MATERIAL SAFETY DATA SHEET
Complies with OSHA Hazard Communications Standard 29 CFR 1910.1200
Product Desc: N.C.C.E. Antibacterial Hand Soap
Product Code 55-1010-00 HMIS codes H F R P
1 0 0 X (See Section VIII)
Section I: Manufacturer Information
Name: N.C. Dept. of Correction, Janitorial Products Plant
Mailing Address: 1205 E. McNeil St., P.O. Box 1569
City/State/ Zip: Lillington, North Carolina 27546
Telephone: For Information- (910) 893-4552
For Emergency - CHEMTREC - 1-800-424-9300
Date Prepared: July 1, 2002 Date Revised: N/A
Contact For Technical Information: Plant Manager
Telephone: (910) 893-4552 Fax: (910) 893-6042
Section II: Composition/Information on ingredients and exposure guidelines
COMPONENTS CAS NO. TYPICAL % NCOS ACGIH
(Chemical Name BY WEIGHT PEL TLV
and Synonyms)
Detergent Blend Trade Secret 12 鈥? 14 NE NE
*Cocoamide DEA 68603-42-9 2-5 NE NE
*Diethanolamine (DEA) 111-42-2 < 0.3 3ppm 0.46ppm
TWA TWA
(skin)
Glycerin 56-81-2 0 - <1 NE NE
Propylene Glycol 57-55-6 1-2 NE NE
*2-Hydroxy-1,2,3-Propanetricarboxylic Acid
(Citric Acid) 77-92-9 0 - <1 NE NE
CI Acid Orange #7 633-96-5 < 0.1 NE NE
*Floral Perfume Trade Secret < 1 NE NE
Sodium Laureth Sulfate 68585-34-2 <1 NE NE
D-Glucopyranoside 113976-90-2 < 1 NE NE
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*Ethanol 75-21-8 <1 1000 ppm 1000 ppm
TWA TWA
*P-Chloroxylenol 88-04-0 < 0.3 NE NE
Water 7732-18-5 78 - 82 NE NE
*These substances are hazardous chemicals as defined by the hazard communication
standard (29 CFR 1910.1200) NE: Not Established
Section III: Hazards Identifications
EMERGENCY OVERVIEW
A viscous, burnt-orange liquid with a sweet scent. May cause mild eye irritation. May
cause irritation of the skin to individuals with sensitive skin. Vapors and mists may cause
nose and throat irritation. May be harmful if swallowed. For large spills, emergency
responders should wear impervious coveralls, boots, gloves, and goggles, and keep
material out of waterways and storm sewers. Absorb spill with inert material or transfer
to a suitable container for reuse or disposal. See section 3, 6, and 10.
Potential Health Effects and Primary Routes of Entry:
Inhalation: Breathing vapors or mists of this product may cause irritation of the nose
and throat.
Skin: May cause irritation of the skin to individuals with sensitive skin. May cause
irritations to breaks of the skin. If skin irritaton develops, discontinue use.
Eyes: Eye contact may cause irritation. Repeated or prolonged exposure may cause
redness of the eyes.
Ingestion: Ingestion may cause mouth, throat, esophagus, and stomach irritation,
nausea, vomiting, and diarrhea.
Chronic Effects/ Carcinogenicity: None of the components in this product at
concentrations of 0.1% or greater are listed by the NTP, IARC or OSHA as carcinogens.
Section IV: First Aid
Eyes: Immediately flush eyes with water for at least 20 minutes and seek immediate
medical attention. Eyelids should be held away from the eyeballs to ensure thorough
rinsing.
Skin: Immediately flush skin with plenty of water. Remove contaminated clothing and
shoes. Seek medical attention if irritation develops and persists. Launder clothing before
reuse.
Inhalation: Move victim to fresh air, administer artificial respiration if not breathing.
Give oxygen if breathing is difficult. Trained person should give oxygen if breathing is
difficult. Get medical attention.
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Ingestion: If swallowed, call a physician immediately. DO NOT induce vomiting,
unless directed to do so by a physician. Give person plenty of water to drink. If possible,
do not leave person unattended. Never give anything by mouth to an unconscious person.
Medical Conditions Generally Aggravated By Exposure: None known
Section V: Fire and Explosion Data
Flash Point: > 200 degrees F. Non-combustible
Flammable Limits: Not determined
Extinguishing Media: If this product is involved in a fire, use an extinguishing
media that is appropriate for combustibles in the area such as water spray, dry chemical,
alcohol foam, or carbon dioxide. Keep containers cool with water spray to prevent
container rupturing due to steam pressure and to prevent thermal decomposition.
Fire and Explosion Hazards: During a fire, the product may decompose and can
emit carbon dioxide and carbon monoxide.
Fire-Fighting Equipment: Exposed firefighters should wear NIOSH/MSHA approved
self-contained breathing apparatuses under positive pressure and chemical-resistant
protective equipment. Refer to section 8 for further information.
Section VI: Accidental Release Measures
SMALL SPILL: Cleanup personnel should wear appropriate equipment (See
Section 8). Floor may be slippery, use care to avoid falling. Stop and control leak. Small
spills can be diluted with plenty of water and mopped up or absorbed with an inert
absorbent material. Mop spill area several times with water. Dispose of waste properly
(See Section 13).
LARGE SPILL: Untrained persons and those not wearing proper protective
equipment should be excluded from the spill area until cleanup is complete. Trained
cleanup personnel should wear chemical splash goggles and a face shield, rubber boots,
rubber gloves, and impervious clothing. Respiratory protection could be required for
controlling large spills in confined or poorly ventilated areas. Stop and control leak and
keep material out of sewers and watercourses by diking or impounding with sand or
absorbent materials. Flush spill area with plenty of water. All cleanup residues should
be collected in a non-metallic labeled container for disposal (See Section 13).
Contact CHEMTREC (800-424-9300) for technical advice and assistance relating to
chemical emergencies involving this product.
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Section VII: Handling and Storage
Handling: Do not get in eyes, on skin, or on clothing. Avoid breathing mist or vapor.
Use with adequate ventilation. Do not taste or swallow. Wash thoroughly after handling.
Remove contaminated clothing and launder before reuse. Do not mix with any other
chemical or cleaning agent.
Storage: Keep containers in well ventilated area and closed when not in use. Keep away
from heat and flame. Keep product in original container. For institutional use only.
Keep this and all chemicals out of reach of children. Do not store above 100 degrees F or
in direct sunlight.
Section VIII: Exposure Control/Personal Protection
Respiratory Protection: Not normally required in well-ventilated area. Use NIOSH
approved air-purifying respirator with an organic vapor cartridge if there is a reasonable
possibility for harmful exposure to vapors or mists. Protection by air purifying
respirators is limited. Use NIOSH approved self-contained apparatus made for
emergencies or entry into unknown concentrations or immediately dangerous to life or
health conditions. All personal respiratory protection equipment should be used in
accordance with OSHA 29 CFR 1910.134.
Ventilation: Provide sufficient mechanical (general and/or local exhaust ventilation) to
maintain vapor mist concentrations below exposure limits.
Protective Gloves: Not needed for normal use. Use chemical-resistant rubber gloves
for spill clean up.
Eye Protection: Avoid eye contact. Chemical splash goggles are recommended for
clean up or whenever eye contact may occur. Provide an ANSI-approved eye wash
station in the work area.
Other Protective Clothing or Equipment: Use chemical-resistant apron or other
impervious clothing, and rubber boots if necessary, to avoid contaminating regular
clothing and shoes and to prevent skin contact.
Section IX: Physical/Chemical Properties
APPEARANCE ODOR
Viscous burnt-orange liquid Sweet scented odor
BOILING RANGE VAPOR PRESSURE
Undetermined Undetermined
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SPECIFIC GRAVITY VAPOR DENSITY (Air = 1)
1.008 鈥? 1.020 Undetermined
pH PERCENT VOLATILE BY VOLUME
7.5 to 8.5 Undetermined
MELTING POINT EVAPORATION RATE
Not applicable Slower than butyl acetate
VISCOSITY SOLUBILITY IN WATER
850 - 1250 Centipoise completely soluble
Section X: Reactivity Information
Stability: Product is stable. Avoid elevated temperatures.
Incompatibility: Due to the organic nature of this detergent, it is expected to be
incompatible with acids and strong oxidizing agents.
Hazardous Reaction/Decomposition or by Product: Burning can produce acrid smoke
and toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
Section XI: Toxicological Information
Significant ingredients used in this product have the following toxicological data:
ANIMAL DATA: Cocoamide DEA
Ingestion: Oral-Rat LD50: 1.2 g/kg
Inhalation: Inhalation Toxicity: Irritant (rabbit)
Contact: Ocular Irritation Studies: Severe (rabbit)
Propylene Glycol
Contact: Eye-Rabbit 100 mg - Mild irritation effects
Eye-Rabbit 500 mg/24H - mild irritation effects
Ingestion: Oral-rat LD50: 20g/kg
Oral-Mouse LD50: 22g/kg
Other: DNA Inhibition-Mouse-Subcutaneous 8,000 mg/kg
Cytogenic Analysis-Mouse-Subcutaneous 8,000 mg/kg
Cytogenic Analysis-Hamster: fibroblast 32 g/L
Experimental teratogenic and reproductive effects have been noted in studies with
laboratory animals injected with this substance.
HUMAN DATA: Propylene Glycol
Contact: Skin-Human 500 mg/7D - Mild irritation effects
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Skin-Human 104 mg/3D-I - Moderate irritation effects (
Ingestion: Human systemic effects by ingestion: general anesthesia, convulsions,
changes in surface electroencephalogram.
Oral-Child TDLo: 79 g/kg/56W-I - Central nervous system effects
Parental-Infant TDLo: 10g/kg/3D-C - Systemic effects
Section XII: Ecological Information
Ecotoxicological information: Not available for product. Product may be
dangerous if it enters water intakes. Keep product out of water intakes and storm sewer
systems.
Chemical Fate Information: Not available for product. Product could slightly
raise the pH of surface water, depending on size of spill. Once the product is diluted with
plenty of water or neutralized, its impact should be slight.
Section XIII: Disposal Consideration
Waste Disposal: Unused product is not expected to be a hazardous waste under RCRA.
Used material may be subject to regulation depending on the contaminates added during
use. Any disposal must be in accordance with federal, state, and local regulations. Do not
discharge product to storm sewers or waterways. Dilute (used) detergent solutions may
typically be discharged to local wastewater treatment facilities. As with any wastewater,
consultation with local treatment plant staff is recommended before disposal.
Concentrated product should be recovered for reuse.
Section XIV: Transport Information
DOT Proper Shipping Description: None
Dot Hazard Class / Division Label: None
Shipping Containers: 1 - Gallon Bottles, 4 bottles per case
Section XV: Regulatory Information
OSHA Hazard Communication Standard: OSHA hazardous chemicals as
defined under 29 CFR 1910.1200 are listed in Section II.
Toxic Substances Control Act (TSCA): The intentional ingredients of this
product are listed.
SARA Title III:
Section 302 Extremely Hazardous Substances: None
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Section 311 /312 Hazard Categories: Immediate (acute) health hazard
Section 313 Toxic Chemicals*: None present at or above the minimum reportable
concentrations.
*Note: Reporting is only applicable to manufacturers in SIC Codes 20 鈥? 39.
CERLA Hazardous Substances: Components present in this product that could
require reporting under the statute are: None present at or above 0.00008 % in final
product.
Section XVI: Other Information
This product is for institutional use only and is not for resale.
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