor density : The highest known value is 4 (Air = 1) (1,2-Benzenedicarboxylic acid, di-C(8-10)
-branched alkyl esters, C9-rich). Weighted average: 3.06 (Air = 1)
Evaporation rate : The highest known value is 7.5 (Acetic Acid, Ethyl Ester) Weighted average:
1.43compared with Butyl acetate.
: Partially dispersible in methanol, diethyl ether.
Dispersibility properties
Not dispersible in cold water, hot water.
See solubility in methanol, diethyl ether, n-octanol, acetone.
Solubility : Easily soluble in methanol, diethyl ether, acetone.
Partially soluble in n-octanol.
Insoluble in cold water, hot water.
10 . Stability and reactivity
Stability and reactivity : The product is stable.
Conditions of instability : Avoid contact with oxidizing agents. (Benzene, (1-methylethenyl)-)
: Reactive or incompatible with the following materials: oxidizing materials, reducing
Incompatibility with various
materials, acids and alkalis.
substances
Slightly reactive or incompatible with the following materials: organic materials.
11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
Acetic Acid, Butyl Ester LD50 14130 mg/kg Oral Rat
LD50 7100 mg/kg Oral Mouse
LD50 5000 mg/kg Dermal Rabbit
LD50 8770 mg/kg Dermal Guinea pig
1-Propanol, 2-methyl- LD50 2500 mg/kg Oral Rat.
LD50 3200 mg/kg Oral Mouse
LD50 4200 mg/kg Dermal Rabbit.
Ethanol LD50 7060 mg/kg Oral Rat.
LC50 8000 mg/l (4 Inhalation Rat.
hour/hours)
Acetic Acid, Ethyl Ester LD50 5620 mg/kg Oral Rat
LD50 4100 mg/kg Oral Mouse
LD50 4935 mg/kg Oral Rabbit
45000 mg/m3 (2
LC50 Inhalation Mouse
hour/hours)
LC50 16000 ppm (6 Inhalation Rat
hour/hours)
: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by
Chronic effects on humans
ACGIH [Ethanol]. Classified A5 (Not suspected for humans.) by ACGIH, 4 (Probably not
for humans.) by IARC [Acetic Acid, Ethyl Ester]. Classified 4 (Probably not for humans.)
by IARC, None. by OSHA [2-Propanol, 1-methoxy-]. Classified 4 (Probably not for
humans.) by IARC [Silica gel, pptd., cryst.-free]. Classified A5 (Not suspected for
humans.) by ACGIH, 4 (Probably not for humans.) by IARC [Phosphoric acid, monobutyl
ester]. Classified A2 (Suspected for humans.) by ACGIH, 2A (Probable for human.) by
IARC [Potential additional emission of formaldehyde].
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11 . Toxicological information
Contains material which causes damage to the following organs: blood, kidneys, the
nervous system, the reproductive system, liver.
: Hazardous in case of ingestion, of inhalation.
Other toxic effects on
humans Slightly hazardous in case of skin contact (permeator).
Special remarks on toxicity : Formaldehyde has caused cancer in test animals at high concentrations (5-15 ppm).
(Potential additional emission of formaldehyde)
to animals
Special remarks on chronic : 0070 Passes through the placental barrier in human.
(1-Propanol, 2-methyl-)
effects on humans
: Material is irritating to mucous membranes and upper respiratory tract. (Acetic Acid,
Special remarks on other
toxic effects on humans Butyl Ester)
Specific effects
Carcinogenic effects : Contains material which may cause cancer. Risk of cancer depends on duration and
level of exposure.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity / : No known significant effects or critical hazards.
Reproductive toxicity
12 . Ecological information
: No known significant effects or critical hazards.
Environmental precautions
: The product is more soluble in octanol.
Octanol/water partition
coefficient
Bioconcentration factor : Not available.
: These products are carbon oxides (CO, CO 2) and water.
Products of degradation
Toxicity of the products of : The product itself and its products of degradation are not toxic.
biodegradation
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Class PG* Label
information
1263 PAINT 3 II
TDG Classification
3
PG* : Packing group
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15 . Regulatoryinformation
United States
HCS Classification : Highly toxic material
Carcinogen
Target organ effects
U.S. Federal regulations : SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Acetic
Acid, Butyl Ester; 2-Propanol: Fire hazard, Delayed (chronic) health hazard; Isobutyl
alcohol: Fire hazard, Delayed (chronic) health hazard; Acetic Acid, Ethyl Ester: Fire
hazard, Immediate (acute) health hazard
Clean Water Act (CWA) 307: Benzene, ethyl-
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
State regulations : WARNING: This product contains chemical/chemicals known to the state of California to
cause cancer, birth defects or other reproductive harm.: Formaldehyde
WARNING: This product contains chemical/chemicals known to the state of California to
cause cancer.: Formaldehyde
Illinois toxic substances disclosure to employee act: Benzene, ethyl-
New York release reporting list: Acetic Acid, Butyl Ester; Acetic Acid, Ethyl Ester
New York acutely hazardous substances: Benzene, ethyl-
Rhode Island RTK hazardous substances: Acetic Acid, Ethyl Ester; Benzene, ethyl-
Pennsylvania RTK: Acetic Acid, Butyl Ester; Isopropyl alcohol; Ethanol; Acetic Acid, Ethyl
Ester; 2-Propanol, 1-methoxy-; Benzene, ethyl-; Benzene, dimethyl-
Florida: Acetic Acid, Butyl Ester; Acetic Acid, Ethyl Ester; Benzene, ethyl-
Minnesota: Acetic Acid, Butyl Ester; Ethanol; Acetic Acid, Ethyl Ester; Benzene, ethyl-
Massachusetts RTK: Acetic Acid, Butyl Ester; Isopropyl alcohol; Ethanol; Acetic Acid,
Ethyl Ester; 2-Propanol, 1-methoxy-; Benzene, ethyl-
New Jersey: Acetic Acid, Butyl Ester; Isopropyl alcohol; Ethanol; Acetic Acid, Ethyl Ester;
2-Propanol, 1-methoxy-; Benzene, ethyl-
TSCA 8(b) inventory: Acetic Acid, Butyl Ester; Isopropyl alcohol; Ethanol; Acetic Acid,
Ethyl Ester; N-Butyl Alcohol; Benzene, ethyl-; Benzene, dimethyl-
TSCA 5(e) substance consent order: Acetic Acid, Butyl Ester; Acetic Acid, Ethyl Ester
TSCA 8(d) H and S data reporting: Benzene, ethyl-
TSCA 12(b) annual export notification: Acetic Acid, Butyl Ester; Acetic Acid, Ethyl Ester
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Acetic
Acid, Butyl Ester; 2-Propanol: Fire hazard, Delayed (chronic) health hazard; Isobutyl
alcohol: Fire hazard, Delayed (chronic) health hazard; Acetic Acid, Ethyl Ester: Fire
hazard, Immediate (acute) health hazard
CERCLA: Hazardous substances.: Acetic Acid, Butyl Ester; Isobutyl alcohol; Acetic Acid,
Ethyl Ester; N-Butyl Alcohol; Benzene, ethyl-: 1000 lbs. (453.6 kg); Benzene, dimethyl-:
100 lbs. (45.36 kg);
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
Acetic Acid, Ethyl Ester No. No. No. No.
Formaldehyde Yes. No. No. No.
Canada
WHMIS (Canada) : Class B-2: Flammable liquid
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
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15 . Regulatoryinformation
16 . Other information
: SUSPECT CANCER HAZARD.
Label requirements
CONTAINS MATERIAL WHICH MAY CAUSE CANCER.
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
BLOOD, KIDNEYS, NERVOUS SYSTEM, REPRODUCTIVE SYSTEM, LIVER.
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
* 3
Hazardous Material : Health
Information System (U.S.A.)
3
Fire hazard
0
Reactivity
H
Personal protection
* Indicates may be chronic effects
National Fire Protection : Flammability
3
Association (U.S.A.)
3 0
Health Instability
Special
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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