SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name : TRIUMPH
Product code : AE F046360 24 EC15 A3
Specification : 21403
Usage : herbicide
Company : Bayer CropScience Limited
Hauxton
Cambridge
Cambridgeshire CB2 5HU
United Kingdom
Telephone : +44(0)1223 870312
Telefax : +44(0)1223 872142
Emergency telephone : 0800-220876 ( UK only )
number
+44(0)1223-870312
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC), contains:
fenoxaprop-P-ethyl/Mefenpyr-diethyl 120:33 g/l
Hazardous components
Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%]
Fenoxaprop-P-ethyl 71283-80-2 Xi, N R43 11.70
R50
Mefenpyr-diethyl 135590-91-9 N R51/53 3.20
Fatty alcohol polyglycol ether 9043-30-5 Xn, N R41 > 5.00 - < 25.00
R51/53
R22
Tetrapropylene benzene C R34 > 1.00 - < 5.00
sulfonate-Ca-salt R21
R52/53
Iso-butanol 78-83-1 Xi R10 > 1.00 - < 5.00
R37/38
R41
R67
Solvent naphtha (petroleum), Xn, N R65 > 50.00
heavy arom. R66
R51/53
1/9 Print Date 20.03.2003
SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Irritating to eyes and skin.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice : Remove contaminated, soaked clothing immediately and
dispose of safely.
Inhalation : Move the patient to fresh air and keep at rest. If symptoms
persist, call a physician.
Skin contact : Take off all contaminated clothing immediately. Wash off
immediately with soap and plenty of water. If symptoms persist,
call a physician.
Eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Ingestion : Do not induce vomiting. Rinse mouth thoroughly with water.
Give small amounts of water to drink If symptoms persist, call a
physician.
Notes to physician
Symptoms : Local:, irritant effects
Symptoms : Systemic:, To date no symptoms are known.
Treatment : Local treatment:
Treat symptomatically.
Treatment : Systemic treatment:
In the event of a mouthful or more being ingested, the following
measures should be considered:
Monitoring of: kidney, liver and red blood cell count.
Observe specific parameters: blood lipids and cholesterol for
hypolipidaemia and lowered cholesterol.
Gastric lavage, then charcoal (carbo medicalis) and sodium
sulfate.
Elimination by dialysis (forced alkaline diuresis).
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : water spray jet
media carbon dioxide (CO2)
dry powder
alcohol-resistant foam
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SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
Specific hazards during fire : In the event of fire the following can be released:
fighting carbon dioxide (CO2)
carbon monoxide (CO)
nitrogen oxides (NOx)
sulphur oxides
hydrogen chloride (HCl)
Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters Wear full protective suit.
Further information : Remove product from areas of fire, or otherwise cool
containers with water in order to avoid pressure being built up
due to heat.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use personal protective equipment.
Evacuate personnel to safe areas.
Environmental precautions : Keep people and animals away.
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local
water company immediately.
If spillage enters rivers or watercourses, inform the
Environment Agency (emergency telephone number 0800
807060).
Methods for cleaning up : Take up with absorbent material (e.g. sand, earth or a
proprietary absorbent material).
Take up mechanically and collect in suitable container for
disposal.
Additional advice : Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see
section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on protection : The product is combustible.
against fire and explosion Keep away from sources of ignition - No smoking.
Advice on protection : The product neither sensitive to impacts nor to rub effects and
against fire and explosion therefore not explosive.
Storage
3/9 Print Date 20.03.2003
SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated
areas and containers place.
Further information on : The storage temperature should lie between 0 癈 and 30 癈,
storage conditions maximum up to 50 癈.
Keep away from direct sunlight.
Protect against frost.
Advice on common storage : Keep away from food, drink and animal feedingstuffs.
Storage period : > 24 Months
Storage temperature : 20 - 30 癈
Suitable materials : glass bottles
Polyamid innerlined polyethylene (coex) bottles
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of substances Hazardous to Health Regulations 1999 as
amended). Engineering controls should be used in preference to personal protective equipment
wherever practicable.
Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
Iso-butanol 78-83-1 154 mg/m3 (TWA) 2001 EH40 OES
231 mg/m3 (STEL) 2001 EH40 OES
Additional advice : Observe: Exposure Limits In Air, Gp3 200mg/m?50ppm.
(aromatic-rich hydrocarbon mixes with > 25% aromatics TRGS
901, No. 72)
Engineering measures
See chapter 7; no measures exceeding those mentioned are necessary.
Personal protective equipment
Respiratory protection : Respiratory protection mask with combination filter A/P2
Hand protection : PVC disposable gloves
solvent-resistant gloves
Eye protection : safety glasses / face shield
Skin and body protection : Light protective clothing, PVC
Hygiene measures : When using, do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Protective measures : Avoid contact with skin and eyes.
4/9 Print Date 20.03.2003
SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form : liquid
Colour : yellowish
Odour : aromatic
Safety data
pH : 6.7
Note: Determined as a 1% emulsion in distilled water.
Flash point : ca. 72 癈
Method: closed cup
Autoignition temperature : 435 癈
Density : ca. 1.04 g/cm3 at 20 癈
Water solubility : Note: emulsifiable
: POW: 6,783
Partition coefficient (n-
log Pow: 3.83
octanol/water)
at: 21 癈Note: The value mentioned relates to the active
ingredient mefenpyr-diethyl.
Viscosity, kinematic : ca. 9.8 mm2/s at 40 癈
Surface tension : 32.5 mN/m at 40 癈
Impact Sensitivity : Not impact-sensitive
10 kg at 0.4 m
Other information : On the basis of the chemical structure of the substance it may
be assumed that the substance has no oxidising properties.
The substance has no functional groups that could have an
oxidising effect.
10. STABILITY AND REACTIVITY
Hazardous reactions : Note: Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 (rat) 3,254 mg/kg
Acute inhalation toxicity : LC50 (rat) > 5.45 mg/l
Exposure time: 4 h
Acute dermal toxicity : LD50 (rat) > 5,000 mg/kg
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SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
Skin irritation : rabbit
Result: Irritating to skin.
Eye irritation : rabbit
Result: Irritating to eyes.
Sensitization : guinea pig
Result: non-sensitizing
Method: OECD 406, Buehler test
Further information : The toxicological data refer to a similar formulation.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to fish : LC50: 1.9 mg/l
Oncorhynchus mykiss (Rainbow trout)
Exposure time: 96 h
Toxicity to daphnia : EC50: 4.2 mg/l
Water flea (Daphnia magna)
Exposure time: 48 h
Toxicity to algae : EC50: 0.9 mg/l
Selenastrum capricornutum
Exposure time: 120 h
Toxicity to algae : EC50: 0.75 mg/l
Selenastrum capricornutum
Exposure time: 72 h
Further information on ecology
Additional ecological : Non-hazardous for Bees.
information
Additional ecological : The ecotoxicological data refer to a similar formulation.
information
13. DISPOSAL CONSIDERATIONS
Product : In accordance with current regulations may be taken to waste
disposal site or incineration plant, after consultation with site
operator and/or with the responsible authority
Can be landfilled or incinerated, when in compliance with local
regulations.
Advice may be obtained from the local waste regulation
authority (part of the Environment Agency in the UK).
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as
product waste.
Empty containers can be landfilled, when in compliance with
6/9 Print Date 20.03.2003
SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
the Environmental Protection (Duty of Care) Regulations 1991.
14. TRANSPORT INFORMATION
ADR/RID 3082
: UN-No
Class 9
Packaging group III
Hazard no. 90
Description of the goods 3082 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S.
( FENOXAPROP-P-ETHYL/SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC )
ADNR 3082
: UN-No
Class 9
Item 11
Letter c
Description of the goods 3082 Environmentally hazardous substance, liquid,
n.o.s.
( FENOXAPROP-P-ETHYL/SOLVENT NAPHTHA
(PETROLEUM) HEAVY AROMATIC )
IMDG 3082
: UN-No
Class 9
Packaging group III
EmS NONE
Marine pollutant P
Description of the goods ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S.
( FENOXAPROP-P-ETHYL 11.7%/SOLVENT
NAPHTHA (PETROLEUM) HEAVY AROMATIC )
IATA 3082
: UN-No
Class 9
Packaging group III
Description of the goods Environmentally hazardous substance, liquid,
n.o.s.
( FENOXAPROP-P-ETHYL 11.7%/SOLVENT
NAPHTHA (PETROLEUM) HEAVY AROMATIC )
7/9 Print Date 20.03.2003
SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
CDG CPL : UN-No 3082
Class 9
Packaging group III
Hazard identification number 90
Emergency action code 2X
Proper shipping name ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (FENOXAPROP-P-
ETHYL/SOLVENT NAPHTHA (PETROLEUM)
HEAVY AROMATIC)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3.
Hazardous components which must be listed on the label:
?Fenoxaprop-P-ethyl
?Mefenpyr-diethyl
Symbol(s): : Xi Irritant
N Dangerous for the environment
R-phrase(s) : R36/38 Irritating to eyes and skin.
R50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
S-phrase(s) : S35 This material and its container must be
disposed of in a safe way.
S57 Use appropriate containment to avoid
environmental contamination.
Exceptional labelling of : Restricted to professional users.
special preparations To avoid risks to man and the environment, comply with the
instructions for use.
Contains Fenoxaprop-P-ethyl. May produce an allergic
reaction.
Further information : WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R10 Flammable.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
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SAFETY DATA SHEET according to EC Directive 2001/58/EC
Bayer CropScience
TRIUMPH
Version 2 GB
102000000828
Revision Date 20.03.2003
R34 Causes burns.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or
policy in force or arising from any risk assessment involving the substance or product should
take precedence over any of the guidance contained in this safety data sheet where there is a
difference in the information given.
The information provided in this safety data sheet is accurate at the date of publication and will
be updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take
account of information or advice contained in this safety data sheet.
Changes since the last version will be highlighted in the margin. This version replaces all
previous versions.
9/9 Print Date 20.03.2003
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