MATERIAL SAFETY DATA SHEET
Product Name: Genfarm Relic 250 EC Systemic Fungicide
This revision issued: August, 2005 Page: 1 of 5
Section 1 - Identification Of Chemical Product And Company
Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
Suite 3, Level 1, 64 Talavera Road Fax: (02) 9889 5411
Macquarie Park, NSW, 2113
Substance: Active ingredient is a triazole derivative.
Genfarm Relic 250 EC Systemic Fungicide
Trade Name:
Product Use: Agricultural fungicide for use as described on the product label.
Creation Date: June, 2004
Revision Date: August, 2005
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R65. Harmful: May cause lung damage if swallowed.
Safety Phrases: S39, S45, S46. Wear eye/face protection. In case of accident or if you feel unwell, contact a doctor
or Poisons Information Centre immediately (show the label where possible). If swallowed, contact a doctor or Poisons
Information Centre immediately and show this container or label.
SUSDP Classification: S6
ADG Classification: None allocated. Not a Dangerous Good.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Clear, yellowish coloured liquid.
Odour: Non specific hydrocarbon odour.
Major Health Hazards: may cause central nervous system depression in contact with skin; if aspirated, may cause
lung damage.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. In addition product is unlikely to cause any discomfort or irritation.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data shows that this product is a mild Central Nervous System depressor, but
symptoms are not available. However product is unlikely to cause any discomfort in normal use.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this
product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to
remove and can cause severe injury or death. This product is unlikely to cause any irritation problems in the short or
long term.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Issued by: Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
MATERIAL SAFETY DATA SHEET
Product Name: Genfarm Relic 250 EC Systemic Fungicide
This revision issued: August, 2005 Page: 2 of 5
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Propiconazole 60207-90-1 25 not set not set
Liquid hydrocarbon 64742-94-5 60 not set not set
Non hazardous emulsifiers secret 10-30 not set not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: If skin contact occurs, thoroughly wash skin with soap and water. If any unusual symptoms become
evident, contact a Poisons Information Centre or a doctor.
Eye Contact: Flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the
eyelid(s) open. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is a moderate risk of
an explosion from this product if commercial quantities are involved in a fire. Firefighters should take care and
appropriate precautions. Violent steam generation or eruption may occur upon application of direct water stream on
hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying
spaces, forming potentially explosive mixtures. They may also flash back considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: >61掳C
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective glasses and,
preferably, goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we
recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you
have any doubts consult the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Can be slippery on floors, especially when wet. Recycle containers wherever possible after
careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering
Issued by: Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
MATERIAL SAFETY DATA SHEET
Product Name: Genfarm Relic 250 EC Systemic Fungicide
This revision issued: August, 2005 Page: 3 of 5
drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of
used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS
and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal.
Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when
sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, may meet the definition of Dangerous
Goods in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods laws in order to clarify your obligations regarding their storage.
Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the
product does not come into contact with substances listed under "Materials to avoid" in Section 10. Some liquid
preparations settle or separate on standing and may require stirring before use. Check packaging - there may be
further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
The ADI for Propiconazole is set at 0.04mg/kg/day. The corresponding NOEL is set at 4mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2003.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Eye protection such as protective glasses or goggles should be worn when there is a chance of
irritant levels of vapours being generated. However, it would be better to remove the vapours or avoid their
generation.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear, yellowish coloured liquid.
Odour: Non specific hydrocarbon odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No data.
Vapour Pressure: No data.
Vapour Density: No data.
Specific Gravity: 0.99 at 20掳C
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Issued by: Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
MATERIAL SAFETY DATA SHEET
Product Name: Genfarm Relic 250 EC Systemic Fungicide
This revision issued: August, 2005 Page: 4 of 5
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Water.
Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,
disturbance of judgment, and unconsciousness followed by coma and death. Hydrogen cyanide poisoning signs and
symptoms are weakness, dizziness, headache, nausea, vomiting, coma, convulsions, and death. Death results from
respiratory arrest. Hydrogen cyanide gas acts very rapidly; symptoms and death can both occur quickly.
Polymerisation: This product is unlikely to undergo polymerisation processes.
Section 11 - Toxicological Information
Toxicity: For Propiconazole:
LD50 Oral (Rat) 1517mg/kg LD50 Oral (Mouse) 1419mg/kg
LD50 Dermal (Rat) >4000mg/kg LD50 Dermal (Rabbit) >6000mg/kg
LC50 Inhal (Rat, 4hr) >5800mg/m3
Section 12 - Ecological Information
For Propiconazole:
Birds: LD50 Japanese quail: 2223mg/kg LD50 Bobwhite quail: >2825mg/kg
LD50 mallard ducks: >2510mg/kg
Fish: LC50 carp: 6.8mg/L LC50 rainbow trout: 5.3mg/L
LC50 golden orfe: 5.1mg/L
Algae: EC50 0.02-13.6mg/L
Bees: not toxic to bees
Daphnia: EC50 4.8mg/L
After oral administration to the rat, Propiconazole is rapidly absorbed and also rapidly and almost completely
eliminated with urine and faeces. Residues in tissues were generally low and there was no evidence for accumulation
or retention of Propiconazole or its metabolites. The major sites of enzymatic attack are the propyl side-chain and the
cleavage of the dioxolane ring, together with some attack at the 2,4-dichlorophenyl and 1,2,4-triazole rings. In the
mouse, the major metabolic pathway is via cleavage of the dioxolane ring.
Plants: Degradation proceeds through hydroxylation of the n-propyl side-chain and deketalisation of the dioloxane
ring. After cleavage of triazole, triazole-alanine is formed as the main metabolite. Metabolites are conjugated mostly
as glucosides.
The main degradation pathways are hydroxylation of the propyl side-chain and the dioxolane ring, and finally
formation of the 1,2,4-triazole. Koc (ads) 950ml/g, immobile in soil.
Section 13 - Disposal Considerations
Disposal: Instructions concerning the disposal of this product and its containers are given on the product label.
These should be carefully followed.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredients: Propiconazole, Liquid hydrocarbon, are mentioned in the SUSDP.
Issued by: Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
MATERIAL SAFETY DATA SHEET
Product Name: Genfarm Relic 250 EC Systemic Fungicide
This revision issued: August, 2005 Page: 5 of 5
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Number Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, August, 2005.
http://www.kilford.com.au/ Phone (02)9251 4532
Issued by: Genfarm Crop Protection Pty Ltd Phone: (02) 9889 5400
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