MATERIAL SAFETY DATA SHEET
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SECTION I - IDENTIFICATION
PRODUCT NAME: PRO-FINISH WHITE & BLACK LAQUER AEROSOL
PRODUCT CODE: PPD300, 301, 302, 313, 320, 321, 322, 340
MANUFACTURER'S NAME: DOVER FINISHING PRODUCTS
3245 J. B. DESCHAMPS
LACHINE, QUEBEC
H8T 3E4
INFORMATION PHONE: (514) 420-6030
DATE PRINTED: 2009-10-26
WHMIS CODES: H: 2 F: 3 R:0 P:1
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SECTION II - HAZARDOUS INGREDIENTS
NAME CAS# %WEIGHT TLV / PEL LD50 / LC50
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ACETONE 67-64-1 30-40 TWA:750 STEL 1000 ORAL (LD50) ACUTE 3000
TWA: 1780 STEL 2380 MG/KG (MOUSE). DERMAL
MG/M3 FROM ACGIH (LD50) ACUTE 20000 MG/KG
(RABBIT). VAPOR (LC50)
29853 PPM 4HRS (RAT)
PROPANE 74-98-6 5-6 OSHA PEL 1000 PPM NOT AVAILABLE
ISOBUTANE 25-1-9 3-4 OSHA PEL 800 PPM NOT AVAILABLE
EB ETHYLENE 111-76-2 0-1 OSHA PEL 50 PPM NOT AVIALABLE
GLYCOL BUTYL ETHER
GLYCOL ETHER PW 107-982 0-1 OSHA PEL 50 PPM NOT AVAILABLE
BENZENE, METHYL- 108-88-3 4-8 TWA:50 PPM (1993) ORAL(LD50):ACUTE 2600
TWA:147 MG/M3 FROM MG/KG (RAT). DERMAL (LD50)
ACGIH ACUTE:12210 MG/KG (RABBIT)
VAPOR (LC50) ACUTE: 8000
PPM 4HRS (RAT)
METHANOL 67-56-1 4-8 TWA:200 (PPM) ORAL(LD50): ACUTE 6200
TWA:262 MG/M3 FROM MG/KG (RAT). DERMAL (LD50)
ACGIH ACUTE: 15800 MG/KG
(RABBIT)
VAPOR (LC50) ACUTE 64000
PPM 4 HRS (RAT)
XYLENE 1330-20-7 10-20 TWA:100 STEL:150 ORAL (LD50)ACUTE 4300
PPM (1992) MG/KG (RAT) DERMAL
TWA:434 STEL 651 (LD50) ACUTE >2000 MG/KG
MG/M3 FROM ACGIH (RABBIT) VAPOR(LC50):
ACUTE 6700 PPM 4 HRS (RAT)
ISOBUTANOL 78-83-1 4-8 TWA: 50 PPM FROM ORAL (LD50): ACUTE 2460
ACGIH (TLV) 1993 MG/KG (RAT) DERMAL (LD50)
ACUTE 3400 MG/KG (RABBIT)
ISOPROPANOL 67-63-0 4-8 TWA: 400 STEL:500 ORAL (LD50) ACUTE 4721
PPM FROM ACGIH MG/KG (RAT) DERMAL (LD50)
(TVL) 1994 ACUTE 13000 MG/KG (RABBIT)
TWA 983 STEL1230 VAPOR LC50 ACUTE 16971
MG/M3 FROM ACGIH PPM 4 HRS (RAT)
1994
N-BUTYL ACETATE 123-86-4 4-8 TWA:150 STEL:200 PPM ORAL (LD50) ACUTE 14000
1994 MG/KG (RAT) DERMAL (LD50)
ACUTE 5000MG/KG (RABBIT)
ETHYL HYDROXIDE 64-17-5 1-3 TWA:1000 PPM FROM ORAL (LD50) ACUTE 7060
ACGIH (TLV) MG/KG (RAT) VAPOR (LC50)
ACUTE 8000 PPM 4HRS (RAT)
ETHYL ACETATE 141-78-6 2-6 TWA: 400 PPM ORAL (LD50) ACUTE 5600
MG/KG (RAT) VAPOR (LC50)
ACUTE 19596 PPM 4HRS
(RAT)
-1-METHOXY-2- 107-98-2 1-3 TWA: 100 STEL 150 PPM ORAL (LD50) ACUTE 5660
PROPANOL MG/KG (RAT) DERMAL (LD50)
ACUTE 13000 MG/KG (RABBIT)
GAS (LC50) ACUTE 15000 PPM
4HRS (RAT)
NITROCELLULOSE 9004-70-0 4-6 NOT AVAILABLE NOT AVAILABLE
METHYL ISOBUTYL 108-10-1 1-3 TWA: 50 STEL: 75 PPM ORAL (LD50) ACUTE 2080
KETONE FROM ACGIH (TVL) MG/KG (RAT) DERMAL (LD50)
1994. TWA:205 STEL: 20001 MG/KG (RABBIT)
307 MG/M3 FROM
ACGIH 1994
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SECTION III - PHYSICAL / CHEMICAL CHARACTERISTICS
BOIILING RANGE: 56 DEG C - 171 DEG C WEIGHT / GAL: 3.15 KG
VAPOR DENSITY EVAPORATION RATE: SLOWER THAN ETHER
HEAVIER THAN AIR
COATING V.O.C. NOT MATERIAL V.O.C. NOT AVAILABLE
AVAILABLE
APPEARANCE AND ODOR: VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE SOLVENTS
LISTED IN SECTION II
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SECTION IV - FIRE AND EXPLOSION HAZARD DATA
THIS PRODUCT IS: FLAMMABLE, EXPLOSIVE, AND INSOLUABLE IN WATER
FIRE DEGRADATION PRODUCTS: THESE PRODUCTS ARE CARBON OXIDES (CO, CO2)
AUTOIGNITION TEMPERATURE: LOWEST KNOWN IS 137 DEG C (1-METHOXY-2PROPANOL)
FLASH POINT: -104 DEC C
FLAMMABLE LIMITS IN AIR BY VOLUME: LOWER: 1.8 UPPER 19.0 (ETHYL HYDROXIDE)
EXTINGUISHING MEDIA:
Use National Fire Protection Association (NFPA) Class B extinguisher. (CarbonDioxide, dry, chemical, or
universal film forming foam) designed to extinguish NFPA flammable liquid fires.
SPECIAL FIREFIGHTING PROCEDURES:
Water spray may be inneffective. Water spray may be used to cool containers to prevente pressure build-up
and possible autoignition or explosion when exposed to extreme heat. If water is used, fog nozzles are
preferrable. Fire fighters should wear self contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Keep containers tighty closed. Isolate from heat, electrical equipment, sparks, and open flames. Closed
containers may explode when exposed to extreme heat. Do not apply on hot surfaces. Do no weld on or
near container. Toxic gases may form when product is contacted by flame or hot surfaces.
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SECTION V - REACTIVITY DATA
STABILITY: The product is unstable (nitrocellulose).
HAZARDOUS DECOMP. OR BYPRODUCTS: May produce hazardous decomposion products when
heated. Welding, brazing, or flame-cutting on surfaces coated with this product may produce fumes
including: Carbon Monoxide or Carbon Dioxide.
PRODUCTS OF DEGRADATION: Possible hazardous short term degradation products are not likely.
However, long term degradation products may arise. The products of degradation are less toxic than the
product itself.
CORROSIVITY: Not considered corrosive for metal and glass.
REACTIVITY: Highly reactive with oxidizing agents. Reactive with reducing agents, organic materials,
metals, acids, alkalis, moisture. Non-reactive with combustible materials.
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SECTION VI - HEALTH HAZARD DATA
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Vapor and spray mist may be harmful if inhaled. Vapor irritates eyes, nose, and throat. Repeated exposure
to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous
system damage. Intentional misuse by deliberatly inhaling the contents can be harmful or fatal.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Eye contact: causes eye irritation. May be harmful if absorbed through the skin. Dryness, itching, cracking,
burning, redness, and swelling are conditions associated with excessive skin contact.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Harmful or fatal if swallowed.
HEALTH HAZARDS (ACUTE AND CHRONIC): Avoid long term and repeated contact.
EMERGENCY AND FIRST AID PROCEDURES: INGESTION: If swallowed, do not induce vomiting.
EYES: In case of eye contact, flush eyes immidiately with plenty of water for at least 15 minutes.
SKIN: In case of skin contact, remove promptly by wiping, followed by waterless handcleaner and soap and
water. INHALATION: If affected by inhalation of vapor or spray mist, remove to fresh air. Apply artificial
respiration and other supportive measures as required. Get medical attention.
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SECTION VII - PREVENTIVE MEASURES
WASTE DISPOSAL: Waste material must be disposed of in accordance with Federal, Provincial, and
Local enviromental control regulations. Empty containers should be recycled or disposed of through an
approved waste management facility.
STORAGE: Do not store above 48 deg. C. Keep in a cool well-ventilated place. Highly toxic materials
should be stored in a separate locked safety cabinet or room.
PRECAUTIONS: Keep locked up. Keep away form sources of ignition. Do not ingest. Do not breath fumes
or vapor or spray. Take precautionary measures against electrostatic discharges. In case of insufficient
ventilation , wear suitable respiratory equipement. If ingested, seek medical advice immidiately. Avoid
contact with eyes and skin. Keep away from incompatibles such as oxidizing agents, reducing agents,
organic materials, metals, acids, alkalis, moisture.
SPILLS OR LEAKS.
Small spill or leak. Absorb with an inert material and put the spilled material in an appropraite waste disposal
container.
Large spill or leak. Provide maximum ventilation. Only personnel equipped with proper respiratory
equipement should be permitted in the area. Remove all sourced of ignition. Stop leak if without risk.
Absorb with DRY earth, sand, or other non-combustible material. Do not touch spilled material. Prevent
entry into sewers, basements or other confined areas. Call local authorities for assistance on disposal.
PROTECTIVE CLOTHING IN CASE OF SPILL: Splash goggles. Full suit. Vapor and dust respirator. Boots.
Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficent, consult a specialist BEFORE handling this product.
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SECTION VIII - PROTECTIVE MEASURES
RESPIRATORY PROTECTION:
Overexposure to vapors may be prevented by ensuring ventilation controls, vapor exhaust or fresh air entry.
If TLV of any component is exceeded, use an appropriate NIOSH / MSHA approved respirator. Follow
respirator manufacturers directions for respirator use.
VENTILATION:
Provide sufficent mechanical and or local exhaust ventilation to keep the concentration of ingredients listed
in section II below the lowest exposure limits.
PROTECTIVE GLOVES:
Use impermeable chemical handling gloves for skin protection.
EYE PROTECTION: Use Chemical safety glasses, goggles, faceshields for eye protection.
OTHER PROTECTIVE CLOTHING OR EQUIPEMENT:
Use impermeable aprons and protective clothing whenever possible to prevent skin contact. The use of
head caps whenever possible is strongly recommened. Clean or dicard contaminated cltohing and shoes.
WORK / HYGIENIC PRACTICES
Eye washes and safety showers in the workplace are recommended.
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SECTION IX - DISCLAIMER
The information and recommendations contained herein are believed to be accurate at the time of the
preparation or obtained from sources believed to be generaly reliable. DOVER FINISHING PRODUCTS will
not be held liable for claims relating to any party's use of, or reliance on information contained herein,
regardless of whether it is claimed the information is inaccurate.
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