Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 1/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name K-OBIOL EC275 12X1L BOT GB
Product code (UVP) 05939488
Usage insecticide
Company Bayer Environmental Science
16, rue Jean-Marie Leclair
69009 Lyon
France
Emergency telephone number +33(0)4.72.85.25.25
Telefax +33(0)4.72.85.27.99
Num閞o INRS +33(0)1.45.42.59.59
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Emulsifiable concentrate (EC)
Deltamethrin/Piperonyl butoxide 25:250 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Deltamethrin 52918-63-5 T, N R23/25, 2,70
258-256-6 R50/53
Piperonyl butoxide 51-03-6 N R50/53 23,90
200-076-7
Tetrapropylene benzene 11117-11-6 C R21, R34, > 1,00 - < 5,00
sulfonate, calcium salt 234-360-7 R52/53
2-Methylpropan-1-ol 78-83-1 Xi R10, R37/38, > 1,00 - < 5,00
201-148-0 R41, R67
Solvent Naphtha (petroleum), 64742-95-6 Xn, N R10, R37, > 50,00
light aromatic R51/53, R65,
R66, R67
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Flammable.
Harmful by inhalation and if swallowed.
Irritating to respiratory system.
Risk of serious damage to eyes.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
4. FIRST AID MEASURES
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 2/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
General advice
Remove contaminated clothing immediately and dispose of safely.
Inhalation
If symptoms persist, call a physician. Move to fresh air. Keep patient warm and at rest.
Skin contact
Take off contaminated clothing and shoes immediately. Take off contaminated clothing and
shoes immediately. Wash off immediately with soap and plenty of water. Wash off immediately
with soap and plenty of water. After skin contact: Apply Vitamin E cream or a simple body milk.
After skin contact: Apply Vitamin E cream or a simple body milk. If symptoms persist, call a
physician.
Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Ingestion
Obtain medical attention. Do not induce vomiting. Rinse mouth. Risk of product entering the
lungs on vomiting after ingestion. Keep at rest.
Notes to Physician
Symptoms
Local:, After skin contact: paresthesia (local)., May cause irritation to skin and mucous
membranes., Inhalation may provoke the following symptoms:, irritation, cough
Symptoms
Systemic:, excitement, gastrointestinal discomfort, tremors, Dizziness, headache, listlessness,
nausea and vomiting, epigastric pain, muscular fasciculation of limbs, unconsciousness,
convulsions and coma (very high doses).
Risks
This product contains a pyrethroid.
Must NOT be confused with organophosphorus compounds!
Treatment
Local treatment:
Initial treatment should be symptomatic and supportive.
After eye contact: Instillation of local anaesthetic drops e.g. 1% Amethocaine Hydrochloride eye
drops. Give Analgesics as necessary.
Treatment
Systemic treatment:
Endotracheal intubation should be done and gastric lavage performed, followed by
administration of charcoal.
Monitoring of respiratory and cardiac functions.
ECG - monitoring (Electrocardiogram).
Check for pulmonary oedema in event of inhalation.
Keep airway clear, administer artificial respiration if necessary.
Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully
sedated; for children 2.5 mg i.v.
There is no specific antidote.
Contraindication: atropine.
Contraindication: derivatives of adrenaline.
Recovery: spontaneous.
5. FIRE-FIGHTING MEASURES
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 3/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media which must not be used for safety reasons
high volume water jet
Specific hazards during fire fighting
In case of fire the evolution of dangerous gases is possible.
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Remove product from areas of fire, or otherwise cool containers with water in order to avoid
pressure being built up due to heat.
Whenever possible, contain fire-fighting water by diking area with sand or earth.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Keep people away from and upwind of spill/leak.
Avoid contact with spilled product or contaminated surfaces.
When dealing with a spillage do not eat, drink or smoke.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Keep in suitable, closed containers for disposal.
Clean floors and contaminated objects with plenty of water.
Additional Advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
Check also for any local site procedures.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
No specific precautions required when handling unopened packs/containers; follow relevant
manual handling advice.
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
The product is flammable.
Keep away from sources of ignition - No smoking.
Vapours may form explosive mixture with air.
Storage
Requirements for storage areas and containers
Keep containers tightly closed in a cool, well-ventilated place.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 4/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
Store in a place accessible by authorized persons only.
Keep away from direct sunlight.
Protect against frost.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage temperature 0 - 30 癈
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
2-Methylpropan-1-ol 78-83-1 150 mg/m3 / 50 ppm 2003 INRS (FR)
(VME)
Personal protective equipment
Respiratory Protection Wear respirator conforming to EN140 type A filter.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and Type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
Hygiene measures
When using, do not eat, drink or smoke.
Remove soiled clothing immediately.
Remove soaked protective clothing immediately.
Clean hands and face at work intervals and after work.
Work in an adequately ventilated room.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colour yellow
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 5/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
Safety data
Flash Point 42 癈
Ignition temperature > 450 癈
The data refers to solvent naphtha petroleum.
Upper explosion limit 7,00 %(V)
The data refers to solvent naphtha petroleum.
Lower explosion limit 0,8 %(V)
The data refers to solvent naphtha petroleum.
Relative vapour density 1,00
The data refers to solvent naphtha petroleum.
Density ca. 0,94 g/cm?at 20 癈
Water Solubility emulsifiable
Other Information The product is flammable.
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid None.
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) 710 mg/kg
Acute Inhalation Toxicity LC50 (rat) 2,69 mg/l
Exposure time: 4 h
Irritating to respiratory system.
Test conducted with a similar formulation.
Acute Dermal Toxicity LD50 (rat) > 2.000 mg/kg
Skin Irritation No skin irritation. (rabbit)
Eye Irritation Risk of serious damage to eyes. (rabbit)
Further information
Cutaneous sensations may occur, such as burning or stinging on the face and mucosae.
However, these sensations cause no lesions and are of a transitory nature (max. 24 hours).
When inhaled in high concentration, the solvent vapours cause a narcotic effect.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 6/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Bioaccumulation Bluegill sunfish
Bioconcentration factor (BCF): 1.400
The value mentioned relates to the active ingredient deltamethrin.
Bioaccumulation Bluegill sunfish
Bioconcentration factor (BCF): 260
The value mentioned relates to the active ingredient piperonyl
butoxide.
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 0,00091 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient deltamethrin.
Toxicity to Fish (Cyprinodon variegatus (sheepshead minnow)) 3,94 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient piperonyl
butoxide.
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0,00056 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient deltamethrin.
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 0,51 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient piperonyl
butoxide.
Toxicity to algae EC50 (Algae) > 9,1 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient deltamethrin.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Contaminated packaging
Rince empty containers and dispose of them through the ADIVALOR collection organization or
another specific collection system. Smaller packagings (consumer products) can also be
disposed of through the cost-free Dual Collection System (Green Dot).
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 7/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
UN-No 1993
Labels 3
Packaging group III
Hazard no. 30
Description of the goods UN 1993 FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION)
Special Provision 640E
IMDG
UN-No 1993
Class 3
Packaging group III
EmS F-E , S-E
Marine pollutant Marine pollutant
Description of the goods FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION )
IATA
UN-No 1993
Class 3
Packaging group III
Description of the goods FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION )
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
1999/45/EC as amended.
Classification:
Labelling according to EEC Directive
Hazardous components which must be listed on the label:
?Deltamethrin
?Piperonyl butoxide
?Solvent Naphtha (petroleum), light aromatic
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 8/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S39 Wear eye/face protection.
S57 Use appropriate container to avoid environmental contamination.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
Classement France (d閏ision d'autorisation de mise sur le march?
Symbol(s)
Xn Harmful
R-phrase(s)
R10 Flammable.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
S-phrase(s)
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feedingstuffs.
S20/21 When using do not eat, drink or smoke.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: II (Moderately hazardous)
L間islation des Installations Class閑s pour la Protection de l'Environnement (Loi du 19/07/76
modifi閑 et D閏ret du 10/08/05)
Rubrique n?1172 : Stockage et emploi de substances dangereuses pour l'environnement (tr鑣
toxiques pour les organismes aquatiques)
Occupational diseases
Table number(s) :
84 Health effects caused by organic solvents in occupational applications.
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R10 Flammable.
R21 Harmful in contact with skin.
R23/25 Toxic by inhalation and if swallowed.
R34 Causes burns.
R37 Irritating to respiratory system.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
K-OBIOL EC275 12X1L BOT GB 9/9
Version 2 / F Revision Date: 27.03.2006
102000002608 Print Date: 03.07.2007
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
The information provided in this safety data sheet has been provided according the requirements
from the French modified decree "arr阾?du 5 janvier 1993". This sheet complements the technical
sheet but does not replace it. The information contained in this sheet is based on knowledge of the
product at the date of publication and is given in good faith. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The user is
fully responsible for taking all the necessary precautions whilst using the product.The aim of the
statutory regulations indicated is to help the user to fulfil his obligations regarding the use of
hazardous products. This list should not be considered as exhaustive. It does not exonerate the user
from fulfilling other existing legal obligations in addition to those mentioned, relating to the use and
storage of the product. This remains solely the responsibility of the user.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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