Material Safety Data Sheet CS: 1.4.20
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PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
40930 SIGMA PHENGUARD 930 BASE
Product Name
PPG INDUSTRIES AUSTRALIA PTY LTD (ABN 82 055 500 939)
Company Name
Address McNaughton Road Clayton
Victoria 3168 Australia
1800 033111 (24hr)
Emergency Tel.
Tel: (03) 9263 6000
Telephone/Fax
Fax: (03) 9263 6970
Number
jchapman@ppg.com
Email
Solvent-based, two-component coating base.
Recommended Use
Other Information This MSDS summarises at the date of issue our best knowledge of the health and
safety hazard information of the product, and in particular how to safely
handle and use the product in the workplace. Since PPG Industries Australia
Pty Limited cannot anticipate or control the conditions under which the
product may be used, each user must, prior to usage, review this MSDS in the
context of how the user intends to handle and use the product in the
workplace.
If clarification or further information is needed to ensure that an
appropriate assessment can be made, the user should contact this company.
Our responsibility for product as sold is subject to our standard terms and
conditions, a copy of which is sent to our customers and is also available
upon request.
2. HAZARDS IDENTIFICATION
Classified as Hazardous according to criteria of National Occupational Health
Hazard
& Safety Commission (NOHSC), Australia.
Classification
Classified as Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail.
Risk Phrase(s) R10 Flammable.
R20 Harmful by inhalation.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Safety Phrase(s) S16 Keep away from sources of ignition - No smoking.
S23(2) Do not breathe vapour.
S23(3) Do not breathe spray.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S61 Avoid release to the environment. Refer to special instructions/safety
data sheet.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS Proportion
Ingredients
28064-14-4 10-<25 %
Epoxy Novolac
Resin
Xylene 1330-20-7 10-<12.5 %
Isobutanol 78-83-1 1-<5 %
Ethyl benzene 100-41-4 1-<2.5 %
Balance
Ingredients
determined to be
not hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not
breathing. Seek medical attention.
Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Seek medical
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Material Safety Data Sheet CS: 1.4.20
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PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
attention.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin
and hair with running water. Remove contaminated clothing and wash before
reuse or discard. Seek medical attention.
Eye If in eyes, hold eyelids apart and flush the eye continuously with running
water. Continue flushing until advised to stop by the Poisons Information
Centre or a doctor, or for at least 15 minutes. Take care not to rinse
contaminated water into the non-affected eye. Seek medical attention.
Eye wash and normal washroom facilities.
First Aid Facilities
Treat symptomatically.
Advice to Doctor
Other Information For advice, contact a Poisons Information Centre (Phone eg Australia 131 126;
New Zealand 0800 764 766) or a doctor (at once).
5. FIRE FIGHTING MEASURES
Foam, carbon dioxide or dry chemical powder.
Suitable
Extinguishing Media
Under fire conditions this product may emit toxic and/or irritating fumes,
Hazards from
smoke and gases including carbon monoxide and nitrogen oxides.
Combustion
Products
Specific Methods Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) and full
protective clothing to prevent exposure to vapours, fumes or products of
combustion. Prevent spillage from entering drains or water courses. Keep
containers cool with water spray.
Specific Hazards This product is flammable. Keep storage tanks, pipelines, fire-exposed
surfaces etc cool with water spray. Shut off any leak if safe to do so and
remove sources of re-ignition. Vapour/air mixtures may ignite explosively.
Flashback along the vapour trail may occur. Runoff to sewer may create fire or
explosion hazard.
3[Y]
Hazchem Code
Fire-fighters should wear full protective clothing and self contained
Precautions in
breathing apparatus (SCBA) operated in positive pressure mode. Water spray may
connection with Fire
be used to keep fire exposed containers cool.
6. ACCIDENTAL RELEASE MEASURES
Exclude sources of ignition and ventilate the area. Clear area of all
Emergency
unprotected personnel. Slippery when spilled. Avoid accidents, clean up
Procedures
immediately. Wear protective equipment to prevent skin and eye exposure and
inhalation of vapours. Contain - prevent run off into drains and waterways.
Use absorbent (soil, sand or other non-combustible material). Collect and seal
in properly labelled containers for disposal. If contamination of sewers or
waterways occurs inform the local water authorities and EPA in accordance with
local regulations.
7. HANDLING AND STORAGE
Avoid skin and eye contact, and inhalation of vapours when mixing and handling
Precautions for Safe
paint. Wear overalls, impervious gloves and approved respirator. Use in
Handling
designated areas with adequate ventilation. Use approved flammable liquid
storage containers in the work area. Electrical equipment must be protected to
the appropriate standard. Preparation may charge electrostatically: always use
earthing leads when
transferring from one container to another. Operators should wear antistatic
footwear and clothing and floors should be of the conducting type. Isolate
from sources of heat, sparks and open flame. No sparking tools should be used.
Prevent release of vapours and mists into workplace air. Keep containers
closed when not in use. Take precautionary measures against static discharges.
Keep material away from sparks, flames and other ignition sources. Do not
empty into drains. Ensure a high level of personal hygiene is maintained when
using this product, that is, always wash hands before eating, drinking,
smoking or using the toilet facilities.
Observe label precautions. Prevent unauthorized access. Containers which are
Conditions for Safe
opened must be carefully resealed and kept upright to prevent leakage. Store
Storage
between 5 and 25癈 in a dry, well ventilated place away from sources of heat,
ignition and direct sunlight. Store away from strong oxidising agents, acids
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Material Safety Data Sheet CS: 1.4.20
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PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
and bases. Keep containers closed at all times - check regularly for leaks.
For information on the design of the storeroom reference should be made to
Australian Standard AS1940, The storage and handling of flammable and
combustible liquids. Reference should also be made to any applicable national
and local regulations.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No exposure standards have been established for this material by the National
National Exposure
Occupational Health And Safety Commission (NOHSC), Australia. However,
Standards
over-exposure to some chemicals may result in enhancement of pre-existing
adverse medical conditions and/or allergic reactions and should be kept to the
least possible levels.
The available Exposure Standards for constituents are as follows:
TWA STEL NOTICES
ppm mg/m3 ppm mg/m3
Isobutanol 50 152 - - -
Xylene 80 350 150 655 -
Ethyl Benzene 100 434 125 543 -
TWA (Time Weighted Average): The average airborne concentration of a
particular substance when calculated over a normal eight-hour working day, for
a five-day week.
STEL (Short Term Exposure Limit): The average airborne concentration over a 15
minute period which should not be exceeded at any time during a normal
eight-hour workday.
No Biological limit allocated.
Biological Limit
Values
Ventilation should be adequate to control the air concentrations of components
Engineering
below quoted exposure standards. A local exhaust ventilation system, drawing
Controls
vapours/mists away from workers breathing zone, should be used. The
ventilation system must be suitable for use with flammable liquids. The spray
applications require the use of a spray booth that comply with local
regulations.
If engineering controls are not effective in controlling airborne exposure
Respiratory
then an approved respirator with a replaceable vapour/mist filter should be
Protection
used. Reference should be made to Australian/New Zealand Standards AS/NZS
1715, Selection, Use and Maintenance of Respiratory Protective Devices; and
AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary
changes for individual circumstances.
Eye Protection Safety glasses with side shields or chemical goggles should be worn. Final
choice of appropriate eye/face protection will vary according to individual
circumstances. Eye protection devices should conform with Australian/New
Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Hand Protection Wear laminated film, Viton, nitrile or other suitable gloves conforming to
AS/NZS 2161: Occupational protective gloves.
Note:
When prolonged or frequently repeated contact may occur, a glove with a
protection class of 6 (breakthrough time greater than 480 minutes according to
EN 374) is recommended. When only brief contact is expected, a glove with a
protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended. The selection of a specific glove
for a particular application and duration of use in a workplace should also
take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled,physical requirements (cut/puncture
protection, dexterity, thermal protection), potential body reactions to
glovematerials, as wellas the instructions/specifications provided by the
glove supplier.
Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist.
Working clothes must not consist of textiles, which show a dangerous melting
behaviour in case of fire. Industrial clothing should conform to the
specifications detailed in AS/NZS 2919: Industrial clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Viscous liquid
Appearance
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Material Safety Data Sheet CS: 1.4.20
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PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
Characteristic odour
Odour
Not available
Melting Point
Not available
Boiling Point
Immiscible
Solubility in Water
Not available
pH Value
Not available
Vapour Pressure
Not available
Vapour Density
(Air=1)
Viscosity 2,500 mPa.s @ 23 癈
Flow time : >= 60 s (Method: ISO 2431 (EN 535) 6 mm Cup)
Various
Colour
1.67 g/cm?@ 20癈
Density
23.7癈
Flash Point
Flammability FLAMMABLE. This product should be stored and used in a well ventilated area
away from naked flames, sparks and other sources of ignition. Electrically
link and ground metal containers for transfers of the product to prevent
accumulation of static electricity. Keep the container tightly closed.
>399癈
Auto-Ignition
Temperature
1.08% v/v
Flammable Limits -
Lower
7.74% v/v
Flammable Limits -
Upper
10. STABILITY AND REACTIVITY
Stable under normal conditions of use and storage.
Chemical Stability
Conditions to Avoid Heat(Avoid temperatures above 60癈), direct sunlight, open flames or other
sources of ignition.
Oxidising agents, strong acids and strong bases.
Incompatible
Materials
Thermal decomposition and combustion produce noxious fumes containing oxides
Hazardous
of carbon and oxides of nitrogen.
Decomposition
Products
Will not occur.
Hazardous
Polymerization
11. TOXICOLOGICAL INFORMATION
No toxicology data available for this product.
Toxicology
Information
Inhalation Harmful by inhalation. Inhalation of product vapours will cause irritation of
the nose, throat and respiratory system.
Ingestion Ingestion of this product may irritate the gastric tract causing nausea and
vomiting.
Skin Irritating to skin resulting in redness and itching. This product may cause
sensitisation in some individuals.
Eye Irritating to eyes. On eye contact it will cause pain, tearing, stinging and
blurred vision.
Chronic Effects Prolonged and repeated exposure through skin contact or inhalation of this
material may result in harmful effects on the central nervous system. Chronic
exposure can also cause damage to kidneys and liver. Repeated exposure may
cause skin dryness and dermatitis.
12. ECOLOGICAL INFORMATION
Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Not available
Persistence /
Degradability
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Material Safety Data Sheet CS: 1.4.20
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PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
Not available
Mobility
Not available
Bioaccumulative
Potential
Do not allow product to enter drains, waterways or sewers.
Environ. Protection
13. DISPOSAL CONSIDERATIONS
Disposal of spilled or waste material must be carried out in accordance with
Disposal
the relevant local, state and federal government regulations. Advise flammable
Considerations
nature. Empty containers may contain flammable residues. Do not puncture, cut
or weld empty containers.
14. TRANSPORT INFORMATION
Road and Rail Transport
Transport
Classified as Dangerous Goods by the criteria of the Australian Dangerous
Information
Goods Code (ADG Code) for transport by road or rail.
UN-No: 1263
Class: 3
Hazchem code: 3[Y]
EPG: 3C1
Packing group: III
Proper Shipping Name: PAINT
Segregation Dangerous Goods:
This material is a Class 3 - Flammable Liquid according to The Australian Code
for the Transport of Dangerous Goods by Road and Rail.
Class 3 - Flammable Liquids are incompatible in a placard load with any of the
following:
- Class 1, Explosives
- Class 2.1, Flammable Gases, if both the Class 3 and Class 2.1 dangerous
goods are in bulk
- Class 2.3, Toxic Gases
- Class 4.2 Spontaneously Combustible Substances
- Class 5.1 Oxidising Agents and Class 5.2, Organic Peroxides
- Class 6 Toxic Substances (where the flammable liquid is nitromethane)
- Class 7 Radioactive Substances.
Marine Transport
Classified as Dangerous Goods by the criteria of the International Maritime
Dangerous Goods Code (IMDG Code) for transport by sea.
UN-No: 1263
Class: 3
Tremcard: 3
EmS: F-E, S-E
Packing group: III
Proper Shipping Name: PAINT
Air Transport
Classified as Dangerous Goods by the criteria of the International Air
Transport Association (IATA) Dangerous Goods Regulations for transport by air.
UN-No: 1263
Class: 3
Packing group: III
Proper Shipping Name: PAINT
1263
U.N. Number
PAINT
Proper Shipping
Name
3
DG Class
3[Y]
Hazchem Code
3.8.3RT1
Packaging Method
III
Packing Group
3C1
EPG Number
14
IERG Number
Print Date: 19/03/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
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Page:
PPKFC Issue Date :March 2008
Infosafe NoTM ISSUED by PPGAUST CS: 1.4.20
Product Name :40930 SIGMA PHENGUARD 930 BASE
15. REGULATORY INFORMATION
Classified as Hazardous according to criteria of National Occupational Health
Regulatory
& Safety Commission (NOHSC).
Information
Classified as Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail.
Classified as a Schedule Poison S5 according to the Standard for the Uniform
Scheduling of Drugs and Poisons (SUSDP).
S5
Poisons Schedule
Harmful,Irritant
Hazard Category
16. OTHER INFORMATION
MSDS Created: March 2008
Date of preparation
or last revision of
MSDS
Contact Person/Point
...End Of MSDS...
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Print Date: 19/03/2008 CS: 1.4.20
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