Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 1/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name TRIUMPH
Product code (UVP) 06472656
Usage herbicide
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC)
Fenoxaprop-P-ethyl/Mefenpyr-diethyl 120:33 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Fenoxaprop-P-ethyl 71283-80-2 Xi, N R43, R50 12.00
Solvent Naphtha (petroleum), 64742-94-5 Xn, N R51/53, R65, > 40.00
heavy aromatic 265-198-5 R66
Fatty alcohol polyglycol ether 9043-30-5 Xn, N R22, R41, > 1.00 - < 25.00
R51/53
2-Methylpropan-1-ol 78-83-1 Xi R10, R37/38, > 1.00 - < 5.00
201-148-0 R41, R67
Tetrapropylene benzene 11117-11-6 C R21, R34, > 1.00 - < 5.00
sulfonate, calcium salt 234-360-7 R52/53
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Irritating to eyes and skin.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Move out of dangerous area. Remove contaminated clothing immediately and dispose of safely.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 2/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Inhalation
If symptoms persist, call a physician. Move to fresh air. Keep patient warm and at rest.
Skin contact
Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400,
subsequently rinse with water. If symptoms persist, call a physician.
Eye contact
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also
under the eyelids, for at least 15 minutes. Get medical attention if irritation develops and
persists.
Notes to Physician
Symptoms
Local:, irritation
Symptoms
Systemic:, To date no symptoms are known.
Treatment
Treat symptomatically.
Gastric lavage is not normally required. If a significant amount (more than a mouthful) has been
ingested, administer activated charcoal and sodium sulphate.
There is no specific antidote.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray
alcohol-resistant foam
carbon dioxide (CO2)
dry powder
Extinguishing media which must not be used for safety reasons
high volume water jet
Specific hazards during fire fighting
In the event of fire the following can be released:
carbon monoxide (CO)
nitrogen oxides (NOx)
Sulphur oxides
hydrogen chloride (HCl)
Special protective equipment for fire-fighters
Wear full protective suit.
In the event of fire, wear self-contained breathing apparatus.
Further information
Remove product from areas of fire, or otherwise cool containers with water in order to avoid
pressure being built up due to heat.
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
6. ACCIDENTAL RELEASE MEASURES
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 3/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Personal Precautions
Evacuate personnel to safe areas.
Use personal protective equipment.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Sweep up or vacuum up spillage and collect in suitable container for disposal.
Additional Advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
The product is combustible.
Keep away from sources of ignition - No smoking.
Storage
Requirements for storage areas and containers
Store in original container.
Keep tightly closed in a dry, cool and well-ventilated place.
Keep away from direct sunlight.
Keep away from heat.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage period > 24 Months
Storage temperature 20 - 30 癈
Other data Storage temperature should ideally lie between 0 and 30 癈,
however, storage for two weeks at 54 癈 has shown no adverse
effects regarding product safety or stability.
Suitable materials
Coextruded containers with an internal barrier layer made of ethylene vinyl alcohol copolymer
(EVOH)
Coextruded containers with an internal barrier layer made of polyamide (PA).
Black mild steel sheet with interior coating
Tinplate with interior lacquer
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 4/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
2-Methylpropan-1-ol 78-83-1 154 mg/m3 / 50 ppm 2005 EH40 WEL
(TWA)
2-Methylpropan-1-ol 78-83-1 231 mg/m3 / 75 ppm 2005 EH40 WEL
(STEL)
Engineering measures
See section 7; no measures exceeding those mentioned are necessary.
Personal protective equipment
Respiratory Protection Wear respirator conforming to EN140 type A filter.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and Type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
Hygiene measures
When using, do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Protective measures
Avoid contact with skin and eyes.
Do not inhale aerosols.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid
Colour light brown
Odour aromatic
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 5/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Safety data
pH 5.5 - 8.0 at 10 % (23 癈)
Flash Point ca. 74 癈
Autoignition Temperature ca. 435 癈
Density ca. 1.030 g/cm?at 20 癈
Viscosity, kinematic ca. 9.8 mm2/s at 40 癈
Surface tension ca. 32.5 mN/m at 40 癈
Impact Sensitivity not impact-sensitive
Oxidizing properties No oxidizing properties
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid None.
Thermal decomposition no data available
Hazardous Reactions None known.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) 3,254 mg/kg
Acute Inhalation Toxicity LC50 (rat) > 5.45 mg/l
Exposure time: 4 h
Acute Dermal Toxicity LD50 (rat) > 5,000 mg/kg
Skin Irritation irritating (rabbit)
Eye Irritation irritating (rabbit)
Sensitization Non-sensitizing. (guinea pig)
OECD Test Guideline 406, Buehler test
Further information
The toxicological data refer to a similar formulation.
12. ECOLOGICAL INFORMATION
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 6/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 1.9 mg/l
Exposure time: 96 h
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 4.2 mg/l
Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) 1.47 mg/l
Exposure time: 72 h
Further information on ecology
Additional ecological information
Non-hazardous for bees.
The ecotoxicological data refer to a similar formulation.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(FENOXAPROP-P-ETHYL, SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC SOLUTION)
IMDG
UN-No 3082
Class 9
Packaging group III
EmS F-A , S-F
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 7/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FENOXAPROP-P-ETHYL, SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC SOLUTION )
IATA
UN-No 3082
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FENOXAPROP-P-ETHYL, SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC SOLUTION )
UK 'Carriage' Regulations
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Emergency action code 3Z
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(FENOXAPROP-P-ETHYL, SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC SOLUTION)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Hazard warning labelling compulsory
Hazardous components which must be listed on the label:
?Fenoxaprop-P-ethyl
Symbol(s)
Xi Irritant
N Dangerous for the environment
R-phrase(s)
R36/38 Irritating to eyes and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S35 This material and its container must be disposed of in a safe way.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
Contains fenoxaprop-P-ethyl. May produce an allergic reaction.
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
TRIUMPH 8/8
Version 1 / GB Revision Date: 08.05.2006
102000011514 Print Date: 14.07.2008
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R10 Flammable.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R34 Causes burns.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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