821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 1 - 7
1. Identification of the substance/mixture and of the company/undertaking
Product name 821R Activator For 820R
Product code 821R
Intended use of the substance/preparation
Thinner for professionnal use
Company/Undertaking Identification
Producer/Supplier DuPont Australia Ltd
Street/Box 7 Eden Park Drive
Nat.-Code/Postal code/City Macquarie Park NSW 2113, Australia
Telephone (02) 9923 6111
Telefax (02) 9923 6011
Product Information
Telephone (02) 9923 6111
Emergency Information
Medical Emergency Phone 1800 674 415
Transportation Emergency Phone (02) 9923 6275
For further information, please also consult our Internet site
http://www.dupont.com
2. Hazards identification
Hazardous Substance. Dangerous Goods.
Human health hazards
Classification : Harmful; Irritant; dangerous for the environment; Highly flammable;
Highly flammable. Irritating to respiratory system and skin. Risk of serious damage to eyes. Harmful to aquatic organisms, may
cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause
drowsiness and dizziness.
Special hazard instructions for humans and environment
Keep away from sources of ignition - No smoking. Do not breathe vapour. In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear eye/face protection. In
case of insufficient ventilation, wear suitable respiratory equipment.
3. Composition/information on ingredients
Chemical characterization
mixture of solvents
Hazardous components
CAS-No. Chemical Name Concentration Classification
78-83-1 iso-butanol 45.00 - < 55.00 % R10
Xi; R37/38
Xi; R41
R67
67-64-1 acetone 25.00 - < 35.00 % Xi; R36
R66
R67
F; R11
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Copyright 2009 E. I. du Pont de Nemours and Company. All rights reserved. Copies may be made only for those using du Pont products.
821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 2 - 7
CAS-No. Chemical Name Concentration Classification
64742-49-0 naphtha (petroleum), hydrotreated light 20.00 - < 25.00 % F; R11
(<0,1% benzene) Xi; R38
N; R51/53
Xn; R65
R67
NotaH
NotaP
Additional advice
See full text of R-phrases in chapter 16.
4. First aid measures
General advice
When symptoms persist or in all cases of doubt seek medical advice. Never give anything by mouth to an unconscious person.
Inhalation
Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or
stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist,
call a physician.
Skin contact
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or
use recognized skin cleanser. If skin irritation persists, call a physician.
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek
medical advice.
Ingestion
If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. Keep at rest.
5. Fire-fighting measures
Hazardous combustion products
Fire will produce dense black smoke containing hazardous combustion products (see heading 10). Exposure to decomposition
products may be a hazard to health.
Fire and Explosion Hazards
Flammable liquid. Vapours may form explosive mixtures with air. Remove all sources of ignition.
Suitable extinguishing media
Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical, Water spray.
Extinguishing media which shall not be used for safety reasons
High volume water jet
Special Protective Equipment and Fire Fighting Procedures
Wear as appropriate: Full protective flameproof clothing. Wear self contained breathing apparatus for fire fighting if necessary. In
the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter drains or water courses.
Additional advice
Cool closed containers exposed to fire with water spray.
Additional information
Hazchem : 3YE
6. Accidental release measures
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821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 3 - 7
Personal precautions
Keep in a well-ventilated place. Keep away from sources of ignition. Comply with safety directives (see chapters 7 and 8). Do not
inhale vapours.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of
rivers, lakes or waste water systems.
Methods for cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations. Clean preferably with a detergent; avoid use of solvents.
7. Handling and storage
Safe handling advice
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the
occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition
have been excluded. Preparation may charge electrostatically: always use grounded leads when transferring from one container
to another. Operators should wear antistatic footwear and clothing. No sparking tools should be used. Avoid skin and eye
contact. Do not breathe vapours or spray mist. Smoking, eating and drinking should be prohibited in the application area. For
personal protection see section 8. Comply with the health and safety at work laws. If material is a coating, do not sand, flame
cut, braze or weld dry coating without an appropriate respirator or appropriate ventilation, and gloves.
Advice on protection against fire and explosion
Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Never use
pressure to empty container: container is not a pressure vessel. Always keep in containers of same material as the original one.
Storage
Requirements for storage areas and containers
Observe label precautions. Store between 5 and 25 C in a dry, well ventilated place away from sources of heat, ignition and
direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Advice on common storage
Store separately from oxidizing agents and strongly alkaline and strongly acidic materials.
8. Exposure controls/personal protection
Additional technical information on the plant
Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasible- by the use of a
local exhaust ventilation. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL,
suitable respiratory protection must be worn.
National occupational exposure limits
CAS-No. Chemical Name Values Control Parameters Basis
78-83-1 iso-butanol TWA 152 mg/m3 NOHSC:1003(2003)
50 ppm NOHSC:1003(2003)
67-64-1 acetone STEL 2,375 mg/m3 NOHSC:1003(2003)
1,000 ppm NOHSC:1003(2003)
TWA 1,185 mg/m3 NOHSC:1003(2003)
500 ppm NOHSC:1003(2003)
64742-49-0 naphtha (petroleum), hy- no exposure standard allocated
drotreated light (<0,1%
benzene)
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
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821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
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Hand protection
The breakthrough time of gloves is unknown for the product itself. The glove material given is recommended on basis of the
substances in the preparation.
Glove material Glove thickness Break through time
Nitrile rubber 0.33 mm 60 min
The protective glove should be checked in each case for their work specific suitability (e.g. mechanical stability, product
compatibility, and anti-static properties). When the intended use is for spray application a nitrile glove of the chemical resistance
group 3 (e.g. Dermatril R glove) is to be used. After contamination, the glove has to be changed. If immersing the hands into the
product is not avoidable (e.g. maintenance work) a butyl or fluorocarbon rubber glove should be used. When skin exposure may
occur to materials specified in section 3 of this SDS, advice should be sought from the glove supplier as to appropriate type to
use with this product and the permeation breakthrough times. Care should be taken when working with sharp edged articles as
these can easily damage the gloves and make them ineffective. The instructions and information provided by the glove supplier
on use, storage, maintenance and replacement must be followed. Damaged gloves or those showing signs of wear should be
replaced immediately.
Eye protection
Wear protective eyewear for protection against solvent spatter.
Skin and body protection
Wear suitable protective clothing. Personnel should wear antistatic clothings made of natural fiber or of high temperature
resistant synthetic fiber.
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do not use organic solvents!
Environmental exposure controls
Do not let product enter drains. For ecological information refer to section 12.
9. Physical and chemical properties
Appearance
Form: liquid Colour: clear
Important physical and chemical information
Value Method
-15 C
Flash point
220 C
Ignition temperature DIN 51794
56 C
Boiling point/boiling range
Lower explosion limit 0.8 %
Upper explosion limit 12.8 %
Vapour pressure 78.0 hPa
0.79 g/cm3
Relative density DIN 53217/ISO 2811
Water solubility appreciable
Viscosity (23 C) <20 s ISO 2431-1993 6 mm
Solvent separation test < 3% ADR/RID
Content of volatile components (including water) 99.0% Basis Vapour pressure >= 0.01 kPa
pH Not applicable.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
Materials to avoid
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide,
smoke, oxides of nitrogen.
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Copyright 2009 E. I. du Pont de Nemours and Company. All rights reserved. Copies may be made only for those using du Pont products.
821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 5 - 7
11. Toxicological information
General observations
There is no data available on the product. See sections 3 and 15 for details.
Practical experience
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse
health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous
system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss
of consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged
contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and
absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.
Toxicity Test Type Value Time Species
iso-butanol
Oral LD50 5.5 ml/kg Female Rat
Dermal LD50 2,460 mg/kg rabbit
Inhalation LC50 8,000 ppm rat
Percutaneous LD50 2.5 ml/kg rabbit
acetone
Oral LD50 5,800 mg/kg rat
Dermal LD50 20 g/kg rabbit
Inhalation LC50 50.1 g/m3 8h rat
naphtha (petroleum), hydrotreated light (<0,1% benzene)
Oral LD50 > 5,000 mg/kg rat
Dermal LD50 > 3,160 mg/kg rabbit
Inhalation LC50 > 12 mg/l 6h rat
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. Product
does not contain organic linked halogens contributing to AOX.
Mobility
No information available.
Persistence and degradability
No information available.
Bioaccumulative potential
No information available.
13. Disposal considerations
Incinerate or otherwise dispose of waste material in accordance with local regulations. The product should not be allowed to
enter drains, water courses or the soil. Do not incinerate in closed containers.
14. Transport information
Transport in accordance with the requirements of the Carriage of Dangerous Goods by Road and Rail (Classifications,
Packaging and Labeling), ADG for road, IMDG for sea and ICAO/IATA for air transport.
ADG (Land transport)
Proper shipping name: PAINT RELATED MATERIAL
UN-Number: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Hazchem: 3YE
IMDG (Sea transport)
Proper shipping name: PAINT RELATED MATERIAL
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Copyright 2009 E. I. du Pont de Nemours and Company. All rights reserved. Copies may be made only for those using du Pont products.
821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 6 - 7
UN-Number: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
Marine Pollutant: N
EmS: F-E,S-E
ICAO/IATA (Air transport)
Proper shipping name: PAINT RELATED MATERIAL
UN-Number: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: II
15. Regulatory information
Symbol and indication of hazard.
F Highly flammable
Xn Harmful
Contains iso-butanol 45.00 - < 55.00 %; acetone 25.00 - < 35.00 %; naphtha (petroleum), hy-
drotreated light (<0,1% benzene) 20.00 - < 25.00 %.
R-phrase(s)
R11 Highly flammable.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic envi-
ronment.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
S-phrase(s)
S16 Keep away from sources of ignition - No smoking.
S23 Do not breathe vapour.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S33 Take precautionary measures against static discharges.
S39 Wear eye/face protection.
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
Standard for the Uniform Scheduling of Drugs and Poisons.
Schedule 5
16. Other information
Full text of R phrases with no. appearing in section 3
R10 Flammable.
R11 Highly flammable.
R36 Irritating to eyes.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environ-
ment.
R65 Harmful: may cause lung damage if swallowed.
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821R v2.0
SAFETY DATA SHEET Revision Date: 2009-10-06
Print Date: 2009-10-15
en/AU Page 7 - 7
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Sources of key data used to compile the datasheet:
1. National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition (NOHSC:2011(2003))
2. Approved Criteria for Classifying Hazardous Substances (NOHSC:1008(1999))
3. List of Designated Hazardous Substances (NOHSC:10005(1999))
4. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment (NOHSC:1003(1995))
5. Australian Dangerous Goods Code, No. 6 (National Road Transport Commission)
6. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP)
7. National Code of Practice for the Labelling of Workplace Substances ((NOHSC:2012 (1994))
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.
Report version
Version Changes
2.0 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16
Revision Date: 2009-10-06
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Copyright 2009 E. I. du Pont de Nemours and Company. All rights reserved. Copies may be made only for those using du Pont products.
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