Product Name: Farmoz Aphidex WG Aphicide
Page: 1 of 6
This revision issued: November, 2006
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Pirimicarb is a carbamate derivative.
Farmoz Aphidex WG Aphicide
Trade Name:
Product Use: Agricultural aphicide for use as described on the product label.
Creation Date: November, 2006
Revision Date: November, 2006
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: T, Toxic. Hazardous according to the criteria of ASCC.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R25, R20/21. Toxic if swallowed. Harmful by inhalation and in contact with skin.
Safety Phrases: S20, S22, S38, S45, S24/25. When using, do not eat or drink. Do not breathe dust. In case of
insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, contact a doctor
or Poisons Information Centre immediately (show this MSDS where possible). Avoid contact with skin and eyes.
SUSDP Classification: S6
ADG Classification: Class 6.1 (CARBAMATE PESTICIDE, SOLID, TOXIC)
UN Number: 2757
Emergency Overview
Physical Description & colour: Off-white granulated solid.
Odour: No data.
Major Health Hazards: toxic if swallowed, harmful by inhalation and in contact with skin. Signs and symptoms
associated with mild exposures to organophosphate and carbamate pesticides include: headache, fatigue, dizziness,
loss of appetite with nausea, stomach cramps and diarrhoea; blurred vision associated with excessive tearing;
contracted pupils of the eye; excessive sweating and salivation; slowed heartbeat, often fewer than 50 per minute;
rippling of surface muscles just under the skin. These symptoms may be mistaken for those of flu, heat stroke or heat
exhaustion, or upset stomach. Moderately severe organophosphate and carbamate insecticide poisoning cases
exhibit all the signs and symptoms found in mild poisonings, but in addition, the victim: is unable to walk; often
complains of chest discomfort and tightness; exhibits marked constriction of the pupils (pinpoint pupils); exhibits
muscle twitching; has involuntary urination and bowel movement. Severe poisonings are indicated by incontinence,
unconsciousness and seizures.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation:
Short term exposure: Long term inhalation of high amounts of any nuisance dust may overload lung clearance
mechanism. Symptoms are described fully above.
Skin Contact:
Short term exposure: Symptoms are described fully above.
Eye Contact:
Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild
transient discomfort.
Ingestion:
Short term exposure: Symptoms are described fully above.
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Aphidex WG Aphicide
Page: 2 of 6
This revision issued: November, 2006
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Pirimicarb 23103-98-2 500g/kg not set not set
Calcium carbonate 471-34-1 320g/kg 10 not set
Other non hazardous ingredients secret to 100% not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The ASCC TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Atropine tablets 0.6mg and activated charcoal should be available in the area where this product is used, or in a
nearby unlocked medicine cabinet. If swallowed, splashed on skin or inhaled, contact a Poisons Information Centre or
a doctor at once. Remove any contaminated clothing and wash skin thoroughly. If swallowed, use of activated
charcoal may be advised. Give atropine if instructed. The usual instruction is to give one atropine tablet every 5
minutes until dryness of the mouth occurs.
Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at
once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if
administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about
unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure. See instructions
above about treatment with atropine.
Skin Contact: Quickly and gently brush away excess solids. Wash gently and thoroughly with warm water (use non-
abrasive soap if necessary) for 10-20 minutes or until product is removed. Under running water, remove contaminated
clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or
discard. See instructions above about treatment with atropine.
Eye Contact: Quickly and gently brush particles from eyes. No effects expected. If irritation does occur, flush
contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical
advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting; rinse mouth thoroughly with water and contact a Poisons
Information Centre, or call a doctor at once. Give activated charcoal if instructed. See instructions above about
treatment with atropine.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot
liquids. This product, if scattered, may form flammable or explosive dust clouds in air.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog. Water fog
or fine spray is the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. Do not scatter spilled
material with high pressure water jets.
Flash point: Combustible solid.
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: No data.
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Aphidex WG Aphicide
Page: 3 of 6
This revision issued: November, 2006
clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that dusts are likely to build up in cleanup area, we recommend that you use a suitable
Dust Mask. Use a P1 mask, designed for use against mechanically generated particles eg silica & asbestos.
Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Because of the toxicity of this product, special personal care should be
taken in any cleanup operation. Sweep up and shovel or collect recoverable product into labelled containers for
recycling or salvage, and dispose of promptly. Consider vacuuming if appropriate. Recycle containers wherever
possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff
from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details
regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict
between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting
regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature
of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store in a cool, well ventilated area. Check containers periodically for leaks. Containers
should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with
substances listed under "Incompatibilities" in Section 10. If you keep more than 10000kg or L of Dangerous Goods of
Packaging Group III, you may be required to license the premises or notify your Dangerous Goods authority. If you
have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check
packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
ASCC Exposure limits
Calcium carbonate 10 not set
The ADI for Pirimicarb is set at 0.002mg/kg/day. The corresponding NOEL is set at 0.4mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2005.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below
the TWA levels. If necessary, use a fan.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being
used, we recommend that you use a suitable Dust Mask. Use a P1 mask, designed for use against mechanically
generated particles eg silica & asbestos. Otherwise, not normally necessary.
Safety deluge showers should, if practical, be provided near to where this product is being used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Off-white granulated solid.
Odour: No data.
Boiling Point: Not available.
Freezing/Melting Point: Pirimicarb melts approx 92掳C
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Aphidex WG Aphicide
Page: 4 of 6
This revision issued: November, 2006
Volatiles: No specific data. Expected to be low at 100掳C.
Vapour Pressure: Pirimicarb 0.97mPa at 25掳C
Vapour Density: No data.
Specific Gravity: No data. Bulk density 0.61
Water Solubility: Soluble.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: 1.7 (unionised) (log P octanol/water)
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Containers should be
kept dry. Keep isolated from combustible materials. Store in the closed original container in a dry, cool, well-ventilated
area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing
atmospheres. Oxides of sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a
foul odour. Water, sodium compounds. Carbon monoxide poisoning produces headache, weakness, nausea,
dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
The following data is for Pirimicarb
ACUTE TOXICITY DERMAL: LD50 = >500mg/kg (rat); nonirritant.
ORAL: LD50 = 147mg/kg (rat) LD50 = 107mg/kg (mouse); 25-50mg/kg (poultry); 100-200mg/kg (dog).
INHALATION LC50 (rat) 0.3mg/L (6 hours) - Pesticides Manual
EYES: Pirimicarb caused no irritation when introduced as a 5% solution of technical material into the eyes of rabbits.
SUBACUTE AND CHRONIC TOXICITY: Rat: No ill effects were detected when rats were fed 750 ppm for 90 days.
Dog: In feeding tests for a period of 90 days, a no-effect level of 1.8 mg/kg was demonstrated. Daily application of
500mg/kg to rabbits (dermally) for 24 hours over a 14 day period produced no toxic signs during the experiment or
during the next 14 days. Rats exposed for 6 hr/d (5 d/week) for 21 d, to air which had been passed over technical
Pirimicarb at room temperature developed no toxic sign, nor was there inhibition of cholinesterase.
Daily applications of 500 mg/kg (for 24-hr) to rabbit skin over a 14-day period produced no toxic symptom. In 2-yr
feeding trials NEL was: for dogs 1.8mg/kg daily; for rats 250 mg/kg diet (12.5mg/kg daily).
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Pirimicarb Conc>=25%: T; R25
Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
Pirimicarb presents some hazard to fish, birds, and beneficial insects. Some hazard to honey bees. Biological
magnification unlikely. Nonphytotoxic. Does not harm lady birds or lacewings. Low bee toxicity. LC50 (96-hr) is: for
bluegill 55mg/l; for rainbow trout 29 mg/l. Acute oral LD50 for mallard duck 17.2mg/kg; for bobwhite quail 8.2mg/kg.
Approximate Residual Period: Relatively short in plants; broken down rapidly by ultraviolet light.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Aphidex WG Aphicide
Page: 5 of 6
This revision issued: November, 2006
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. This
product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these
options is suitable, we suggest that you contact a specialist disposal company to arrange disposal. Disposal by
untrained personnel may cause a dangerous incident.
Section 14 - Transport Information
ADG Code: 2757, CARBAMATE PESTICIDE, SOLID, TOXIC
Hazchem Code: 2X
Special Provisions: SP61, SP109, SP274
Dangerous Goods Class: Class 6.1, Toxic Substances.
Packaging Group: III
Packaging Method: 3.8.6
Class 6 Toxic Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 3 (Flammable Liquids where the Flammable Liquid is nitromethane), 5.1 (Oxidising Agents
where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides where the Toxic Substances are Fire
Risk Substances), 8 (Corrosive Substances where the Toxic Substances are cyanides and the Corrosives are acids),
Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the same freight
container with Classes, 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Toxic Gases), 3
(Flammable liquids, except where the flammable liquid is nitromethane), 4.1 (Flammable Solids), 4.2 (Spontaneously
Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents except where the Toxic
Substances are Fire Risk Substances), 5.2 (Organic Peroxides except where the Toxic Substances are Fire Risk
Substances), 7 (Radioactive Substances), 8 (Corrosive Substances except where the Toxic Substances are cyanides
and the Corrosives are acids), 9 (Miscellaneous Dangerous Goods)
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredient; pirimicarb is listed in the Standard for the Uniform Scheduling of Drugs and Poisons.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
ASCC Office of the Australian Safety and Compensation Council
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Aphidex WG Aphicide
Page: 6 of 6
This revision issued: November, 2006
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document 鈥淣ational Code of Practice for the Preparation
of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, November, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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